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Isopropyl iodide

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Isopropyl iodide
Names
IUPAC name 2-iodopropane
Other names iododimethylmethane, isopropyl iodide, 2-propyliodide, sec-propyl iodide
Identifiers
CAS Number
3D model (JSmol)
ECHA InfoCard 100.000.782 Edit this at Wikidata
RTECS number
  • TZ4200000
CompTox Dashboard (EPA)
SMILES
  • CC(I)C
Properties
Chemical formula C3H7I
Molar mass 169.99
Appearance Colourless liquid
Density 1.703
Melting point −90.0 °C (−130.0 °F; 183.2 K)
Boiling point 89.5 °C (193.1 °F; 362.6 K)
Solubility in water 0.14 g/100 ml at 12.5 °C
Solubility in ethanol fully miscible
Solubility in diethyl ether fully miscible
Solubility in chloroform fully miscible
Solubility in benzene fully miscible
Refractive index (nD) 1.4997
Viscosity 8.841 cP at 0 °C
6.971 cP at 20 °C
Hazards
Occupational safety and health (OHS/OSH):
Main hazards Possible carcinogen. Harmful if swallowed, inhaled and in contact with skin. Eye, respiratory and mucous membrane irritant.
Flash point 42 °C
Related compounds
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). checkverify (what is  ?) Infobox references
Chemical compound

Isopropyl iodide is the organoiodine compound with the formula (CH3)2CHI. It is colorless, flammable, and volatile. Organic iodides are light-sensitive and take on a yellow colour upon storage, owing to the formation of iodine.

Preparation

Isopropyl iodide is prepared by iodination of isopropyl alcohol using hydrogen iodide or, equivalently, with a mixture of glycerol, iodine, and phosphorus. An alternative preparation involves the reaction of 2-propyl bromide with an acetone solution of potassium iodide (KI):

(CH3)2CHBr + KI → (CH3)2CHI + KBr

References

  1. Merck Index of Chemicals and Drugs, 9th ed., monograph 5074
  2. Textbook of Practical Organic Chemistry, 5th Edition, Prentice Hall, 1989


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