Revision as of 17:16, 16 February 2012 editBeetstra (talk | contribs)Edit filter managers, Administrators172,031 edits Saving copy of the {{chembox}} taken from revid 444962246 of page 2-Chlorophenol for the Chem/Drugbox validation project (updated: ''). |
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{{ambox | text = This page contains a copy of the infobox ({{tl|chembox}}) taken from revid of page ] with values updated to verified values.}} |
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{{chembox |
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{{chembox |
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| verifiedrevid = 444961058 |
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| verifiedrevid = 477213052 |
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| Name = 2-Chlorophenol |
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| Name = 3-Chlorophenol |
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| ImageFile = 3-Chlorphenol.svg |
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| Reference = <ref name="hand"> |
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| ImageName = 3-Chlorophenol |
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{{Citation |
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| last = Lide |
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| ImageSize = 120px |
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| PIN = 3-Chlorophenol<ref name=iupac2013>{{cite book | title = Nomenclature of Organic Chemistry : IUPAC Recommendations and Preferred Names 2013 (Blue Book) | publisher = ] | date = 2014 | location = Cambridge | page = 690 | doi = 10.1039/9781849733069-FP001 | isbn = 978-0-85404-182-4 | quote = Only one name is retained, phenol, for C<sub>6</sub>H<sub>5</sub>-OH, both as a preferred name and for general nomenclature. The structure is substitutable at any position. Locants 2, 3, and 4 are recommended, not ''o'', ''m'', and ''p''.}}</ref> |
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| first = David R. |
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| OtherNames = ''m''-Chlorophenol <br />''meta''-Chlorophenol <br />3-Hydroxychlorobenzene |
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| author-link = |
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|Section1={{Chembox Identifiers |
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| last2 = |
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| first2 = |
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| CASNo = 108-43-0 |
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| CASNo_Ref = {{cascite|correct|CAS}} |
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| author2-link = |
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| UNII_Ref = {{fdacite|correct|FDA}} |
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| publication-date = |
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| UNII = Z2Z7M2FTAD |
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| date = |
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| ChEBI_Ref = {{ebicite|correct|EBI}} |
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| year = 1998 |
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| ChEBI = |
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| title = Handbook of Chemistry and Physics |
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| edition = 87 |
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| volume = |
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| series = |
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| publication-place = Boca Raton, FL |
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| publisher = CRC Press |
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| id = |
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| isbn = 0-8493-0594-2 |
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| doi = |
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| oclc = |
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| pages = 3–120 |
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| url = |
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| postscript = <!--none--> |
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}}</ref><ref name="hand2"> |
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{{Citation |
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| last = Lide |
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| first = David R. |
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| author-link = |
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| first2 = |
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| author2-link = |
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| publication-date = |
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| date = |
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| year = 1998 |
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| title = Handbook of Chemistry and Physics |
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| edition = 87 |
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| volume = |
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| publication-place = Boca Raton, FL |
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| publisher = CRC Press |
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| id = |
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| isbn = 0-8493-0594-2 |
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| pages = 1281 |
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| postscript = <!--none--> |
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}}</ref><ref name="hand3"> |
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{{Citation |
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| last = Lide |
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| first = David R. |
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| author-link = |
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| last2 = |
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| first2 = |
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| author2-link = |
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| publication-date = |
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| date = |
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| year = 1998 |
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| title = Handbook of Chemistry and Physics |
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| edition = 87 |
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| volume = |
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| series = |
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| publication-place = Boca Raton, FL |
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| place = |
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| publisher = CRC Press |
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| id = |
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| isbn = 0-8493-0594-2 |
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| pages = 8–103 |
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| postscript = <!--none--> |
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}}</ref><ref name="hand4"> |
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{{Citation |
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| last = Lide |
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| first = David R. |
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| author-link = |
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| last2 = |
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| first2 = |
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| author2-link = |
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| publication-date = |
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| date = |
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| year = 1998 |
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| title = Handbook of Chemistry and Physics |
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| edition = 87 |
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| volume = |
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| series = |
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| publication-place = Boca Raton, FL |
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| place = |
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| publisher = CRC Press |
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| id = |
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| isbn = 0-8493-0594-2 |
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| doi = |
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| oclc = |
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| pages = 15–18 |
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| url = |
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| accessdate = |
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| postscript = <!--none--> |
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}}</ref> |
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| ImageFileL1 = 2-Chlorphenol.svg |
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| ImageSizeL1 = 120px |
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| ImageNameL1 = 2-Chlorophenol |
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| ImageFileR1 = 2-chlorophenol.png |
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| ImageSizeR1 = 120px |
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| ImageNameR1 = 2-Chlorophenol |
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| IUPACName = 2-Chlorophenol |
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| OtherNames = 2-Hydroxychlorobenzene, ''o''-Chlorophenol |
