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Revision as of 10:09, 7 November 2011 editBeetstra (talk | contribs)Edit filter managers, Administrators172,031 edits Script assisted update of identifiers for the Chem/Drugbox validation project (updated: 'CASNo').← Previous edit Latest revision as of 02:06, 25 December 2023 edit undo1234qwer1234qwer4 (talk | contribs)Extended confirmed users, Page movers197,942 edits →Applications: links 
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{{no footnotes|date=November 2011}}
{{chembox {{chembox
| Verifiedfields = changed
| Watchedfields = changed
| verifiedrevid = 459434931
| ImageFile = Julolidine.png | ImageFile = Julolidine.png
| ImageFile_Ref = {{Chemboximage|correct|??}} | ImageFile_Ref = {{Chemboximage|correct|??}}
| ImageName = Diagram showing structure of Julolidine | ImageName = Diagram showing structure of julolidine
| PIN = 2,3,6,7-Tetrahydro-1''H'',5''H''-pyridoquinoline
⚫ | Section1 = {{Chembox Identifiers
| OtherNames =
| IUPACName = Julolidine
⚫ |Section1={{Chembox Identifiers
| OtherNames = 2,3,6,7-tetrahydro-1H,5H-benzoquinolizine
| CASNo = <!-- blanked - oldvalue: 479-59-4 --> | CASNo = 479-59-4
| CASNo_Ref = {{cascite|correct|CAS}} | CASNo_Ref = {{cascite|correct|CAS}}
⚫ | UNII_Ref = {{fdacite|correct|FDA}}
⚫ | PubChem = 68069
| UNII = 8ERL3KJ6GQ
⚫ | UNII_Ref = {{fdacite|changed|FDA}}
⚫ | PubChem = 68069
| SMILES = C1CC2=C3C(=CC=C2)CCCN3C1
| ChemSpiderID_Ref = {{chemspidercite|changed|chemspider}}
| ChemSpiderID = 61383
| SMILES = c13c2c(ccc1)CCCN2CCC3
| StdInChI_Ref = {{stdinchicite|changed|chemspider}}
| StdInChI = 1S/C12H15N/c1-4-10-6-2-8-13-9-3-7-11(5-1)12(10)13/h1,4-5H,2-3,6-9H2
| StdInChIKey_Ref = {{stdinchicite|changed|chemspider}}
| StdInChIKey = DZFWNZJKBJOGFQ-UHFFFAOYSA-N
⚫ }}
⚫ |Section2={{Chembox Properties
| C=12 | H=15 | N=1
⚫ | Appearance =
⚫ | Density = 1.003 g/mL
| MeltingPtC = 35
⚫ | BoilingPt =
| RefractIndex = 1.568
⚫ }}
|Section7={{Chembox Hazards
| FlashPtC = 110
}}
}} }}
⚫ | Section2 = {{Chembox Properties
| Formula = C<sub>12</sub>H<sub>15</sub>N


| MolarMass = 173.26 g/mol
⚫ | Appearance =
⚫ | Density = 1.003 g/ml
| MeltingPt = 35 °C
⚫ | BoilingPt =
| Refractive index = 1.568
| Flash point = 110 °C

⚫ }}
⚫ }}
'''Julolidine''' is a ] ] ]. It has the formula C<sub>12</sub>H<sub>15</sub>N. '''Julolidine''' is a ] ] ]. It has the formula C<sub>12</sub>H<sub>15</sub>N.


== Synthesis == == Synthesis ==
⚫ The first synthesis of julolidine was first reported by G. Pinkus in 1892.<ref>Pinkus, G. Ueber die Einwirkung von Trimethylenchlorbromid auf einige aromatische Amine und Amide. ] 1892, 25 (2), 2798–2806</ref>
Synthesized of Julolidine was first reported by
G. Pinkus in 1892.


==Applications== ==Applications==
This compound and its derivatives have found recent This compound and its derivatives have found recent interest as ] materials, ]
⚫ substances, ] substrates in analytical ], dye intermediates, potential antidepressants
interest as photoconductive materials, chemiluminescence
and tranquilizers, ] materials, high sensitivity ] materials, and for improving color stability in photography.
substances, chromogenic substrates in analytical
⚫ redox reactions, dye intermediates, potential antidepressants
and tranquilizers, nonlinear optical materials,
high sensitivity photopolymerizable materials,
and for improving color stability in photography.


==References== ==References==
{{reflist}} {{reflist}}


==External links==
⚫ *Pinkus, G. Ueber die Einwirkung von Trimethylenchlorbromid auf einige aromatische Amine und Amide. ] 1892, 25 (2), 2798–2806.
*Katritzky, A.; Rachwal, B.; Rachwal, S. Convenient Synthesis of Julolidines Using Benzotriazole Methodology. J. Org. Chem. Rachwal 1996, 61, 3117–3126. * {{cite journal | doi = 10.1021/jo9519118| pmid = 11667174| title = Convenient Synthesis of Julolidines Using Benzotriazole Methodology| journal = The Journal of Organic Chemistry| volume = 61| issue = 9| pages = 3117| year = 1996| last1 = Katritzky| first1 = Alan R.| last2 = Rachwal| first2 = Bogumila| last3 = Rachwal| first3 = Stanislaw| last4 = Abboud| first4 = Khalil A.}}


]


]
{{uncategorized|date=November 2011}}
]
]
]

Latest revision as of 02:06, 25 December 2023

Julolidine
Diagram showing structure of julolidine
Names
Preferred IUPAC name 2,3,6,7-Tetrahydro-1H,5H-pyridoquinoline
Identifiers
CAS Number
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.006.851 Edit this at Wikidata
PubChem CID
UNII
CompTox Dashboard (EPA)
InChI
  • InChI=1S/C12H15N/c1-4-10-6-2-8-13-9-3-7-11(5-1)12(10)13/h1,4-5H,2-3,6-9H2Key: DZFWNZJKBJOGFQ-UHFFFAOYSA-N
SMILES
  • c13c2c(ccc1)CCCN2CCC3
Properties
Chemical formula C12H15N
Molar mass 173.259 g·mol
Density 1.003 g/mL
Melting point 35 °C (95 °F; 308 K)
Refractive index (nD) 1.568
Hazards
Flash point 110 °C (230 °F; 383 K)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). ☒N verify (what is  ?) Infobox references
Chemical compound

Julolidine is a heterocyclic aromatic organic compound. It has the formula C12H15N.

Synthesis

The first synthesis of julolidine was first reported by G. Pinkus in 1892.

Applications

This compound and its derivatives have found recent interest as photoconductive materials, chemiluminescence substances, chromogenic substrates in analytical redox reactions, dye intermediates, potential antidepressants and tranquilizers, nonlinear optical materials, high sensitivity photopolymerizable materials, and for improving color stability in photography.

References

  1. Pinkus, G. Ueber die Einwirkung von Trimethylenchlorbromid auf einige aromatische Amine und Amide. Berichte der deutschen chemischen Gesellschaft 1892, 25 (2), 2798–2806

External links

  • Katritzky, Alan R.; Rachwal, Bogumila; Rachwal, Stanislaw; Abboud, Khalil A. (1996). "Convenient Synthesis of Julolidines Using Benzotriazole Methodology". The Journal of Organic Chemistry. 61 (9): 3117. doi:10.1021/jo9519118. PMID 11667174.
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