Revision as of 18:23, 5 August 2011 edit186.225.32.18 (talk)No edit summary← Previous edit |
Latest revision as of 20:32, 9 June 2024 edit undoRuslik0 (talk | contribs)Edit filter managers, Administrators54,720 edits sp |
(68 intermediate revisions by 49 users not shown) |
Line 1: |
Line 1: |
|
|
{{short description|Chemical compound}} |
|
{{chembox |
|
{{chembox |
|
|
|Watchedfields = changed |
|
| verifiedrevid = 399530625 |
|
|verifiedrevid = 443220539 |
⚫ |
| Name = Argon fluorohydride |
|
|
| ImageFile = Argon-fluorohydride-3D-vdW.png |
|
|Name = Argon fluorohydride |
|
|
|ImageFile = Argon-fluorohydride-3D-vdW.png |
|
⚫ |
|ImageName = Argon fluorohydride |
|
<!-- | ImageSize = 150px --> |
|
|
| ImageName = Argon fluorohydride |
|
|OtherNames = Argon hydrofluoride |
|
| Section1 = {{Chembox Identifiers |
|
|Section1={{Chembox Identifiers |
|
| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} |
|
|ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} |
|
| ChemSpiderID = 15863741 |
|
|ChemSpiderID = 15863741 |
|
|
|DTXSID = DTXSID701018815 |
⚫ |
| InChI = 1/ArFH/c1-2/h1H |
|
|
|
|PubChem = 154735196 |
⚫ |
| InChIKey = HEPJAPHKUAGBIG-UHFFFAOYAL |
|
|
⚫ |
|InChI = 1/ArFH/c1-2/h1H |
⚫ |
| SMILES = F |
|
|
⚫ |
|InChIKey = HEPJAPHKUAGBIG-UHFFFAOYAL |
⚫ |
| StdInChI_Ref = {{stdinchicite|correct|chemspider}} |
|
|
⚫ |
|SMILES = F |
⚫ |
| StdInChI = 1S/ArFH/c1-2/h1H |
|
|
| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}} |
|
|StdInChI_Ref = {{stdinchicite|correct|chemspider}} |
|
⚫ |
|StdInChI = 1S/ArFH/c1-2/h1H |
⚫ |
| StdInChIKey = HEPJAPHKUAGBIG-UHFFFAOYSA-N |
|
|
⚫ |
|StdInChIKey_Ref = {{stdinchicite|correct|chemspider}} |
⚫ |
| CASNo = 163731-16-6 |
|
|
⚫ |
|StdInChIKey = HEPJAPHKUAGBIG-UHFFFAOYSA-N |
⚫ |
}} |
|
|
|
|CASNo_Ref = {{cascite|correct|??}} |
⚫ |
| Section2 = {{Chembox Properties |
|
|
⚫ |
|CASNo = 163731-16-6 |
⚫ |
| Formula = HArF |
|
|
⚫ |
}} |
⚫ |
| MolarMass = 59.954 g/mol |
|
|
⚫ |
|Section2={{Chembox Properties |
⚫ |
| Appearance = Unknown |
|
|
⚫ |
|Formula = HArF |
⚫ |
| Density = Unknown |
|
|
⚫ |
|MolarMass = 59.954 g/mol |
⚫ |
| Solubility = Unknown |
|
|
⚫ |
|Appearance = Unknown |
|
| MeltingPt = −256°C (Decomposes) |
|
|
⚫ |
|Density = Unknown |
⚫ |
}} |
|
|
⚫ |
|Solubility = Unknown |
|
|
|MeltingPtC = −256 |
|
|
|MeltingPt_notes = (decomposes) |
|
⚫ |
}} |
|
}} |
|
}} |
|
|
|
|
|
'''Argon fluorohydride''' (HArF) is the first known compound of the ] ]. |
|
'''Argon fluorohydride''' (systematically named '''fluoridohydridoargon''') or '''argon hydrofluoride''' is an ] with the ] HArF (also written ArHF). It is a compound of the ] ]. |
|
|
|
|
|
==Discovery== |
|
== Discovery == |
|
The discovery of this first ] compound is credited to a group of Finnish scientists, led by Markku Räsänen. On 24 August 2000, in the journal '']'', they announced their discovery of argon fluorohydride.<ref>{{cite journal | last = Khriachtchev | first = Leonid | coauthors = Mika Pettersson, Nino Runeberg, Jan Lundell & Markku Räsänen | date = 24 August 2000 | title = A stable argon compound | journal = Nature | volume = 406 | pages = 874–876 | doi = 10.1038/35022551 | url = http://www.nature.com/nature/journal/v406/n6798/abs/406874a0.html | pmid = 10972285 | issue = 6798 }}</ref> |
