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Methylammonium formate

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Methylammonium formate
Identifiers
CAS Number
3D model (JSmol)
EC Number
  • 827-119-8
PubChem CID
InChI
  • InChI=1S/CH5N.CH2O2/c1-2;2-1-3/h2H2,1H3;1H,(H,2,3)Key: BAONHUZQTANSBI-UHFFFAOYSA-N
SMILES
  • C.C(=O)
Properties
Chemical formula C2H7NO2
Molar mass 77.083 g·mol
Density 1.05
Melting point 13 °C (55 °F; 286 K)
Boiling point 162.1 °C (323.8 °F; 435.2 K)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). Infobox references
Chemical compound

Methylammonium formate is an ionic liquid consisting of methylammonium (CH3NH3) as the cation and formate (HCOO) as the anion. This salt can be formed by the reaction between methylamine (CH3NH2) and formic acid (HCOOH). It has characteristics of both an ammonium salt and a formate salt. It is soluble in water, as well as other polar solvents.

References

  1. Gu, Lei; Ran, Chenxin; Chao, Lingfeng; Bao, Yaqi; Hui, Wei; Wang, Yue; Chen, Yonghua; Gao, Xingyu; Song, Lin (2022). "Designing Ionic Liquids as the Solvent for Efficient and Stable Perovskite Solar Cells". ACS Applied Materials & Interfaces. 14 (20): 22870–22878. doi:10.1021/acsami.1c21035. PMID 35077147.
  2. Grossman, Shau; Danielson, Neil D. (April 2009). "Methylammonium formate as a mobile phase modifier for totally aqueous reversed-phase liquid chromatography". Journal of Chromatography A. 1216 (16): 3578–3586. doi:10.1016/j.chroma.2008.09.064. PMC 2716170. PMID 18849044.
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