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Revision as of 19:10, 17 April 2024 by Trasheater Midir (talk | contribs) (→top)(diff) ← Previous revision | Latest revision (diff) | Newer revision → (diff) "KHPh" redirects here. For the radio station KHPH in Hawaii, see List of radio stations in Hawaii. "KHP" redirects here. For other uses, see KHP (disambiguation).
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Names | |||
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Preferred IUPAC name Potassium 2-carboxybenzoate | |||
Other names
hydrogen potassium phthalate; phthalic acid potassium salt; potassium biphthalate; potassium acid phthalate; 1,2-benzenedicarboxylic acid, monopotassium salt; KHP; KHPh | |||
Identifiers | |||
CAS Number | |||
3D model (JSmol) | |||
ChEMBL | |||
ChemSpider | |||
ECHA InfoCard | 100.011.718 | ||
EC Number |
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PubChem CID | |||
UNII | |||
CompTox Dashboard (EPA) | |||
InChI
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SMILES
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Properties | |||
Chemical formula | C8H5KO4 | ||
Molar mass | 204.222 g·mol | ||
Appearance | White or colorless solid | ||
Density | 1.636 g/cm | ||
Melting point | ~295 °C (decomposes) | ||
Solubility in water | 80 g/L (20 °C) | ||
Solubility | slightly soluble in alcohol | ||
Acidity (pKa) | 5.4 | ||
Structure | |||
Coordination geometry | tetrahedral | ||
Hazards | |||
Occupational safety and health (OHS/OSH): | |||
Main hazards | Irritant to eyes, skin, and respiratory system | ||
GHS labelling: | |||
Pictograms | |||
Signal word | Warning | ||
Hazard statements | H315, H319, H335 | ||
Flash point | Non-flammable | ||
Safety data sheet (SDS) | External MSDS | ||
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). Y verify (what is ?) Infobox references |
Potassium hydrogen phthalate, often called simply KHP, is an acidic salt compound. It forms white powder, colorless crystals, a colorless solution, and an ionic solid that is the monopotassium salt of phthalic acid. KHP is slightly acidic, and it is often used as a primary standard for acid–base titrations because it is solid and air-stable, making it easy to weigh accurately. It is not hygroscopic. It is also used as a primary standard for calibrating pH meters because, besides the properties just mentioned, its pH in solution is very stable. It also serves as a thermal standard in thermogravimetric analysis.
KHP dissociates completely in water, giving the potassium cation (K) and hydrogen phthalate anion (HP or Hphthalate)
- KHP K + HP
and then, acting as a weak acid, hydrogen phthalate reacts reversibly with water to give hydronium (H3O) and phthalate ions.
- HP + H2O ⇌ P + H3O
KHP can be used as a buffering agent in combination with hydrochloric acid (HCl) or sodium hydroxide (NaOH). The buffering region is dependent upon the pKa, and is typically +/- 1.0 pH units of the pKa. The pKa of KHP is 5.4, so its pH buffering range would be 4.4 to 6.4; however, due to the presence of the second acidic group that bears the potassium ion, the first pKa also contributes to the buffering range well below pH 4.0, which is why KHP is a good choice for use as a reference standard for pH 4.00.
KHP is also a useful standard for total organic carbon (TOC) testing. Most TOC analyzers are based on the oxidation of organics to carbon dioxide and water, with subsequent quantitation of the carbon dioxide. Many TOC analysts suggest testing their instruments with two standards: one typically easy for the instrument to oxidize (KHP), and one more difficult to oxidize. For the latter, benzoquinone is suggested.
References
- "104874 | Potassium hydrogen phthalate". Archived from the original on 2014-08-21.
- "Lincoln Public Schools" (PDF).
- "C&L Inventory". echa.europa.eu.
- Hendrixson, W. S. (1920). "Further Work on Potassium Hydrogen Phthalate as a Standard in Volumetric Analysis". J Am Chem Soc. 42 (4): 724–727. doi:10.1021/ja01449a008.
- "Potassium Hydrogen Phthalate". Arlington, TX: Ricca Chemical Company. Archived from the original on 2012-11-30. Retrieved 2012-10-03.
- "The Standardization Of NaOH and KHP Assay" (PDF). Clark College. Archived from the original (PDF) on 2012-11-19. Retrieved 2012-10-03.
- Smalley, I.J.; Lill, G.O.; Bentley, S.P.; Wood, D.R. (1977). "Thermogravimetry of potassium hydrogen phthalate and its use as a thermal standard". Canadian Mineralogist. 15 (1): 30–35.
- "pH Metrology". Projects/Programs. National Institute of Standards and Technology. Retrieved 4 August 2022.
- Buck, R.P.; Rondinini, S.; Baucke, F.G.K.; Brett, C.M.A.; Camoes, M.F.; Covington, A.K.; Milton, M.J.T.; Mussini, T.; Naumann, R.; Pratt, K.W.; Spitzer, P.; Wilson, G.S. (2002). "Measurement of pH. Definition, Standards, and Procedures; IUPAC Recommendation" (PDF). Pure Appl. Chem. 74: 2169–2200. doi:10.1351/pac200274112169. hdl:2434/195966. S2CID 96759529. Retrieved 4 August 2022.