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{{short description|Chemical compound}} |
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{{chembox |
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{{chembox |
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|Watchedfields = changed |
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| Name = Argon fluorohydride |
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|verifiedrevid = 443220539 |
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| ImageFile = Argon-fluorohydride-3D-vdW.png |
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|Name = Argon fluorohydride |
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<!-- | ImageSize = 150px --> |
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| ImageName = Argon fluorohydride |
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|ImageFile = Argon-fluorohydride-3D-vdW.png |
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|ImageName = Argon fluorohydride |
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| Section1 = {{Chembox Identifiers |
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|OtherNames = Argon hydrofluoride |
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| ChemSpiderID = 15863741 |
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|Section1={{Chembox Identifiers |
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| InChI = 1/ArFH/c1-2/h1H |
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|ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} |
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| InChIKey = HEPJAPHKUAGBIG-UHFFFAOYAL |
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|ChemSpiderID = 15863741 |
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| SMILES = F |
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|DTXSID = DTXSID701018815 |
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| StdInChI = 1S/ArFH/c1-2/h1H |
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|PubChem = 154735196 |
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| StdInChIKey = HEPJAPHKUAGBIG-UHFFFAOYSA-N |
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|InChI = 1/ArFH/c1-2/h1H |
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| CASNo = 163731-16-6 |
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|InChIKey = HEPJAPHKUAGBIG-UHFFFAOYAL |
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}} |
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|SMILES = F |
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| Section2 = {{Chembox Properties |
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|StdInChI_Ref = {{stdinchicite|correct|chemspider}} |
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| Formula = HArF |
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|StdInChI = 1S/ArFH/c1-2/h1H |
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| MolarMass = 59.954 g/mol |
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|StdInChIKey_Ref = {{stdinchicite|correct|chemspider}} |
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| Appearance = Unknown |
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|StdInChIKey = HEPJAPHKUAGBIG-UHFFFAOYSA-N |
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| Density = Unknown |
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|CASNo_Ref = {{cascite|correct|??}} |
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| Solubility = Unknown |
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|CASNo = 163731-16-6 |
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| MeltingPt = −256°C (Decomposes) |
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|Section2={{Chembox Properties |
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|Formula = HArF |
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|MolarMass = 59.954 g/mol |
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|Appearance = Unknown |
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|Density = Unknown |
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|Solubility = Unknown |
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|MeltingPtC = −256 |
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|MeltingPt_notes = (decomposes) |
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}} |
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}} |
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'''Argon fluorohydride''' (systematically named '''fluoridohydridoargon''') or '''argon hydrofluoride''' is an ] with the ] HArF (also written ArHF). It is a compound of the ] ]. |
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== Discovery == |
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'''Argon fluorohydride''' (HArF) is the first known compound of the ] ]. |
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The discovery of this ] is credited to a group of Finnish scientists, led by Markku Räsänen.<ref>{{cite journal | last = Räsänen | first = Markku | date = 17 December 2013 | title = Argon out of thin air | journal = Nature Chemistry | volume = 6 | pages = 82 | doi = 10.1038/nchem.1825 | pmid = 24345939 | issue = 1 | doi-access = free }}</ref> On 24 August 2000, in the journal '']'', they announced their discovery of argon fluorohydride.<ref name=ASAC>{{cite journal | last = Khriachtchev | first = Leonid |author2=Mika Pettersson |author3=Nino Runeberg |author4=Jan Lundell |author5=Markku Räsänen | date = 24 August 2000 | title = A stable argon compound | journal = Nature | volume = 406 | pages = 874–876 | doi = 10.1038/35022551 | pmid = 10972285 | issue = 6798 | bibcode = 2000Natur.406..874K | s2cid = 4382128 }}</ref> This discovery caused the recognition that argon could form weakly bound compounds, even though it was not the first compound made with noble gases.<ref>{{Cite web |last=Perkins |first=Sid |date=29 April 2003 |title="HArF! Argon's not so noble after all – researchers make argon fluorohydride" |url=https://www.sciencenews.org/article/harf-argons-not-so-noble-after-all |access-date=24 April 2024 |website=Science News}}</ref> |
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==Discovery== |
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== Synthesis == |
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This chemical was synthesized by mixing ] and ] on a ] surface at 8 K (−265 °C), and exposing the mixture to ultraviolet radiation. This caused the gases to combine. |
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The discovery of this first ] compound is credited to a group of Finnish scientists, led by Markku Räsänen. On 24 August 2000, in the journal '']'', they announced their discovery of argon fluorohydride.<ref>{{cite journal | last = Khriachtchev | first = Leonid | coauthors = Mika Pettersson, Nino Runeberg, Jan Lundell & Markku Räsänen | date = 24 August 2000 | title = A stable argon compound | journal = Nature | volume = 406 | pages = 874–876 | doi = 10.1038/35022551 | url = http://www.nature.com/nature/journal/v406/n6798/abs/406874a0.html | pmid = 10972285 | issue = 6798 }}</ref> |
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The ] of the resulting gas mixture shows that it definitely contains chemical bonds, albeit very weak ones; thus, it is argon fluorohydride, and not a ] or a mixture of argon and hydrogen fluoride. Its chemical bonds are stable only if the substance is kept at temperatures below 27 K (−246 °C); upon warming, it decomposes into argon and hydrogen fluoride.<ref name=ASAC/> |
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==Synthesis== |
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This chemical was synthesized by mixing argon and ] on a ] surface at −265 °C, and exposing the mixture to ultraviolet radiation. This caused the gases to combine. |
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== References == |
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The ] of the resulting gas mixture shows that it definitely contains chemical bonds, albeit very weak ones; thus, it is argon hydrofluoride. Its chemical bonds are only stable if the substance is kept at temperatures below −256 °C; upon warming, it decomposes into argon and hydrogen fluoride. |
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{{Reflist}} |
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== Further reading == |
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==References== |
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*{{cite book|last=Emsley|first=John|title=Nature's Building Blocks: An A–Z Guide to the Elements|year=2001|publisher=Oxford University Press|location=Oxford|isbn=0-19-850341-5}} |
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*{{cite book|last=Emsley|first=John|title=Nature's Building Blocks: An A–Z Guide to the Elements|year=2001|publisher=Oxford University Press|location=Oxford|isbn=0-19-850341-5}} |
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<references/> |
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{{Noble gas compounds}} |
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{{hydrogen compounds}} |
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{{fluorine compounds}} |
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