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{{distinguish|Copper arsenite}}
{{chembox {{chembox
| Watchedfields = changed
| verifiedrevid = 399729736 | verifiedrevid = 443420181
| ImageFile = Copper(II)-arsenate-constituent-ions-2D.png | ImageFile = Copper(II)-arsenate-constituent-ions-2D.png
| ImageSize = | ImageSize =
| IUPACName = Copper(II) arsenate | IUPACName = Copper(II) arsenate
| OtherNames = Copper arsenate | OtherNames = Copper arsenate
| Section1 = {{Chembox Identifiers |Section1={{Chembox Identifiers
| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} | ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
| ChemSpiderID = 24279 | ChemSpiderID = 24279
Line 15: Line 17:
| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}} | StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}
| StdInChIKey = RKYSWCFUYJGIQA-UHFFFAOYSA-H | StdInChIKey = RKYSWCFUYJGIQA-UHFFFAOYSA-H
| CASNo = 7778-41-8 | CASNo = 7778-41-8
| CASNo_Ref = {{cascite|??|??}} | CASNo_Ref = {{cascite|correct|??}}
| UNII_Ref = {{fdacite|correct|FDA}}
| UNII = EV78GZO3YS
| PubChem = 26065 | PubChem = 26065
| RTECS = | RTECS =
}} }}
| Section2 = {{Chembox Properties |Section2={{Chembox Properties
| Formula = Cu<sub>3</sub>(AsO<sub>4</sub>)<sub>2</sub> | Formula = Cu<sub>3</sub>(AsO<sub>4</sub>)<sub>2</sub>
| MolarMass = 468.48 g/mol | MolarMass = 468.48 g/mol
| Appearance = blue or bluish green powder | Appearance = blue or bluish green powder
| Density = 5.2 g/cm<sup>3</sup> | Density = 5.2 g/cm<sup>3</sup>
| MeltingPt = 1100 °C | MeltingPtC = 1100
| BoilingPt = | BoilingPt =
| Solubility = insoluble | Solubility = insoluble
| SolubleOther = soluble in ], dilute ]s | SolubleOther = soluble in ], dilute ]s
| SolubilityProduct = 7.95{{e|&minus;36}}<ref name="crc">{{cite book |author1=John Rumble |title=CRC Handbook of Chemistry and Physics |date=June 18, 2018 |publisher=CRC Press |isbn=978-1138561632 |pages=5–188|edition=99 |language=English}}</ref>
}} }}
| Section7 = {{Chembox Hazards |Section7={{Chembox Hazards
| EUIndex = Not listed
| FlashPt = | FlashPt =
| PEL = TWA 1 mg/m<sup>3</sup> (as Cu)<ref name=PGCH>{{PGCH|0150}}</ref>
| REL = TWA 1 mg/m<sup>3</sup> (as Cu)<ref name=PGCH/>
| IDLH = TWA 100 mg/m<sup>3</sup> (as Cu)<ref name=PGCH/>
}} }}
| Section8 = {{Chembox Related |Section8={{Chembox Related
| OtherAnions = | OtherAnions =
| OtherCations = | OtherCations =
}} }}
}} }}


'''Copper arsenate''' (Cu<sub>3</sub>(AsO<sub>4</sub>)<sub>2</sub>.4H<sub>2</sub>O, or Cu<sub>5</sub>H<sub>2</sub>(AsO<sub>4</sub>)<sub>4</sub>.2H<sub>2</sub>O), also called '''copper orthoarsenate''' or '''tricopper arsenate''' or '''tricopper orthoarsenate''', is a blue or bluish-green powder insoluble in water and alcohol and soluble in aqueous ] and dilute acids. Its ] is {{CASREF|CAS=7778-41-8}} or {{CASREF|CAS=10103-61-4}}. '''Copper arsenate''' (Cu<sub>3</sub>(AsO<sub>4</sub>)<sub>2</sub>·4H<sub>2</sub>O, or Cu<sub>5</sub>H<sub>2</sub>(AsO<sub>4</sub>)<sub>4</sub>·2H<sub>2</sub>O), also called '''copper orthoarsenate''', '''tricopper arsenate''', '''cupric arsenate''', or '''tricopper orthoarsenate''', is a blue or bluish-green powder insoluble in water and alcohol and soluble in aqueous ] and dilute acids. Its ] is {{CASREF|CAS=7778-41-8}} or {{CASREF|CAS=10103-61-4}}.


