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{{Other uses|Ochre (disambiguation)}} {{Other uses|Ochre (disambiguation)}}
'''Antimony ochre''' or ''ochre of antimony'' ({{langx|de|аntimonocker}}, {{langx|fr|antimon ochre}}) — a partially obsolete ] for secondary antimony minerals of the ]. Antimony ochres most often have the appearance of a powdery brown-yellow to whitish product of weathering (oxidation) of ] or ]. Usually they are not a pure mineral (one of the ochres), but a mixture of two or more minerals: ], ], ], ], ], sometimes with an admixture of ] or ]. '''Antimony ochre''' (Antimony ocher in ]) or ''ochre of antimony'' ({{langx|de|аntimonocker}}, {{langx|fr|antimon ochre}}) — a partially obsolete ] for secondary antimony minerals of the ]. Antimony ochres most often have the appearance of a powdery brown-yellow to whitish product of weathering (oxidation) of ] or ]. Usually they are not a pure mineral (one of the ochres), but a mixture of two or more minerals: ], ], ], ], ], sometimes with an admixture of ] or ].


In the mineralogical sense of the word, antimony ochres are a loosely defined group of secondary antimony minerals of the oxide and hydroxide class. The most common antimony ochres are ], ], and ],<ref name="kriv">''Krivovichev V. G.'' Mineralogical glossary. Scientific editor ]. — St.Petersburg: St.Petersburg Univ. Publ. House. 2009. — 556 p. — ISBN 978-5-288-04863-0</ref>{{rp|330}} but their number is by no means exhaustive. At various times, this conditional list also included other names, some of which are now recognized as incorrect or non-existent. In the mineralogical sense of the word, antimony ochres are a loosely defined group of secondary ] minerals of the oxide and hydroxide class. The most common antimony ochres are ], ], and ],<ref name="kriv">''Krivovichev V. G.'' Mineralogical glossary. Scientific editor ]. — St.Petersburg: St.Petersburg Univ. Publ. House. 2009. — 556 p. — ISBN 978-5-288-04863-0</ref>{{rp|330}} but their number is by no means exhaustive. At various times, this conditional list also included other names, some of which are now recognized as incorrect or non-existent.


