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'''Tribenzylamine''' is an ] with the formula {{chem2|N(CH2C6H5)3}}. It is a symmetrical ]. It is of some historic interest as one of the first compounds produced by the ]. | '''Tribenzylamine''' is an ] with the formula {{chem2|N(CH2C6H5)3}}. It is a symmetrical ]. It is of some historic interest as one of the first compounds produced by the ].<ref>{{cite journal |doi=10.1002/cber.188501802113 |title=Ueber eine neue Bildungsweise von Tribenzylamin |date=1885 |last1=Leuckart |first1=R. |journal=Berichte der Deutschen Chemischen Gesellschaft |volume=18 |issue=2 |pages=2341–2344 }}</ref> | ||
The compound is a common |
The compound is a common target in the development of new synthetic methods, e.g. from ].<ref>{{cite journal |doi=10.1021/ja807323a |title=Ruthenium-Catalyzed ''N'' -Alkylation of Amines and Sulfonamides Using Borrowing Hydrogen Methodology |date=2009 |last1=Hamid |first1=M. Haniti S. A. |last2=Allen |first2=C. Liana |last3=Lamb |first3=Gareth W. |last4=Maxwell |first4=Aoife C. |last5=Maytum |first5=Hannah C. |last6=Watson |first6=Andrew J. A. |last7=Williams |first7=Jonathan M. J. |journal=Journal of the American Chemical Society |volume=131 |issue=5 |pages=1766–1774 |pmid=19191700 |bibcode=2009JAChS.131.1766H }}</ref><ref>{{cite journal |doi=10.1021/ja107274w |title=Multialkylation of Aqueous Ammonia with Alcohols Catalyzed by Water-Soluble Cp*Ir−Ammine Complexes |date=2010 |last1=Kawahara |first1=Ryoko |last2=Fujita |first2=Ken-Ichi |last3=Yamaguchi |first3=Ryohei |journal=Journal of the American Chemical Society |volume=132 |issue=43 |pages=15108–15111 |pmid=20931960 |bibcode=2010JAChS.13215108K }}</ref> | ||
==References== | ==References== |
Revision as of 01:03, 13 December 2024
Identifiers | |
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CAS Number | |
ECHA InfoCard | 100.009.673 |
CompTox Dashboard (EPA) | |
Properties | |
Chemical formula | C21H21N |
Molar mass | 287.406 g·mol |
Appearance | white solid |
Melting point | 91.5 °C (196.7 °F; 364.6 K) |
Boiling point | 385 °C (725 °F; 658 K) |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). Infobox references |
Tribenzylamine is an organic compound with the formula N(CH2C6H5)3. It is a symmetrical tertiary amine. It is of some historic interest as one of the first compounds produced by the Leuckart reaction.
The compound is a common target in the development of new synthetic methods, e.g. from benzyl alcohol.
References
- Leuckart, R. (1885). "Ueber eine neue Bildungsweise von Tribenzylamin". Berichte der Deutschen Chemischen Gesellschaft. 18 (2): 2341–2344. doi:10.1002/cber.188501802113.
- Hamid, M. Haniti S. A.; Allen, C. Liana; Lamb, Gareth W.; Maxwell, Aoife C.; Maytum, Hannah C.; Watson, Andrew J. A.; Williams, Jonathan M. J. (2009). "Ruthenium-Catalyzed N -Alkylation of Amines and Sulfonamides Using Borrowing Hydrogen Methodology". Journal of the American Chemical Society. 131 (5): 1766–1774. Bibcode:2009JAChS.131.1766H. doi:10.1021/ja807323a. PMID 19191700.
- Kawahara, Ryoko; Fujita, Ken-Ichi; Yamaguchi, Ryohei (2010). "Multialkylation of Aqueous Ammonia with Alcohols Catalyzed by Water-Soluble Cp*Ir−Ammine Complexes". Journal of the American Chemical Society. 132 (43): 15108–15111. Bibcode:2010JAChS.13215108K. doi:10.1021/ja107274w. PMID 20931960.