==Uses== ==Uses==
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==Natural occurrences== ==Natural occurrences==
Anhydrous copper arsenate, Cu<sub>3</sub>(AsO<sub>4</sub>)<sub>2</sub>, is found in nature as the mineral '''lammerite'''.<ref>{{ cite journal | first1 = F. C. | last1 = Hawthorne | journal = ] | volume = 71 | year = 1986 | pages = 206–209 | title = Lammerite, Cu<sub>3</sub>(AsO<sub>4</sub>)<sub>2</sub>, a modulated close-packed structure | url = http://www.minsocam.org/ammin/AM71/AM71_206.pdf }}</ref> Copper arsenate tetrahydrate, Cu<sub>3</sub>(AsO<sub>4</sub>)<sub>2</sub>.4H<sub>2</sub>O, occurs naturally as the mineral '''rollandite'''.<ref>{{ cite journal | title = Rollandite, Cu<sub>3</sub>(AsO<sub>4</sub>)<sub>2</sub>·4H<sub>2</sub>O, a new mineral | first1 = H. | last1 = Sarp | first2 = R. | last2 = Černý | journal = Eur. J. Mineral. | volume = 12 | year = 2000 | pages = 1045–1050 | doi = 10.1127/0935-1221/2000/0012-1045 }}</ref> Anhydrous copper arsenate, Cu<sub>3</sub>(AsO<sub>4</sub>)<sub>2</sub>, is found in nature as the mineral '''lammerite'''.<ref>{{ cite journal | first1 = F. C. | last1 = Hawthorne | journal = ] | volume = 71 | year = 1986 | pages = 206–209 | title = Lammerite, Cu<sub>3</sub>(AsO<sub>4</sub>)<sub>2</sub>, a modulated close-packed structure | url = http://www.minsocam.org/ammin/AM71/AM71_206.pdf }}</ref> Copper arsenate tetrahydrate, Cu<sub>3</sub>(AsO<sub>4</sub>)<sub>2</sub>·4H<sub>2</sub>O, occurs naturally as the mineral '''rollandite'''.<ref>{{ cite journal | title = Rollandite, Cu<sub>3</sub>(AsO<sub>4</sub>)<sub>2</sub>·4H<sub>2</sub>O, a new mineral | first1 = H. | last1 = Sarp | first2 = R. | last2 = Černý | journal = Eur. J. Mineral. | volume = 12 | year = 2000 | pages = 1045–1050 | doi = 10.1127/0935-1221/2000/0012-1045 | url = https://archive-ouverte.unige.ch/unige:86439 }}</ref>


==Related compounds== ==Related compounds==
'''Copper arsenate hydroxide''' or '''basic copper arsenate''' (Cu(OH)AsO<sub>4</sub>) is a basic variant with CAS number {{CASREF|CAS=16102-92-4}}. It is found naturally as the mineral ]. It is used as an insecticide, fungicide, and ]. Its use is banned in Thailand since 2001. '''Copper arsenate hydroxide''' or '''basic copper arsenate''' (Cu(OH)AsO<sub>4</sub>) is a basic variant with CAS number {{CASREF|CAS=16102-92-4}}. It is found naturally as the mineral ]. It is used as an insecticide, fungicide, and ]. Its use is banned in Thailand since 2001.<ref>{{cite web |url=http://www.ipmthailand.org/en/Pesticides/pesticides_banned_abc.htm |title=Banned pesticides (Sorted by common name) |access-date=2006-01-14 |url-status=dead |archive-url=https://web.archive.org/web/20051122181117/http://www.ipmthailand.org/en/Pesticides/pesticides_banned_abc.htm |archive-date=2005-11-22 }}</ref>


==See also== ==See also==
* ] *]
* ] *]
⚫ *]
* ] (copper arsenate-acetate) *] (copper acetoarsenite)
⚫ * ]
* ] (copper arsenite) *] (copper arsenite)

