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| verifiedrevid = 401800846 |
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| verifiedrevid = 428203184 |
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| ImageFile = Ammonium phosphate.png |
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| ImageFile = Ammonium phosphate.png |
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| ImageSize = 200px |
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| ImageFile1 = Triammonium-phosphate-3D-balls.png |
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| ImageFile1 = Triammonium-phosphate-3D-balls.png |
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| ImageSize1 = 240px |
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| ImageSize1 = 240px |
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| Reference = <ref name="hand"> |
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| Reference = <ref name="hand"> |
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{{cite book | last = Lide | first = David R. | year = 1998 |
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{{cite book | last = Lide | first = David R. | year = 1998 |
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| title = Handbook of Chemistry and Physics |
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| title = Handbook of Chemistry and Physics |
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| edition = 87 | volume = |
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| edition = 87 | volume = |
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| location = Boca Raton, FL |
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| location = Boca Raton, Florida |
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| publisher = CRC Press |
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| publisher = CRC Press |
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| isbn = 0-8493-0594-2 | pages = 4–42, 5–19}}</ref> |
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| isbn = 978-0-8493-0594-8 | pages = 4–42, 5–19}}</ref> |
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| IUPACName = ammonium phosphate |
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| IUPACName = ammonium phosphate |
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| OtherNames = triammonium phosphate |
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| OtherNames = triammonium phosphate |
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| Section1 = {{Chembox Identifiers |
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|Section1={{Chembox Identifiers |
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| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} |
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| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} |
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| ChemSpiderID = 140090 |
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| ChemSpiderID = 140090 |
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| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}} |
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| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}} |
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| StdInChIKey = ZRIUUUJAJJNDSS-UHFFFAOYSA-N |
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| StdInChIKey = ZRIUUUJAJJNDSS-UHFFFAOYSA-N |
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| CASNo_Ref = {{cascite|correct|CAS}} |
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| CASNo_Comment = {{cascite|correct|CAS}} |
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| CASNo = 10361-65-6 |
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| CASNo = 10361-65-6 |
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| PubChem = |
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| EC_number = 269-789-9 |
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| UNII_Ref = {{fdacite|changed|FDA}} |
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| UNII = 2ZJF06M0I9 |
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| PubChem = 159282 |
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| SMILES = P()()=O... |
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| SMILES = P()()=O... |
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| Section2 = {{Chembox Properties |
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|Section2={{Chembox Properties |
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| Formula = (NH<sub>4</sub>)<sub>3</sub>PO<sub>4</sub> |
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| N=3|H=12|O=4|P=1 |
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| Appearance = |
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| Appearance = White, ] crystals |
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| Density = |
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| Density = |
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| MeltingPt = |
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| MeltingPt = |
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| BoilingPt = |
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| BoilingPt = |
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| Solubility = 58.0 g/100 mL (25°C)}} |
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| Solubility = 58.0 g/100 mL (25 °C) |
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| SolubleOther = Insoluble in ]<ref name="crc">{{cite book |author1=John Rumble |title=CRC Handbook of Chemistry and Physics |date=June 18, 2018 |publisher=CRC Press |isbn=978-1138561632 |pages=4–41|edition=99th |language=English}}</ref> |
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| Section3 = {{Chembox Hazards |
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| MolarMass<!-- MolecularWeight -->=149.09 g/mol}} |
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| FlashPt = |
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| GHSPictograms = {{GHS07}} |
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| GHSSignalWord = Warning |
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| Section4 = {{Chembox Thermochemistry |
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| HPhrases = {{H-phrases|302|319}} |
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| DeltaHf = -1671.9 kJ/mol |
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| PPhrases = {{P-phrases|264|270|280|301+312|305+351+338|330|337+313|501}} |
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| DeltaHc = |
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| Entropy = |
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| NFPA-H = 2 |
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| NFPA-F = 0 |
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| NFPA-R = 0 |
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| AutoignitionPt = }} |
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|Section4={{Chembox Thermochemistry |
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| DeltaHf = −1671.9 kJ/mol |
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| HeatCapacity = }} |
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| Section8 = {{Chembox Related |
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| OtherAnions = ]<br/>] |
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| OtherCations = ]<br/>] |
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| OtherCations = ]<br/>] |
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| OtherCompounds = ]<br/>] |
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| OtherFunctn = |
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| Function = |
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'''Ammonium phosphate''' is the ] of ] and ]. It has the ] (NH<sub>4</sub>)<sub>3</sub>PO<sub>4</sub> and consists of ] ]s and ] ]. It is obtained as a crystalline powder upon mixing concentrated solutions of ammonia and phosphoric acid, or on the addition of excess of ammonia to the acid phosphate ]. It is soluble in water, and the aqueous solution on boiling loses ammonia and the acid phosphate ] is formed. |
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'''Ammonium phosphate''' is the ] with the ] (NH<sub>4</sub>)<sub>3</sub>PO<sub>4</sub>. It is the ammonium ] of orthophosphoric acid. A related "double salt", (NH<sub>4</sub>)<sub>3</sub>PO<sub>4</sub><sup>.</sup>(NH<sub>4</sub>)<sub>2</sub>HPO<sub>4</sub> is also recognized but is impractical to use. Both triammonium salts evolve ammonia. In contrast to the unstable nature of the triammonium salts, the ] (NH<sub>4</sub>)<sub>2</sub>HPO<sub>4</sub> and ] (NH<sub>4</sub>)H<sub>2</sub>PO<sub>4</sub> are stable materials that are commonly used as fertilizers to provide plants with fixed nitrogen and phosphorus.<ref name=Ullmann>{{Ullmann|first1=Klaus|last1=Schrödter|first2=Gerhard|last2=Bettermann|first3=Thomas |last3=Staffel|first4=Friedrich|last4=Wahl|first5=Thomas|last5=Klein||first6=Thomas|last6=Hofmann|title=Phosphoric Acid and Phosphates|year=2008|doi=10.1002/14356007.a19_465.pub3}}</ref> |
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==Preparation of triammonium phosphate== |
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Ammonium phosphate is used as an ingredient in some ]s as a high source of elemental ]. It is also used as a ] in thermoplastic compositions. It is also used in bread making to promote the growth of the yeast.<ref>http://www.freshpatents.com/Flame-retardant-composition-dt20051229ptan20050288402.php</ref> |
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Triammonium phosphate can be prepared in the laboratory by treating 85% phosphoric acid with 30% ammonia solution:{{cn|date=April 2019}} |
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:H<sub>3</sub>PO<sub>4</sub> + 3 NH<sub>3</sub> → (NH<sub>4</sub>)<sub>3</sub>PO<sub>4</sub> |
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(NH<sub>4</sub>)<sub>3</sub>PO<sub>4</sub> is a colorless, crystalline solid. The solid, which has the odor of ammonia, is readily soluble in water. The salt converts to diammonium hydrogen phosphate (NH<sub>4</sub>)<sub>2</sub>HPO<sub>4</sub>. |
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==See also== |
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==See also== |
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==References== |
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==References== |
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{{Reflist}} |
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{{Ammonium salts}} |
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{{Phosphates}} |
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