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'''Tetracyclopropylmethane''' is an ], a ] ] with formula C<sub>13</sub>H<sub>20</sub>, or (C<sub>3</sub>H<sub>5</sub>-)<sub>4</sub>C. The ] skeleton of its molecule consists of four ] rings attached to a central carbon atom. '''Tetracyclopropylmethane''' is an ], a ] ] with formula C<sub>13</sub>H<sub>20</sub>, or (C<sub>3</sub>H<sub>5</sub>-)<sub>4</sub>C. The ] skeleton of its molecule consists of four ] rings attached to a central carbon atom.


This compound was synthesized in 2001 by ] and others, with ] as an intermediate step.<ref>{{cite journal | doi = 10.1002/1521-3773(20010105)40:1<180::AID-ANIE180>3.0.CO;2-K | author = Kozhushkov, Sergei I.; Kostikov, Rafael R.; Molchanov, Alexander P.; Boese, Roland; Benet-Buchholz, Jordi; Schreiner, Peter R.; Rinderspacher, Christopher; Ghiviriga, Ion; De Meijere, Armin. | title = Tetracyclopropylmethane: a unique hydrocarbon with S4 symmetry | journal = Angewandte Chemie, International Edition | year = 2001 | volume = 40 | issue = 1 | pages = 180–183}} </ref> In the solid state, the molecules have a propeller shape with S4 symmetry. This compound was synthesized in 2001 by ] and others, with ] as an intermediate step.<ref>{{cite journal | doi = 10.1002/1521-3773(20010105)40:1<180::AID-ANIE180>3.0.CO;2-K | author = Kozhushkov, Sergei I.; Kostikov, Rafael R.; Molchanov, Alexander P.; Boese, Roland; Benet-Buchholz, Jordi; Schreiner, Peter R.; Rinderspacher, Christopher; Ghiviriga, Ion; De Meijere, Armin. | title = Tetracyclopropylmethane: a unique hydrocarbon with S4 symmetry | journal = Angewandte Chemie International Edition | year = 2001 | volume = 40 | issue = 1 | pages = 180–183}}</ref> In the solid state, the molecules have a propeller shape with S4 symmetry.


==References== ==References==

Revision as of 23:38, 18 February 2016

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Tetracyclopropylmethane
Names
IUPAC name Tetracyclopropylmethane
Identifiers
CAS Number
3D model (JSmol)
CompTox Dashboard (EPA)
SMILES
  • C1(CC1)C(C2CC2)(C3CC3)C4CC4
Properties
Chemical formula C13H20
Molar mass 176.303 g·mol
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). checkY verify (what is  ?) Infobox references
Chemical compound

Tetracyclopropylmethane is an organic compound, a polycyclic hydrocarbon with formula C13H20, or (C3H5-)4C. The carbon skeleton of its molecule consists of four cyclopropane rings attached to a central carbon atom.

This compound was synthesized in 2001 by Armin de Meijere and others, with dicyclopropyldiethenylmethane as an intermediate step. In the solid state, the molecules have a propeller shape with S4 symmetry.

References

  1. Kozhushkov, Sergei I.; Kostikov, Rafael R.; Molchanov, Alexander P.; Boese, Roland; Benet-Buchholz, Jordi; Schreiner, Peter R.; Rinderspacher, Christopher; Ghiviriga, Ion; De Meijere, Armin. (2001). "Tetracyclopropylmethane: a unique hydrocarbon with S4 symmetry". Angewandte Chemie International Edition. 40 (1): 180–183. doi:10.1002/1521-3773(20010105)40:1<180::AID-ANIE180>3.0.CO;2-K.{{cite journal}}: CS1 maint: multiple names: authors list (link)


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