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| verifiedrevid = 407872079 | verifiedrevid = 407872079
| ImageFile = Tetracyclopropylmethane.svg | ImageFile = Tetracyclopropylmethane.svg
| ImageSize = 150px | ImageSize = 150px
| ImageAlt = | ImageAlt =
| IUPACName = Tetracyclopropylmethane | IUPACName = Tetracyclopropylmethane
| OtherNames = | OtherNames =
| Section1 = {{Chembox Identifiers |Section1={{Chembox Identifiers
| CASNo = 332104-93-5 | CASNo = 332104-93-5
| CASNo_Ref = {{cascite|correct|CAS}} | CASNo_Ref = {{cascite|correct|CAS}}
| PubChem = | PubChem =
| SMILES = C1(CC1)C(C2CC2)(C3CC3)C4CC4}} | SMILES = C1(CC1)C(C2CC2)(C3CC3)C4CC4}}
| Section2 = {{Chembox Properties |Section2={{Chembox Properties
| C=13 | H=20 | C=13 | H=20
| Appearance = | Appearance =
| Density = | Density =
| MeltingPt = | MeltingPt =
| BoilingPt = | BoilingPt =
| Solubility = }} | Solubility = }}
| Section3 = {{Chembox Hazards |Section3={{Chembox Hazards
| MainHazards = | MainHazards =
| FlashPt = | FlashPt =
| Autoignition = }} | AutoignitionPt = }}
}} }}



Revision as of 18:41, 7 July 2015

Tetracyclopropylmethane
Names
IUPAC name Tetracyclopropylmethane
Identifiers
CAS Number
3D model (JSmol)
CompTox Dashboard (EPA)
SMILES
  • C1(CC1)C(C2CC2)(C3CC3)C4CC4
Properties
Chemical formula C13H20
Molar mass 176.303 g·mol
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). checkverify (what is  ?) Infobox references
Chemical compound

Tetracyclopropylmethane is an organic compound, a polycyclic hydrocarbon with formula C13H20, or (C3H5-)4C. The carbon skeleton of its molecule consists of four cyclopropane rings attached to a central carbon atom.

This compound was synthesized in 2001 by Armin de Meijere and others, with dicyclopropyldiethenylmethane as an intermediate step. In the solid state, the molecules have a propeller shape with S4 symmetry.

References

  1. Kozhushkov, Sergei I.; Kostikov, Rafael R.; Molchanov, Alexander P.; Boese, Roland; Benet-Buchholz, Jordi; Schreiner, Peter R.; Rinderspacher, Christopher; Ghiviriga, Ion; De Meijere, Armin. (2001). "Tetracyclopropylmethane: a unique hydrocarbon with S4 symmetry". Angewandte Chemie, International Edition. 40 (1): 180–183. doi:10.1002/1521-3773(20010105)40:1<180::AID-ANIE180>3.0.CO;2-K.{{cite journal}}: CS1 maint: multiple names: authors list (link)


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