Misplaced Pages

Trimethylolethane trinitrate: Difference between revisions

Article snapshot taken from Wikipedia with creative commons attribution-sharealike license. Give it a read and then ask your questions in the chat. We can research this topic together.
Browse history interactively← Previous editNext edit →Content deleted Content addedVisualWikitext
Revision as of 07:48, 28 September 2009 editGCarty (talk | contribs)Extended confirmed users17,060 edits changing category← Previous edit Revision as of 00:52, 7 November 2010 edit undo66.65.72.111 (talk) This entry still needs grammatical helpNext edit →
Line 30: Line 30:
'''Trimethylolethane trinitrate''' ('''TMETN'''), also known as '''metriol trinitrate''' ('''METN''', '''MTN''', '''METRTN''') or '''nitropentaglycerin''', is a nitro ]. It is a ] similar to ]. It is a transparent oily liquid, colorless to light brown. It is odorless. It is used in some ]s and ]s as a ]. Its chemical formula is CH<sub>3</sub>-C(CH<sub>2</sub>-O-NO<sub>2</sub>)<sub>3</sub>. '''Trimethylolethane trinitrate''' ('''TMETN'''), also known as '''metriol trinitrate''' ('''METN''', '''MTN''', '''METRTN''') or '''nitropentaglycerin''', is a nitro ]. It is a ] similar to ]. It is a transparent oily liquid, colorless to light brown. It is odorless. It is used in some ]s and ]s as a ]. Its chemical formula is CH<sub>3</sub>-C(CH<sub>2</sub>-O-NO<sub>2</sub>)<sub>3</sub>.


TMETN was first prepared and patented in Italy under name '''Metriolo'''. Germans became producing it before WW2 after it proved as an erosion and flash reducing agent in smokeless powders. It is a liquid explosive with properties similar to nitroglycerin but more stable to heat. It is prepared by ] of ] (metriol). It does not induce headaches. TMETN was first prepared and patented in Italy under name '''Metriolo'''. Germans began producing it before WWII when it was demonstrated to be an erosion and flash reducing agent in smokeless powders. It is a liquid explosive with properties similar to nitroglycerin but more stable to heat. It is prepared by ] of ] (metriol). It does not induce headaches.


TMETN can be initiated by friction, impact, and electrostatic discharge. It can be used as a high viscosity plasticizer-binder together with ], but its poor coloiding properties made such use rare; long-term milling can however assist here; success can also be achieved by adding an inert plasticizer and a volatile solvent/colloiding agent. TMETN can be initiated by friction, impact, and electrostatic discharge. It can be used as a high viscosity plasticizer-binder together with ], but its poor coloiding properties made such use rare; long-term milling can however assist here; success can also be achieved by adding an inert plasticizer and a volatile solvent/colloiding agent.

Revision as of 00:52, 7 November 2010

Trimethylolethane trinitrate
Names
IUPAC name nitrate
Other names TMETN; Metriol trinitrate; METN; Nitropentaglycerin; 1,1,1-trimethylolethane trinitrate
Identifiers
CAS Number
3D model (JSmol)
ECHA InfoCard 100.019.287 Edit this at Wikidata
CompTox Dashboard (EPA)
SMILES
  • CC(CO()=O)(CO()=O)CO()=O
Properties
Chemical formula C5H9N3O9
Molar mass 255.14
Density 1.47 g/cm
Melting point -3 °C
Boiling point decomposes at 182 °C
Hazards
Flash point 26.7 °C
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). Infobox references
Chemical compound

Trimethylolethane trinitrate (TMETN), also known as metriol trinitrate (METN, MTN, METRTN) or nitropentaglycerin, is a nitro ester. It is a high explosive similar to nitroglycerin. It is a transparent oily liquid, colorless to light brown. It is odorless. It is used in some solid propellants and smokeless powders as a plasticizer. Its chemical formula is CH3-C(CH2-O-NO2)3.

TMETN was first prepared and patented in Italy under name Metriolo. Germans began producing it before WWII when it was demonstrated to be an erosion and flash reducing agent in smokeless powders. It is a liquid explosive with properties similar to nitroglycerin but more stable to heat. It is prepared by nitration of trimethylolethane (metriol). It does not induce headaches.

TMETN can be initiated by friction, impact, and electrostatic discharge. It can be used as a high viscosity plasticizer-binder together with nitrocellulose, but its poor coloiding properties made such use rare; long-term milling can however assist here; success can also be achieved by adding an inert plasticizer and a volatile solvent/colloiding agent.

TMETN is miscible with ether and acetone. It is insoluble in 95% sulfuric acid.

TMETN can be used as a plasticizer together, or as an alternative to, triethyleneglycol dinitrate (TEGDN).

TMETN can also be used as a monopropellant.

Triethylene glycol dinitrate, diethylene glycol dinitrate, and trimethyloleate trinitrate are being considered as replacements for nitroglycerin in propellants.

References

External links

Categories: