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| '''Triuret''' is an ] with the formula <sub>2</sub> |
'''Triuret''' is an ] with the formula <sub>2</sub>CO. It is a product from the pyrolysis of ]. Triuret is a colorless, crystalline, hygroscopic solid, slightly soluble in cold water or ether, and more soluble in hot water. | ||
| ==Synthesis== | ==Synthesis== | ||
| It is prepared by heating thin layers of urea, the thin layers facilitating escape of ]: | It is prepared by heating thin layers of urea, the thin layers facilitating escape of ]: | ||
| :3 <sub>2</sub> |
:3 <sub>2</sub>CO + 2 NH<sub>3</sub> | ||
| It can also prepared by treatment of urea with ]:<ref name=Ullmann>{{ Ullmann | authors = C. Nitschke, G. Scherr | title = Urea Derivatives | year = 2012| doi = 10.1002/14356007.o27_o04}}</ref> | It can also prepared by treatment of urea with ]:<ref name=Ullmann>{{ Ullmann | authors = C. Nitschke, G. Scherr | title = Urea Derivatives | year = 2012| doi = 10.1002/14356007.o27_o04}}</ref> | ||
| :2 <sub>2</sub> |
:2 <sub>2</sub>CO + 2 HCl | ||
| Triuret is a complicating by-product in the industrial synthesis of ] from urea. | Triuret is a complicating by-product in the industrial synthesis of ] from urea. | ||
Revision as of 14:37, 19 July 2014
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| Names | |
|---|---|
| Other names
Carbonyldiurea 1,3-Dicarbamylurea Dicarbamylurea Diimidotricarbonic diamide 2,4-diimidotricarbonic diamide Tricarbonodiimidic diamide | |
| Identifiers | |
| CAS Number | |
| ECHA InfoCard | 100.008.317 
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| PubChem CID | |
| CompTox Dashboard (EPA) | |
| Properties | |
| Chemical formula | C3H6N4O3 |
| Molar mass | 146.106 g·mol |
| Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). Infobox references | |
Triuret is an organic compound with the formula 2CO. It is a product from the pyrolysis of urea. Triuret is a colorless, crystalline, hygroscopic solid, slightly soluble in cold water or ether, and more soluble in hot water.
Synthesis
It is prepared by heating thin layers of urea, the thin layers facilitating escape of ammonia:
- 3 2CO + 2 NH3
It can also prepared by treatment of urea with phosgene:
- 2 2CO + 2 HCl
Triuret is a complicating by-product in the industrial synthesis of melamine from urea.
Related compounds
References
- "Urea Derivatives". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. 2012. doi:10.1002/14356007.o27_o04. ISBN 978-3527306732.
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