Antimony ochres are associated ore minerals, often more difficult to obtain antimony than the main antimonite, in addition, they are found in nature in small quantities, as an impurity or coating, which is why they are rarely used separately. They received their name by analogy, for their external resemblance to light ]s.<ref name="rober">'']''. A System of Mineralogy. Vol.3: Class IV. Metallic Minerals. — Edinburgh, A. Constable & Co., 1816.</ref>{{rp|489}} Antimony ochres are associated ore minerals, often more difficult to obtain antimony than the main antimonite, in addition, they are found in nature in small quantities, as an impurity or coating, which is why they are rarely used separately. They received their name by analogy, for their external resemblance to light ]s.<ref name="rober">'']''. A System of Mineralogy. Vol.3: Class IV. Metallic Minerals. — Edinburgh, A. Constable & Co., 1816.</ref>{{rp|489}}
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== Essential minerals == == Essential minerals ==
* ]<ref name="wang">''Wang, Chung Yu''. Antimony: its history, chemistry, mineralogy, geology, metallurgy, uses, preparations, analysis, production, and valuation; with complete bibliographies. — London, C. Griffin & company limited, 1909.</ref>{{rp|46}} ({{langx|de|Cervantit}})<ref name="kriv"/>{{rp|330}} or ''white lustrous antimony ore'' — antimony tetroxide with the ideal formula Sb<sub>2</sub>O<sub>4</sub> or, in more detailed form, Sb<sup>3+</sup>Sb<sup>5+</sup>O<sub>4</sub>, an oxidation product of antimonite,<ref name="Dana">''], ]'' A system of mineralogy : Descriptive mineralogy, comprising the most recent discoveries. — New York : J. Wiley & Sons, 1884.</ref>{{rp|188}} along with ] — the lightest of the antimony ochers.<ref name="bull">Bulletin of the United States National Museum. Published under the Direction of the Smitsonian Institution. Washington: Governement Printing Office, No.32, 1887.</ref>{{rp|118}} * ]<ref name="wang">''Wang, Chung Yu''. Antimony: its history, chemistry, mineralogy, geology, metallurgy, uses, preparations, analysis, production, and valuation; with complete bibliographies. — London, C. Griffin & company limited, 1909.</ref>{{rp|46}} ({{langx|de|Cervantit}})<ref name="kriv"/>{{rp|330}} or ''white lustrous antimony ore'' — antimony tetroxide with the ideal formula Sb<sub>2</sub>O<sub>4</sub> or, in more detailed form, Sb<sup>3+</sup>Sb<sup>5+</sup>O<sub>4</sub>, an oxidation product of antimonite,<ref name="Dana">''], ]'' A system of mineralogy : Descriptive mineralogy, comprising the most recent discoveries. — New York : J. Wiley & Sons, 1884.</ref>{{rp|188}} along with ] — the lightest of the antimony ochers.<ref name="bull">Bulletin of the United States National Museum. Published under the Direction of the Smitsonian Institution. Washington: Governement Printing Office, No.32, 1887.</ref>{{rp|118}}
* ]<ref name="bull"/>{{rp|118}} ({{langx|de|Stibiconit}})<ref name="kriv"/>{{rp|330}} or ''kumengite''<ref name="nemrd">''A. A. Nemodruk''. Analytical chemistry of antimony. — Moscow: V. I. Vernadsky Institute of Geochemistry and Analytical Chemistry, Nauka Publishing House, 1978. — 222 p.</ref>{{rp|8}} — a mineral of the ] of variable composition with the conventional formula (Sb<sup>3+</sup>,Ca)<sub>2-x</sub>Sb<sub>2</sub><sup>5+</sup>(O,OH)<sub>6-7</sub>•nH<sub>2</sub>O. The name ''stibiconite'' is very characteristic of all antimony ochres; from the Latin Stibium — antimony and the Greek χονίς (konis) — dust, powder. * ]<ref name="bull"/>{{rp|118}} ({{langx|de|Stibiconit}})<ref name="kriv"/>{{rp|330}} or ''kumengite''<ref name="nemrd">''A. A. Nemodruk''. Analytical chemistry of antimony. — Moscow: V. I. Vernadsky Institute of Geochemistry and Analytical Chemistry, Nauka Publishing House, 1978. — 222 p.</ref>{{rp|8}} — a mineral of the ] of variable composition with the conventional formula (Sb<sup>3+</sup>,Ca)<sub>2-x</sub>Sb<sub>2</sub><sup>5+</sup>(O,OH)<sub>6-7</sub>•nH<sub>2</sub>O. The name ''stibiconite'' is very characteristic of all antimony ochres; from the Latin Stibium — ] and the Greek χονίς (konis) — ], powder.
* ] ({{langx|de|Romeit}})<ref name="kriv"/>{{rp|330}} — a mineral of the oxide class from the ] with the theoretical formula (Ca,Na,Fe,Mn)<sub>2</sub>Sb<sub>2</sub><sup>5+</sup>O<sub>6</sub>(O,OH,F). It is known in five varieties: atopite, schneeberghite, mauseliite, weslinite, lewisite.<ref name="чухро">''], Bonshtedt-Kupletskaya E. M.'' Minerals. Handbook. Issue 3. Complex oxides, titanates, niobates, tantalates, antimonates, hydroxides. — Moscow: Nauka, 1967. — 676 p.</ref> * ] ({{langx|de|Romeit}})<ref name="kriv"/>{{rp|330}} — a mineral of the oxide class from the ] with the theoretical formula (Ca,Na,Fe,Mn)<sub>2</sub>Sb<sub>2</sub><sup>5+</sup>O<sub>6</sub>(O,OH,F). It is known in five varieties: atopite, schneeberghite, mauseliite, weslinite, lewisite.<ref name="чухро">''], Bonshtedt-Kupletskaya E. M.'' Minerals. Handbook. Issue 3. Complex oxides, titanates, niobates, tantalates, antimonates, hydroxides. — Moscow: Nauka, 1967. — 676 p.</ref>
* ] ({{langx|de|Valentinit}})<ref name="solog">''], Z. A. Zinchenko''. Enrichment of antimony ores (ed. by V. A. Glembotsky). — Moscow: Nauka, 1985. — 180 p.</ref> — one of the simplest oxidic antimony ochres, representing ] with the calculated formula Sb<sub>2</sub>O<sub>3</sub>. In antimony ochres it is usually found in a mixture with other antimony oxides. * ] ({{langx|de|Valentinit}})<ref name="solog">''], Z. A. Zinchenko''. Enrichment of antimony ores (ed. by V. A. Glembotsky). — Moscow: Nauka, 1985. — 180 p.</ref> — one of the simplest oxidic antimony ochres, representing ] with the calculated formula Sb<sub>2</sub>O<sub>3</sub>. In antimony ochres it is usually found in a mixture with other antimony oxides.
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<gallery> <gallery>
Cervantite. Baia Sprie, Romania-9099.jpg|{{center|]}} Cervantite. Baia Sprie, Romania-9099.jpg|{{center|]}}
Stibiconite.jpg|{{center|{{center|]}} Stibiconite.jpg|{{center|{{center|]}}
Romeite-290541.jpg|{{center|{{center|]}} Romeite-290541.jpg|{{center|{{center|]}}

Revision as of 13:13, 24 December 2024

Secondary minerals of antimony oxide class
Antimony ochre
Cervantite (Guerrero, Mexico)
General
CategoryMineral
For other uses, see Ochre (disambiguation).

