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| Section2 = {{Chembox Properties | | Section2 = {{Chembox Properties | ||
| Formula = |
| Formula = NaBrO<sub>2</sub> | ||
| O=2 | Na=1 | Br=1 | | O=2 | Na=1 | Br=1 | ||
| Formula_Charge = 0 | | Formula_Charge = 0 |
Revision as of 00:59, 12 January 2024
Names | |
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IUPAC name Sodium bromite | |
Identifiers | |
CAS Number | |
3D model (JSmol) | |
ChemSpider | |
ECHA InfoCard | 100.028.446 |
EC Number |
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PubChem CID | |
UNII | |
CompTox Dashboard (EPA) | |
InChI
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SMILES
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Properties | |
Chemical formula | NaBrO2 |
Molar mass | 134.892 g·mol |
Appearance | Yellow solid |
Density | 2.22 g/cm (trihydrate) |
Structure | |
Crystal structure | Triclinic |
Space group | P1 |
Point group | Ci |
Lattice constant | a = 5.42 Å, b = 6.44 Å, c = 9.00 Åα = 72.8°, β = 87.9°, γ = 70.7° |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). Infobox references |
Sodium bromite is a sodium salt of bromous acid. Its trihydrous form has been isolated in crystal form. It is used by the textile refining industry as a desizing agent for oxidative starch removal.
It is also used as an oxidizing agent for converting alcohols to aldehydes, such as the conversion of benzyl alcohol to benzaldehyde, and for the Hofmann degradation of amides to amines.
References
- Holleman, A. F.; Wiberg, Egon; Wiberg, Nils (2001). Inorganic Chemistry. Academic Press. p. 449. ISBN 9780123526519. Retrieved 7 October 2018.
- Makoto Okawara (1984). "亜臭素酸ナトリウム" [Sodium bromite]. Journal of Synthetic Organic Chemistry, Japan (in Japanese). 42 (8): 751–754. doi:10.5059/yukigoseikyokaishi.42.751.
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Inorganic |
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Organic |
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