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IUPAC name 2-iodopropane | |
Other names iododimethylmethane, isopropyl iodide, 2-propyliodide, sec-propyl iodide | |
Identifiers | |
CAS Number | |
3D model (JSmol) | |
ECHA InfoCard | 100.000.782 |
RTECS number |
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CompTox Dashboard (EPA) | |
SMILES
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Properties | |
Chemical formula | C3H7I |
Molar mass | 169.99 |
Appearance | Colourless liquid |
Density | 1.703 |
Melting point | −90.0 °C (−130.0 °F; 183.2 K) |
Boiling point | 89.5 °C (193.1 °F; 362.6 K) |
Solubility in water | 0.14 g/100 ml at 12.5 °C |
Solubility in ethanol | fully miscible |
Solubility in diethyl ether | fully miscible |
Solubility in chloroform | fully miscible |
Solubility in benzene | fully miscible |
Refractive index (nD) | 1.4997 |
Viscosity | 8.841 cP at 0 °C 6.971 cP at 20 °C |
Hazards | |
Occupational safety and health (OHS/OSH): | |
Main hazards | Possible carcinogen. Harmful if swallowed, inhaled and in contact with skin. Eye, respiratory and mucous membrane irritant. |
Flash point | 42 °C |
Related compounds | |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). Y verify (what is ?) Infobox references |
Isopropyl iodide is the organoiodine compound with the formula (CH3)2CHI. It is colorless, flammable, and volatile. Organic iodides are light-sensitive and take on a yellow colour upon storage, owing to the formation of iodine.
Preparation
Isopropyl iodide is prepared by iodination of isopropyl alcohol using hydrogen iodide or, equivalently, with a mixture of glycerol, iodine, and phosphorus. An alternative preparation involves the reaction of 2-propyl bromide with an acetone solution of potassium iodide (KI):
- (CH3)2CHBr + KI → (CH3)2CHI + KBr
References
- Merck Index of Chemicals and Drugs, 9th ed., monograph 5074
- Textbook of Practical Organic Chemistry, 5th Edition, Prentice Hall, 1989
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