Antimony ochre (Antimony ocher in American English) or ochre of antimony (German: аntimonocker, French: antimon ochre) — a partially obsolete trivial name for secondary antimony minerals of the oxide class. Antimony ochres most often have the appearance of a powdery brown-yellow to whitish product of weathering (oxidation) of antimonite or native antimony. Usually they are not a pure mineral (one of the ochres), but a mixture of two or more minerals: cervantite, valentinite, romeite, senarmontite, stibiconite, sometimes with an admixture of limonite or quartz.

In the mineralogical sense of the word, antimony ochres are a loosely defined group of secondary antimony minerals of the oxide and hydroxide class. The most common antimony ochres are cervantite, romeite, and stibiconite, but their number is by no means exhaustive. At various times, this conditional list also included other names, some of which are now recognized as incorrect or non-existent.

Antimony ochres are associated ore minerals, often more difficult to obtain antimony than the main antimonite, in addition, they are found in nature in small quantities, as an impurity or coating, which is why they are rarely used separately. They received their name by analogy, for their external resemblance to light ochres.

Essential minerals

  • Cervantite (German: Cervantit) or white lustrous antimony ore — antimony tetroxide with the ideal formula Sb2O4 or, in more detailed form, SbSbO4, an oxidation product of antimonite, along with valentinite — the lightest of the antimony ochers.
  • Stibiconite (German: Stibiconit) or kumengite — a mineral of the oxide class of variable composition with the conventional formula (Sb,Ca)2-xSb2(O,OH)6-7•nH2O. The name stibiconite is very characteristic of all antimony ochres; from the Latin Stibium — antimony and the Greek χονίς (konis) — dust, powder.
  • Romeite (German: Romeit) — a mineral of the oxide class from the stibiconite group with the theoretical formula (Ca,Na,Fe,Mn)2Sb2O6(O,OH,F). It is known in five varieties: atopite, schneeberghite, mauseliite, weslinite, lewisite.
  • Valentinite (German: Valentinit) — one of the simplest oxidic antimony ochres, representing antimony oxide with the calculated formula Sb2O3. In antimony ochres it is usually found in a mixture with other antimony oxides.
  • Senarmontite (German: Senarmontit) — a mineral of the same chemical composition as valentinite, less common, differing in syngony and forming rather large octahedral crystals, colorless, transparent, white or gray.
  • Volgerite (obsolete) — a mineral form of antimony acid, identified in the mid-19th century by the German geologist Otto Volger as antimony ochre in the Algerian mines of Constantine Province. It is white or off-white in color., is now recognized as one of the varieties of stibiconite.

Gallery


See also

References

  1. ^ Krivovichev V. G. Mineralogical glossary. Scientific editor A. G. Bulakh. — St.Petersburg: St.Petersburg Univ. Publ. House. 2009. — 556 p. — ISBN 978-5-288-04863-0
  2. Robert Jameson. A System of Mineralogy. Vol.3: Class IV. Metallic Minerals. — Edinburgh, A. Constable & Co., 1816.
  3. Wang, Chung Yu. Antimony: its history, chemistry, mineralogy, geology, metallurgy, uses, preparations, analysis, production, and valuation; with complete bibliographies. — London, C. Griffin & company limited, 1909.
  4. ^ James Dwight Dana A. M., Brush G. J. A system of mineralogy : Descriptive mineralogy, comprising the most recent discoveries. — New York : J. Wiley & Sons, 1884.
  5. ^ Bulletin of the United States National Museum. Published under the Direction of the Smitsonian Institution. Washington: Governement Printing Office, No.32, 1887.
  6. A. A. Nemodruk. Analytical chemistry of antimony. — Moscow: V. I. Vernadsky Institute of Geochemistry and Analytical Chemistry, Nauka Publishing House, 1978. — 222 p.
  7. Chukhrov F. V., Bonshtedt-Kupletskaya E. M. Minerals. Handbook. Issue 3. Complex oxides, titanates, niobates, tantalates, antimonates, hydroxides. — Moscow: Nauka, 1967. — 676 p.
  8. P. M. Solozhenkin, Z. A. Zinchenko. Enrichment of antimony ores (ed. by V. A. Glembotsky). — Moscow: Nauka, 1985. — 180 p.
  9. V. N. Loginov, A. F. Bushmakin, V. I. Kainov and others. Oxides and hydroxides of antimony... Mineralogy of the Urals. Oxides and hydroxides. Part 2. — Ekaterinburg-Miass: Ural Branch of the Russian Academy of Sciences, 2007. — 288 p.
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