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{{short description|Chemical compound}}
{{chembox {{chembox
|Watchedfields = changed
| verifiedrevid = 399530625 |verifiedrevid = 443220539
| Name = Argon fluorohydride
| ImageFile = Argon-fluorohydride-3D-vdW.png |Name = Argon fluorohydride
|ImageFile = Argon-fluorohydride-3D-vdW.png
|ImageName = Argon fluorohydride
<!-- | ImageSize = 150px -->
| ImageName = Argon fluorohydride |OtherNames = Argon hydrofluoride
| Section1 = {{Chembox Identifiers |Section1={{Chembox Identifiers
| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} |ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
| ChemSpiderID = 15863741 |ChemSpiderID = 15863741
|DTXSID = DTXSID701018815
| InChI = 1/ArFH/c1-2/h1H
|PubChem = 154735196
| InChIKey = HEPJAPHKUAGBIG-UHFFFAOYAL
|InChI = 1/ArFH/c1-2/h1H
| SMILES = F
|InChIKey = HEPJAPHKUAGBIG-UHFFFAOYAL
| StdInChI_Ref = {{stdinchicite|correct|chemspider}}
|SMILES = F
| StdInChI = 1S/ArFH/c1-2/h1H
| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}} |StdInChI_Ref = {{stdinchicite|correct|chemspider}}
|StdInChI = 1S/ArFH/c1-2/h1H
| StdInChIKey = HEPJAPHKUAGBIG-UHFFFAOYSA-N
|StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}
| CASNo = 163731-16-6
|StdInChIKey = HEPJAPHKUAGBIG-UHFFFAOYSA-N
}}
|CASNo_Ref = {{cascite|correct|??}}
| Section2 = {{Chembox Properties
|CASNo = 163731-16-6
| Formula = HArF
}}
| MolarMass = 59.954 g/mol
|Section2={{Chembox Properties
| Appearance = Unknown
|Formula = HArF
| Density = Unknown
|MolarMass = 59.954 g/mol
| Solubility = Unknown
|Appearance = Unknown
| MeltingPt = −256°C (Decomposes)
|Density = Unknown
}}
|Solubility = Unknown
|MeltingPtC = −256
|MeltingPt_notes = (decomposes)
}}
}} }}


'''Argon fluorohydride''' (HArF) is the first known compound of the ] ]. '''Argon fluorohydride''' (systematically named '''fluoridohydridoargon''') or '''argon hydrofluoride''' is an ] with the ] HArF (also written ArHF). It is a compound of the ] ].


==Discovery== == Discovery ==
The discovery of this first ] compound is credited to a group of Finnish scientists, led by Markku Räsänen. On 24 August 2000, in the journal '']'', they announced their discovery of argon fluorohydride.<ref>{{cite journal | last = Khriachtchev | first = Leonid | coauthors = Mika Pettersson, Nino Runeberg, Jan Lundell & Markku Räsänen | date = 24 August 2000 | title = A stable argon compound | journal = Nature | volume = 406 | pages = 874–876 | doi = 10.1038/35022551 | url = http://www.nature.com/nature/journal/v406/n6798/abs/406874a0.html | pmid = 10972285 | issue = 6798 }}</ref> The discovery of this ] is credited to a group of Finnish scientists, led by Markku Räsänen.<ref>{{cite journal | last = Räsänen | first = Markku | date = 17 December 2013 | title = Argon out of thin air | journal = Nature Chemistry | volume = 6 | pages = 82 | doi = 10.1038/nchem.1825 | pmid = 24345939 | issue = 1 | doi-access = free }}</ref> On 24 August 2000, in the journal '']'', they announced their discovery of argon fluorohydride.<ref name=ASAC>{{cite journal | last = Khriachtchev | first = Leonid |author2=Mika Pettersson |author3=Nino Runeberg |author4=Jan Lundell |author5=Markku Räsänen | date = 24 August 2000 | title = A stable argon compound | journal = Nature | volume = 406 | pages = 874–876 | doi = 10.1038/35022551 | pmid = 10972285 | issue = 6798 | bibcode = 2000Natur.406..874K | s2cid = 4382128 }}</ref> This discovery caused the recognition that argon could form weakly bound compounds, even though it was not the first compound made with noble gases.<ref>{{Cite web |last=Perkins |first=Sid |date=29 April 2003 |title="HArF! Argon's not so noble after all – researchers make argon fluorohydride" |url=https://www.sciencenews.org/article/harf-argons-not-so-noble-after-all |access-date=24 April 2024 |website=Science News}}</ref>


==Synthesis== == Synthesis ==
This chemical was synthesized by mixing argon and ] on a ] surface at −265&nbsp;°C, and exposing the mixture to ultraviolet radiation. This caused the gases to combine. This chemical was synthesized by mixing ] and ] on a ] surface at 8 K (−265 °C), and exposing the mixture to ultraviolet radiation. This caused the gases to combine.


The ] of the resulting gas mixture shows that it definitely contains chemical bonds, albeit very weak ones; thus, it is argon hydrofluoride. Its chemical bonds are only stable if the substance is kept at temperatures below −256&nbsp;°C; upon warming, it decomposes into argon and hydrogen fluoride. The ] of the resulting gas mixture shows that it definitely contains chemical bonds, albeit very weak ones; thus, it is argon fluorohydride, and not a ] or a mixture of argon and hydrogen fluoride. Its chemical bonds are stable only if the substance is kept at temperatures below 27 K (−246 °C); upon warming, it decomposes into argon and hydrogen fluoride.<ref name=ASAC/>


==References== == References ==
{{Reflist}}
<references/>


==Further reading== == Further reading ==
*{{cite book|last=Emsley|first=John|title=Nature's Building Blocks: An A–Z Guide to the Elements|year=2001|publisher=Oxford University Press|location=Oxford|isbn=0-19-850341-5}} *{{cite book|last=Emsley|first=John|title=Nature's Building Blocks: An A–Z Guide to the Elements|year=2001|publisher=Oxford University Press|location=Oxford|isbn=0-19-850341-5}}


{{Noble gas compounds}}

{{hydrogen compounds}}
{{fluorine compounds}}
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