| Revision as of 16:37, 16 February 2012 editBeetstra (talk | contribs)Edit filter managers, Administrators172,031 edits Saving copy of the {{chembox}} taken from revid 431363576 of page 1-Chlorobutane for the Chem/Drugbox validation project (updated: ''). |
Latest revision as of 08:43, 12 August 2023 edit OAbot (talk | contribs)Bots440,440 editsm Open access bot: doi added to citation with #oabot. |
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{{ambox | text = This page contains a copy of the infobox ({{tl|chembox}}) taken from revid of page ] with values updated to verified values.}} |
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{{chembox |
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{{chembox |
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| Watchedfields = changed |
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| verifiedrevid = 413091747 |
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| verifiedrevid = 477207412 |
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| ImageFile = 1-Chlorobutane.png |
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| ImageFile = 1-Chlorobutane.svg |
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| ImageSize = 180px |
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| ImageSize = 200px |
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| ImageName = Skeltal formula |
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| ImageName = Skeltal formula |
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| ImageFile1 = 1-chlorobutane-3D-balls.png |
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| ImageFile1 = 1-chlorobutane-3D-balls.png |
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| ImageName1 = Ball-and-stick model |
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| ImageName1 = Ball-and-stick model |
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| PIN = 1-Chlorobutane |
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| IUPACName = 1-chlorobutane, N-Butyl chloride |
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| OtherNames = |
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| OtherNames = ''n''-Butyl chloride |
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|Section1={{Chembox Identifiers |
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|Section1={{Chembox Identifiers |
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| UNII_Ref = {{fdacite|correct|FDA}} |
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| UNII_Ref = {{fdacite|correct|FDA}} |
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| CASNo=109-69-3 |
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| CASNo=109-69-3 |
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| PubChem=8005 |
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| PubChem=8005 |
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| EC_number = 203-696-6 |
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| RTECS = EJ6300000 |
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| UNNumber = 1127 |
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| DrugBank = DB11534 |
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| SMILES = ClCCCC |
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| SMILES = ClCCCC |
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| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} |
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| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} |
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| ChemSpiderID=7714 |
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| ChemSpiderID=7714 |
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}} |
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|Section2={{Chembox Properties |
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|Section2={{Chembox Properties|Solvent = |
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| C = 4 | H = 9 | Cl = 1 |
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| C=4 | H=9 | Cl=1 |
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| Appearance= Colorless liquid<ref name=GESTIS>{{GESTIS|ZVG=26510}}</ref> |
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| Appearance= |
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| Density=.88 g/mL |
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| Density= 0.89 g/mL |
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| MeltingPt= -123 C |
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| MeltingPtC= -123.1 |
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| MeltingPt_ref = <ref name=GESTIS/> |
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| BoilingPt= 79 C |
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| BoilingPtC= 78 |
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| Solubility= |
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| BoilingPt_ref = <ref name=GESTIS/> |
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| Solubility=0.5 g/L (20 °C)<ref name=GESTIS/> |
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| SolubleOther = Miscible with ], ether{{citation needed|date=November 2012}} |
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| LogP = 2.56<ref name="chemsrc">{{Cite web|url=https://www.chemsrc.com/en/cas/109-69-3_343510.html|title=1-Chlorobutane CAS#:109-69-3}}</ref> |
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| RefractIndex = 1.396<ref name="chemsrc">{{Cite web|url=https://www.chemsrc.com/en/cas/109-69-3_343510.html|title=1-Chlorobutane CAS#:109-69-3}}</ref> |
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| VaporPressure = 103.4±0.1 mmHg at 25°C<ref name="chemsrc">{{Cite web|url=https://www.chemsrc.com/en/cas/109-69-3_343510.html|title=1-Chlorobutane CAS#:109-69-3}}</ref> |
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| MagSus = -67.10·10<sup>−6</sup> cm<sup>3</sup>/mol |
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| Viscosity = 0.4261 mPa·s<ref name="CourseyHeric1971">{{cite journal|last1=Coursey|first1=B. M.|last2=Heric|first2=E. L.|title=AApplication of the Congruence Principle to Viscosities of 1-Chloroalkane Binary Mixtures|journal=Canadian Journal of Chemistry|volume=49|issue=16|year=1971|pages=2631–2635|issn=0008-4042|doi=10.1139/v71-437|doi-access=free}}</ref> |
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|Section3={{Chembox Hazards |
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|Section3={{Chembox Hazards |
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| ExternalMSDS = |
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| ExternalSDS = |
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| GHSPictograms = {{GHS02}} |
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| EUClass = Highly flammable |
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| GHSSignalWord = Danger |
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| FlashPt= |
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| HPhrases = {{H-phrases|225}} |
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| Autoignition= |
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| PPhrases = {{P-phrases|210|233|240|241|242|243|280|303+361+353|370+378|403+235|501}} |
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| NFPA-H = 1 |
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| NFPA-F = 3 |
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| FlashPtC = -12 |
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| FlashPt_ref = <ref name=GESTIS/> |
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| NFPA-R = 1 |
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| AutoignitionPt = |
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| NFPA-H = 1 |
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| NFPA-F = 3 |
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| NFPA-R = 1 |
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'''1-Chlorobutane''' is an ] with the chemical formula CH<sub>3</sub>(CH<sub>2</sub>)<sub>3</sub>Cl. It is a colorless, flammable liquid. |
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==Preparation and reactions== |
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It can be prepared from ] by treatment with ].<ref>{{cite journal|doi= 10.15227/orgsyn.005.0027|title= N-Butyl Chloride|journal= Organic Syntheses|volume= 5|pages= 27|year= 1925|first1=J. E.|last1= Copenhaver|first2= A. M.|last2=Whaley}}</ref> |
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It reacts with ] metal to give ]:<ref name=Brandsma>{{cite book |author1=Brandsma, L. |author2=Verkraijsse, H. D. | title = Preparative Polar Organometallic Chemistry I | publisher = ] | location = Berlin | year = 1987 | isbn = 3-540-16916-4}}</ref> |
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: 2 Li + CH<sub>3</sub>(CH<sub>2</sub>)<sub>3</sub>Cl → CH<sub>3</sub>(CH<sub>2</sub>)<sub>3</sub>Li + ] |
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==References== |
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{{reflist}} |
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{{DEFAULTSORT:Chlorobutane1}} |
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] |
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{{organohalide-stub}} |