⚫ ==References==
{{Reflist}}


==External links== ==External links==
{{Commons category|Copper(II) arsenate}} {{Commons category}}
* *

⚫ ==References==
{{reflist}}


{{Copper compounds}} {{Copper compounds}}
{{insecticides}} {{Insecticides}}


] ]
] ]
] ]
] ]
] ]
] ]

]
]

Latest revision as of 19:37, 19 January 2024

Not to be confused with Copper arsenite.
Copper(II) arsenate
Names
IUPAC name Copper(II) arsenate
Other names Copper arsenate
Identifiers
CAS Number
3D model (JSmol)
ChemSpider
PubChem CID
UNII
CompTox Dashboard (EPA)
InChI
  • InChI=1S/2AsH3O4.3Cu/c2*2-1(3,4)5;;;/h2*(H3,2,3,4,5);;;/q;;3*+2/p-6Key: RKYSWCFUYJGIQA-UHFFFAOYSA-H
  • InChI=1/2AsH3O4.3Cu/c2*2-1(3,4)5;;;/h2*(H3,2,3,4,5);;;/q;;3*+2/p-6Key: RKYSWCFUYJGIQA-CYFPFDDLAM
SMILES
  • ...()(=O).()()=O
Properties
Chemical formula Cu3(AsO4)2
Molar mass 468.48 g/mol
Appearance blue or bluish green powder
Density 5.2 g/cm
Melting point 1,100 °C (2,010 °F; 1,370 K)
Solubility in water insoluble
Solubility product (Ksp) 7.95×10
Solubility soluble in ammonia, dilute acids
Hazards
NIOSH (US health exposure limits):
PEL (Permissible) TWA 1 mg/m (as Cu)
REL (Recommended) TWA 1 mg/m (as Cu)
IDLH (Immediate danger) TWA 100 mg/m (as Cu)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). checkY verify (what is  ?) Infobox references
Chemical compound

Copper arsenate (Cu3(AsO4)2·4H2O, or Cu5H2(AsO4)4·2H2O), also called copper orthoarsenate, tricopper arsenate, cupric arsenate, or tricopper orthoarsenate, is a blue or bluish-green powder insoluble in water and alcohol and soluble in aqueous ammonium and dilute acids. Its CAS number is 7778-41-8 or 10103-61-4.

Uses

Copper arsenate is an insecticide used in agriculture. It is also used as a herbicide, fungicide, and a rodenticide. It is also used as a poison in slug baits.

Copper arsenate can also be a misnomer for copper arsenite, especially when meant as a pigment.

Natural occurrences

Anhydrous copper arsenate, Cu3(AsO4)2, is found in nature as the mineral lammerite. Copper arsenate tetrahydrate, Cu3(AsO4)2·4H2O, occurs naturally as the mineral rollandite.

Related compounds

Copper arsenate hydroxide or basic copper arsenate (Cu(OH)AsO4) is a basic variant with CAS number 16102-92-4. It is found naturally as the mineral olivenite. It is used as an insecticide, fungicide, and miticide. Its use is banned in Thailand since 2001.

See also

References

  1. John Rumble (June 18, 2018). CRC Handbook of Chemistry and Physics (99 ed.). CRC Press. pp. 5–188. ISBN 978-1138561632.
  2. ^ NIOSH Pocket Guide to Chemical Hazards. "#0150". National Institute for Occupational Safety and Health (NIOSH).
  3. Hawthorne, F. C. (1986). "Lammerite, Cu3(AsO4)2, a modulated close-packed structure" (PDF). American Mineralogist. 71: 206–209.
  4. Sarp, H.; Černý, R. (2000). "Rollandite, Cu3(AsO4)2·4H2O, a new mineral". Eur. J. Mineral. 12: 1045–1050. doi:10.1127/0935-1221/2000/0012-1045.
  5. "Banned pesticides (Sorted by common name)". Archived from the original on 2005-11-22. Retrieved 2006-01-14.

External links

Copper compounds
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Cu(I)
Cu(I,II)
Cu(II)
Cu(III)
Cu(IV)
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