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Neodymium bismuthide

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Neodymium bismuthide
Names
Other names Neodymium(III) bismuthide
Identifiers
CAS Number
3D model (JSmol)
ChemSpider
PubChem CID
CompTox Dashboard (EPA)
InChI
  • InChI=1S/Bi.NdKey: VNARRZRNLSEBPY-UHFFFAOYSA-N
SMILES
  • .
Properties
Chemical formula BiNd
Molar mass 352.22 g/mol
Density 8.8 g/cm
Melting point 1775°C; 1900°C
Critical point (T, P) -111 kJ/mol
Structure
Crystal structure cubic
Space group Fm3m
Lattice constant a = 6.4222 Å
Formula units (Z) 4
Related compounds
Other anions Neodymium(III) nitride
Neodymium(III) arsenide
Neodymium(III) phosphide
Neodymium(III) antimonide
Neodymium(III) oxide
Other cations PrBi
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). Infobox references
Chemical compound

Neodymium bismuthide or Bismuth-Neodymium is a binary inorganic compound of neodymium and bismuth with the formula NdBi. It forms crystals.

Preparation

Neodymium bismuthide can be prepared by reacting a stoichiometric amount of neodymium and bismuth at 1900°C:

Nd + Bi → NdBi

Physical properties

Neodymium bismuthide forms cubic crystals of the space group Fm3m, with cell parameters a = 0.64222 nm, Z = 4 with a structure like sodium chloride. The compound melts at 1900°C. At a temperature of 24 K, an antiferromagnetic transition occurs in the compound.

References

  1. Abulkhaev V.D. (2001). "Phase digram of the neodymium-bismuth system". Zhurnal Neorganicheskoj Khimii. 46 (4) (Zhurnal Neorganicheskoj Khimii ed.): 659-662. ISSN 0044-457X.
  2. ^ Alloy Phase Diagrams. Vol. 3. 1992. ISBN 0-87170-381-5.
  3. A. Borsese; R. Capelli; S. Delfino; R. Ferro (1974). "The heat of formation of neodymium-bismuth alloys". Thermochimica Acta. 8 (4): 393-397. doi:10.1016/0040-6031(74)85107-5.
  4. Okamoto, H. (2002-03-01). "Bi-Nd (Bismuth-Neodymium)". Journal of Phase Equilibria. 23 (2): 191. doi:10.1361/1054971023604224. ISSN 1054-9714.
  5. Ed. N. P. Lyakisheva (1996). State Diagrams of Binary Metal Systems. Vol. 1. Engineering. p. 992. ISBN 5-217-02688-X.
  6. P. Schobinger-Papamantellos, P. Fischer, O. Vogt, E. Kaldis (1973). "Magnetic ordering of neodymium monopnictides determined by neutron diffraction". J. Phys. C: Solid State Phys. 6 (4): 725-737. Bibcode:1973JPhC....6..725S. doi:10.1088/0022-3719/6/4/020.{{cite journal}}: CS1 maint: multiple names: authors list (link)
Salts and covalent derivatives of the bismuthide ion
-BiH
BiH3
+H 		He
Li Be B R3Bi N -BiO
-BiO3 		F Ne
Na Mg Al Si P S +Cl2 Ar
KBi2 Ca Sc Ti V Cr MnBi Fe Co Ni Cu Zn Ga Ge As Se Br Kr
RbBi2 Sr Y Zr Nb Mo Tc Ru Rh PdBi2 Ag Cd In Sn Sb Te I Xe
CsBi2 Ba * Lu Hf Ta W Re Os Ir PtBi2 Au Hg Tl Pb Bi
-Bi 		Po At Rn
Fr Ra ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
 
* La Ce PrBi NdBi Pm Sm Eu5Sb3
Eu4Sb3
Eu11Sb10 		Gd Tb DyBi HoBi Er Tm Yb
** Ac ThBi
ThBi2 		Pa U NpBi Pu AmBi Cm Bk Cf Es Fm Md No
Neodymium compounds
Nd(II)
Nd(III)
Nd(IV)
Bismuth compounds
Bismuth(III)
Organobismuth(III)
Bismuth(V)
Organobismuth(V)
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