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| Section1 = {{Chembox Identifiers |
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| ChEBI_Ref = {{ebicite|correct|EBI}} |
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| ChEBI = 47083 |
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| DrugBank_Ref = {{drugbankcite|correct|drugbank}} |
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| DrugBank_Ref = {{drugbankcite|correct|drugbank}} |
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| DrugBank = DB03110 |
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| DrugBank = |
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| SMILES = Oc1ccccc1Cl |
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| SMILES = C1=CC(=CC(=C1)Cl)O |
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| KEGG_Ref = {{keggcite|correct|kegg}} |
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| KEGG_Ref = {{keggcite|correct|kegg}} |
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| KEGG = C14219 |
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| KEGG = |
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| InChI = 1/C6H5ClO/c7-5-3-1-2-4-6(5)8/h1-4,8H |
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| InChI = 1S/C6H5ClO/c7-5-2-1-3-6(8)4-5/h1-4,8H |
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| InChIKey = ISPYQTSUDJAMAB-UHFFFAOYAM |
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| InChIKey = HORNXRXVQWOLPJ-UHFFFAOYSA-N |
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| ChEMBL_Ref = {{ebicite|correct|EBI}} |
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| ChEMBL_Ref = {{ebicite|correct|EBI}} |
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| ChEMBL = 108877 |
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| ChEMBL = |
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| StdInChI_Ref = {{stdinchicite|correct|chemspider}} |
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| StdInChI_Ref = {{stdinchicite|correct|chemspider}} |
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| StdInChI = 1S/C6H5ClO/c7-5-3-1-2-4-6(5)8/h1-4,8H |
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| StdInChI = |
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| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}} |
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| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}} |
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| StdInChIKey = ISPYQTSUDJAMAB-UHFFFAOYSA-N |
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| StdInChIKey = |
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| CASNo_Ref = {{cascite|correct|CAS}} |
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| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} |
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| CASNo = 95-57-8 |
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| ChemSpiderID = 13875432 |
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| CASNo_valid = yes |
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| PubChem = 7933 |
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| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} |
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| ChemSpiderID = 13837686 |
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}} |
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}} |
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| Section2 = {{Chembox Properties |
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|Section2={{Chembox Properties |
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| C=6 | H=5 | Cl=1 | O=1 |
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| Formula = C<sub>6</sub>H<sub>5</sub>ClO |
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| Appearance = Colorless or white oily solid |
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| MolarMass = 128.56 g/mol |
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| Density = 1.245 g/cm<sup>3</sup> at 45 °C<ref name=crc/> |
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| Appearance = Light amber, liquid |
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| Density = 1.2634 g/cm<sup>3</sup> at 20 °C |
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| Solubility = 20 g/L at 20 °C |
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| SolubleOther = Soluble in ], ], ] |
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| Solubility = 20 g/L at 20 °C |
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| Solvent = other solvents |
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| SolubleOther = soluble in ], ], ] |
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| MeltingPt = 9.4 °C |
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| MeltingPtC = 32.5 |
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| MeltingPt_ref =<ref name=crc>Haynes, p. 3.116</ref> |
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| BoilingPt = 174.9 °C |
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| pKa = 8.56 |
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| BoilingPtC = 210 |
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| BoilingPt_ref =<ref name=crc/> |
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| VaporPressure = 0.308 kPa |
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| RefractIndex = 1.5565<ref name=crc/> |
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| pKa = 9.12<ref>Haynes, p. 5.90</ref> |
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| MagSus = -77.6·10<sup>−6</sup> cm<sup>3</sup>/mol<ref>Haynes, p. 3.577</ref> |
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}} |
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}} |
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| Section4 = {{Chembox Thermochemistry |
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|Section4={{Chembox Thermochemistry |
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| Thermochemistry_ref=<ref>Haynes, pp. 5.10, 6.156</ref> |
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| DeltaHf = |
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| DeltaHf = -206.4 kJ·mol<sup>−1</sup> (s)<br> −189.3 kJ·mol<sup>−1</sup> (l) |
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| DeltaHc = |
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| DeltaHc = |
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| Entropy = |
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| Entropy = |
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| HeatCapacity = 1.468 J·g<sup>-1</sup>·K<sup>-1</sup> |
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| HeatCapacity = |
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| DeltaHfus = 14.9 kJ·mol<sup>−1</sup> |
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}} |
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}} |
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| Section7 = {{Chembox Hazards |
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|Section7={{Chembox Hazards |
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| ExternalSDS = |
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| Autoignition = 550 °C |
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| MainHazards = Corrosive – causes burns |
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| ExternalMSDS = |
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| FlashPtC = 120 |
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| MainHazards = Corrosive - causes burns |
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| AutoignitionPtC = 550 |
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| FlashPt = 64°C |
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}} |
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}} |
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| Section8 = {{Chembox Related |
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|Section8={{Chembox Related |
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| Function = ] |
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| OtherFunction_label = ] |
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| OtherFunctn = ]<br />]<br />] |
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| OtherFunction = ]<br />]<br />] |
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}} |
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}} |
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}} |
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}} |
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'''3-Chlorophenol''' is an ] with the molecular formula C<sub>6</sub>H<sub>4</sub>ClOH. It is one of three ]s of mono]. It is a colorless or white solid that melts easily and exhibits significant solubility in water. Together with 3,5-dichlorophenol, it is prepared industrially by dechlorination of polychlorophenols. Alternatively, it arises via the ], which starts with the alkylation of chlorobenzene with propylene.<ref>{{Ullmann|author1=François Muller |author2=Liliane Caillard|title=Chlorophenols|year=2011|doi=10.1002/14356007.a07_001.pub2}}</ref> |
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==References== |
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{{Reflist}} |
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==Cited sources== |
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*{{cite book |ref=Haynes| editor= Haynes, William M. | date = 2016| title = ] | edition = 97th | publisher = ] | isbn = 9781498754293}} |
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{{DEFAULTSORT:Chlorophenol, 3-}} |
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] |
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] |