Misplaced Pages

Fulvene: Difference between revisions

Article snapshot taken from[REDACTED] with creative commons attribution-sharealike license. Give it a read and then ask your questions in the chat. We can research this topic together.
Browse history interactively← Previous editNext edit →Content deleted Content addedVisualWikitext
Revision as of 07:35, 9 August 2011 editCheMoBot (talk | contribs)Bots141,565 edits Updating {{chembox}} (no changed fields - added verified revid - updated 'DrugBank_Ref', 'UNII_Ref', 'ChEMBL_Ref', 'ChEBI_Ref', 'KEGG_Ref') per Chem/Drugbox validation (report [[Wikipedia_talk:Wi← Previous edit Revision as of 14:09, 21 October 2011 edit undoCitation bot 1 (talk | contribs)Bots130,044 editsm Add: issue. You can use this bot yourself. Report bugs here.Next edit →
Line 68: Line 68:
| pages = 417–432 | pages = 417–432
| year = 2004 | year = 2004
| doi = 10.1070/RC2004v073n05ABEH000842}}</ref> | doi = 10.1070/RC2004v073n05ABEH000842
| issue = 5}}</ref>


==References== ==References==

Revision as of 14:09, 21 October 2011

Fulvene
Names
IUPAC name Fulvene
Other names 5-Methylene-1,3-cyclopentadiene
Identifiers
CAS Number
3D model (JSmol)
ChEBI
ChemSpider
PubChem CID
CompTox Dashboard (EPA)
InChI
  • InChI=1S/C6H6/c1-6-4-2-3-5-6/h2-5H,1H2Key: PGTKVMVZBBZCKQ-UHFFFAOYSA-N
  • InChI=1/C6H6/c1-6-4-2-3-5-6/h2-5H,1H2Key: PGTKVMVZBBZCKQ-UHFFFAOYAV
SMILES
  • C=C1\C=C/C=C1
Properties
Chemical formula C6H6
Molar mass 78.11 g/mol
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). checkY verify (what is  ?) Infobox references
Chemical compound

Fulvene is one of several hydrocarbons with the same formula as benzene, C6H6. Fulvenes include the derivatives of this simple hydrocarbon, which itself is rarely encountered. Thiele is credited with discovering the scope of the reaction between cyclopentadiene and aldehydes and ketones that affords the brightly coloured fulvene derivatives. Most fulvenes are prepared by the reactions starting from cyclopentadiene or sodium cyclopentadienyl.

2,3,4,5-Tetramethylfulvene, abbreviated Me4Fv, is a relatively common ligand in organometallic chemistry. It typically results from the deprotonation of cationic pentamethylcyclopentadienyl complexes.

References

  1. Bergmann, E. D. (1968). "Fulvenes and Substituted Fulvenes". Chemical Reviews. 68: 41–84. doi:10.1021/cr60251a002.
  2. Thiele, J. (1900). "Ueber Ketonreactionen bei dem Cyclopentadiën". Chemische Berichte. 33: 666–673. doi:10.1002/cber.190003301113.
  3. Hafner, K.; Vöpel, K. H.; Ploss, G.; König, C. (1973). "6-(Dimethylamino)fulvene" (PDF). Organic Syntheses Coll. Vol. 5: 431.{{cite journal}}: CS1 maint: multiple names: authors list (link)
  4. Kreindlin, A. Z.; Rybinskaya, M. A. (2004). "Cationic and Neutral Transition Metal Complexes with a Tetramethylfulvene or Trimethylallyldiene Ligand". Russian Chemical Reviews. 73 (5): 417–432. doi:10.1070/RC2004v073n05ABEH000842.{{cite journal}}: CS1 maint: multiple names: authors list (link)
Category:
Fulvene: Difference between revisions Add topic