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Spertiniite

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Spertiniite
Spertiniite from Dzhezkazgan, Kazakhstan (size: 5 mm)
General
CategoryOxide mineral
Formula
(repeating unit)
Cu(OH)2
IMA symbolSni
Strunz classification4.FD.05
Dana classification6.2.4.1
Crystal systemOrthorhombic
Crystal classPyramidal (mm2)
H-M symbol: (mm2)
Space groupCmc21
Unit cella = 2.95 Å, b = 10.59 Å
c = 5.27 Å; Z = 4
Identification
Formula mass97.56 g/mol
ColorBlue, blue-green
Crystal habitFlat tabular crystals occurring in radial to botryoidal aggregates
CleavageNone
TenacityBrittle
Mohs scale hardnessSoft
LusterVitreous
DiaphaneityTransparent
Specific gravity3.93
Optical propertiesBiaxial
Refractive indexnα = 1.720, nβ= n.d., nγ = > 1.800
PleochroismStrong; X = colorless; Z = dark blue
Other characteristicsDecomposes in hot water (synthetic)
References

Spertiniite is a rare copper hydroxide mineral. Chemically, it is copper(II) hydroxide with the formula Cu(OH)2. It occurs as blue to blue-green tabular orthorhombic crystal aggregates in a secondary alkaline environment altering chalcocite. Associated minerals include chalcocite, atacamite, native copper, diopside, grossular, and vesuvianite.

Discovery and occurrence

It was first described in 1981 for an occurrence in the Jeffrey quarry of the Johns-Manville mine, Asbestos, Estrie, Québec. It was named for mine geologist Francesco Spertini (born 1937). In addition to the type locality, it has also been reported from Mont Saint-Hilaire, Quebec; Ely, White Pine County, Nevada; and Bisbee, Cochise County, Arizona. It has been reported from Dzhezkazgan, Kazakhstan; from slag at Juliushutte, Astfeld, Harz Mountains, Germany; and from Tsumeb, Namibia.

A 2006 study has produced evidence the blue mineral chrysocolla may be a microscopic mixture of spertiniite, amorphous silica and water.

Crystal structure of spertiniite

References

  1. Warr, L. N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi:10.1180/mgm.2021.43. S2CID 235729616.
  2. ^ Spertiniite on Mindat
  3. ^ Spertiniite in The Handbook of Mineralogy
  4. Spertiniite on Webmineral
  5. François Farges, Karim Benzerara, Gordon E. Brown, Jr.; Chrysocolla Redefined as Spertiniite; SLAC-PUB-12232; 13th International Conference On X-Ray Absorption Fine Structure (XAFS13); July 9-14, 2006; Stanford, California
  6. Chrysocolla on Mindat
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