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1,1,1,3,3,3-Hexafluoropropane

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1,1,1,3,3,3-Hexafluoropropane
Names
IUPAC name 1,1,1,3,3,3-hexafluoropropane
Other names FE-36; FE 36; HFC-236fa; FC-236fa; CCO610;HCFC 236fa; R 236fa; 2,2-dihydroperfluoropropane; bistrifluoromethylmethane
Identifiers
CAS Number
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.130.489 Edit this at Wikidata
EC Number
  • 425-320-1
RTECS number
  • TZ4043332
CompTox Dashboard (EPA)
InChI
  • InChI=1S/C3H2F6/c4-2(5,6)1-3(7,8)9/h1H2Key: NSGXIBWMJZWTPY-UHFFFAOYSA-N
  • InChI=1/C3H2F6/c4-2(5,6)1-3(7,8)9/h1H2Key: NSGXIBWMJZWTPY-UHFFFAOYAC
SMILES
  • FC(F)(F)CC(F)(F)F
Properties
Chemical formula C3H2F6
Molar mass 152.039 g·mol
Appearance Colorless gas
Melting point -98.0 to -93.6 °C
Boiling point -1.4 to -0.7 °C
Solubility in water 724 mg/l
Vapor pressure 270 kPa at 25 °C
Henry's law
constant
 (kH)
mol.kg.bar
Hazards
Occupational safety and health (OHS/OSH):
Main hazards asphyxiant
Flash point Non-flammable
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). checkverify (what is  ?) Infobox references
Chemical compound

1,1,1,3,3,3-Hexafluoropropane is an organic chemical, an organofluoride. It is a colorless gas, usually available in the form of a liquid gas. It is used as a fire suppression agent, a foaming agent, a highly effective refrigerant, a heat transfer medium, a dielectric gas, a sterilant carrier, a polymerization medium, a carrier fluid, a displacement drying agent, a thermodynamic power cycle working fluid, etc.

When used as a fire suppressant, hexafluoropropane carries the DuPont trade name, FE-36.

1,1,1,3,3,3-Hexafluoropropane is a greenhouse gas; its global warming potential is 6300.

It is manufactured by reacting 1,1,1,3,3,3-hexachloropropane with hydrogen fluoride in gas phase at temperature between 250-400 °C, in presence of a catalyst in the form of trivalent chromium (e.g. chromium(III) chloride) supported on carbon with low content of specific impurities.

References

  1. http://www.matheson-trigas.com/pdfs/msds/00226046.pdf
  2. http://www.sumobrain.com/patents/wipo/Process-manufacture-111333-hexafluoropropane/WO1996017812.html
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