|
The discovery of this ] is credited to a group of Finnish scientists, led by Markku Räsänen.<ref>{{cite journal | last = Räsänen | first = Markku | date = 17 December 2013 | title = Argon out of thin air | journal = Nature Chemistry | volume = 6 | pages = 82 | doi = 10.1038/nchem.1825 | pmid = 24345939 | issue = 1 | doi-access = free }}</ref> On 24 August 2000, in the journal '']'', they announced their discovery of argon fluorohydride.<ref name=ASAC>{{cite journal | last = Khriachtchev | first = Leonid |author2=Mika Pettersson |author3=Nino Runeberg |author4=Jan Lundell |author5=Markku Räsänen | date = 24 August 2000 | title = A stable argon compound | journal = Nature | volume = 406 | pages = 874–876 | doi = 10.1038/35022551 | pmid = 10972285 | issue = 6798 | bibcode = 2000Natur.406..874K | s2cid = 4382128 }}</ref> This discovery caused the recognition that argon could form weakly bound compounds, even though it was not the first compound made with noble gases.<ref>{{Cite web |last=Perkins |first=Sid |date=29 April 2003 |title="HArF! Argon's not so noble after all – researchers make argon fluorohydride" |url=https://www.sciencenews.org/article/harf-argons-not-so-noble-after-all |access-date=24 April 2024 |website=Science News}}</ref> |
|
|
|
|
|
==Synthesis== |
|
== Synthesis == |
|
This chemical was synthesized by mixing argon and ] on a ] surface at −265 °C, and exposing the mixture to ultraviolet radiation. This caused the gases to combine. |
|
This chemical was synthesized by mixing ] and ] on a ] surface at 8 K (−265 °C), and exposing the mixture to ultraviolet radiation. This caused the gases to combine. |
|
|
|
|
|
The ] of the resulting gas mixture shows that it definitely contains chemical bonds, albeit very weak ones; thus, it is argon hydrofluoride. Its chemical bonds are only stable if the substance is kept at temperatures below −256 °C; upon warming, it decomposes into argon and hydrogen fluoride. |
|
The ] of the resulting gas mixture shows that it definitely contains chemical bonds, albeit very weak ones; thus, it is argon fluorohydride, and not a ] or a mixture of argon and hydrogen fluoride. Its chemical bonds are stable only if the substance is kept at temperatures below 27 K (−246 °C); upon warming, it decomposes into argon and hydrogen fluoride.<ref name=ASAC/> |
|
|
|
|
|
==References== |
|
== References == |
|
|
{{Reflist}} |
|
<references/> |
|
|
|
|
|
|
==Further reading== |
|
== Further reading == |
|
*{{cite book|last=Emsley|first=John|title=Nature's Building Blocks: An A–Z Guide to the Elements|year=2001|publisher=Oxford University Press|location=Oxford|isbn=0-19-850341-5}} |
|
*{{cite book|last=Emsley|first=John|title=Nature's Building Blocks: An A–Z Guide to the Elements|year=2001|publisher=Oxford University Press|location=Oxford|isbn=0-19-850341-5}} |
|
|
|
|
|
|
{{Noble gas compounds}} |
|
|
|
|
|
{{hydrogen compounds}} |
|
|
{{fluorine compounds}} |
|
] |
|
] |
|
|
] |
|
] |
|
] |
|
] |
|
] |
|
|
] |
|
|
|
|
|
|
] |
|
] |
|
|
] |
|
|
] |
|
|
] |
|
|
] |
|
|
] |
|
|
] |
|
|
] |
|
|
] |
|
|
] |
|
|
] |
|