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Revision as of 10:37, 13 August 2023 editOAbot (talk | contribs)Bots439,234 editsm Open access bot: doi added to citation with #oabot.← Previous edit Revision as of 00:59, 12 January 2024 edit undoMaruf (talk | contribs)234 edits correctionTag: RevertedNext edit →
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| Section2 = {{Chembox Properties | Section2 = {{Chembox Properties
| Formula = BrNaO<sub>2</sub> | Formula = NaBrO<sub>2</sub>
| O=2 | Na=1 | Br=1 | O=2 | Na=1 | Br=1
| Formula_Charge = 0 | Formula_Charge = 0

Revision as of 00:59, 12 January 2024

Sodium bromite
Names
IUPAC name Sodium bromite
Identifiers
CAS Number
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.028.446 Edit this at Wikidata
EC Number
  • 231-290-9
PubChem CID
UNII
CompTox Dashboard (EPA)
InChI
  • InChI=1S/BrHO2.Na/c2-1-3;/h(H,2,3);/q;+1/p-1Key: NYCVSSWORUBFET-UHFFFAOYSA-M
SMILES
  • Br=O.
Properties
Chemical formula NaBrO2
Molar mass 134.892 g·mol
Appearance Yellow solid
Density 2.22 g/cm (trihydrate)
Structure
Crystal structure Triclinic
Space group P1
Point group Ci
Lattice constant a = 5.42 Å, b = 6.44 Å, c = 9.00 Åα = 72.8°, β = 87.9°, γ = 70.7°
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). Infobox references
Chemical compound

Sodium bromite is a sodium salt of bromous acid. Its trihydrous form has been isolated in crystal form. It is used by the textile refining industry as a desizing agent for oxidative starch removal.

It is also used as an oxidizing agent for converting alcohols to aldehydes, such as the conversion of benzyl alcohol to benzaldehyde, and for the Hofmann degradation of amides to amines.

References

  1. Holleman, A. F.; Wiberg, Egon; Wiberg, Nils (2001). Inorganic Chemistry. Academic Press. p. 449. ISBN 9780123526519. Retrieved 7 October 2018.
  2. Makoto Okawara (1984). "亜臭素酸ナトリウム" [Sodium bromite]. Journal of Synthetic Organic Chemistry, Japan (in Japanese). 42 (8): 751–754. doi:10.5059/yukigoseikyokaishi.42.751.
Sodium compounds
Inorganic
Halides
Chalcogenides
Pnictogenides
Oxyhalides
Oxychalcogenides
Oxypnictogenides
Others
Organic


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