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{{Chembox {{Chembox
| Verifiedfields = changed
⚫ | verifiedrevid = 396301862
| Watchedfields = changed
| ImageFile = brilliantgruen.png
⚫ | verifiedrevid = 434149900
| ImageFile = Brilliant green (dye) Structural Formula V1.svg
| ImageSize = 150px | ImageSize = 150px
| Name = Brilliant green
| IUPACName = | IUPACName =
| OtherNames = Malachite green G, Emerald green, Solid green JJO, Diamond green G, Aniline green, Benzaldehyde green, Fast green J | OtherNames = Malachite green G, Emerald green, Solid green JJO, Diamond green G, Aniline green, Benzaldehyde green, Fast green J
| Section1 = {{Chembox Identifiers |Section1={{Chembox Identifiers
| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} | ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
| ChemSpiderID = 11941 | ChemSpiderID = 11941
| ChEMBL_Ref = {{ebicite|changed|EBI}}
| ChEMBL = 1181633
| ChEBI_Ref = {{ebicite|changed|EBI}}
| ChEBI = 88173
| UNII_Ref = {{fdacite|correct|FDA}} | UNII_Ref = {{fdacite|correct|FDA}}
| UNII = G0L543D370 | UNII = G0L543D370
Line 17: Line 24:
| StdInChIKey = NNBFNNNWANBMTI-UHFFFAOYSA-M | StdInChIKey = NNBFNNNWANBMTI-UHFFFAOYSA-M
| CASNo_Ref = {{cascite|correct|CAS}} | CASNo_Ref = {{cascite|correct|CAS}}
| CASNo = 633-03-4 | CASNo = 633-03-4
| PubChem = 12449 | PubChem = 12449
| SMILES = S(=O)(=O)O.(=C/1\C=C/C(C=C\1)=C(/c2ccccc2)c3ccc(N(CC)CC)cc3)(\CC)CC | SMILES = S(=O)(=O)O.(=C/1\C=C/C(C=C\1)=C(/c2ccccc2)c3ccc(N(CC)CC)cc3)(\CC)CC
}} }}
| Section2 = {{Chembox Properties |Section2={{Chembox Properties
| Formula = ]<sub>27</sub>]<sub>33</sub>]<sub>2</sub>.H]<sub>4</sub>] | Formula = ]<sub>27</sub>]<sub>33</sub>]<sub>2</sub>.H]<sub>4</sub>]
| MolarMass = 482,64 g/mol | MolarMass = 482.64 g/mol
| Appearance = | Appearance =
| Density = | Density =
| MeltingPt = 210 °C (decomposes) | MeltingPtC = 210
| MeltingPt_notes = (decomposes)
| BoilingPt =
| Solubility = 100 g/L a 20 °C | BoilingPt =
| Solubility = 100 g/L a 20 °C
⚫ }}
⚫ | Section3 = {{Chembox Hazards
⚫ | MainHazards =
⚫ | FlashPt =
| Autoignition =
}} }}
⚫ |Section3={{Chembox Hazards
⚫ | MainHazards =
⚫ | FlashPt =
| AutoignitionPt =
⚫ }}
}} }}


'''Brilliant Green''' is one of the ]s. It is closely related to ].<ref name=gessner2002>{{citation | last1=Gessner | first1=T. | last2=Mayer | first2=U. | year=2002 | contribution= Triarylmethane and Diarylmethane Dyes | title= Ullmann's Encyclopedia of Industrial Chemistry 6th Edition | publisher=Wiley-VCH | place=Weinheim | doi=10.1002/14356007.a27_179 }}</ref> '''Brilliant green''' (also known as {{transl|ru|zelyonka}} or {{transl|uk|zelenka}}) is one of the ]s. It is closely related to ].<ref name=gessner2002>{{citation | last1=Gessner | first1=T. | last2=Mayer | first2=U. | year=2002 | contribution= Triarylmethane and Diarylmethane Dyes | title= Ullmann's Encyclopedia of Industrial Chemistry 6th Edition | publisher=Wiley-VCH | place=Weinheim | doi=10.1002/14356007.a27_179 | isbn=3527306730 }}</ref>


==Uses== ==Uses==
]
Brilliant Green has been used to color silk and wool. Brilliant green has been used to color ] and ].


It is indicated for disinfection of fresh postoperative and post-traumatic scars, ] of newborns, abrasions, cuts, and other violations of the integrity of the skin, in the treatment of purulent-inflammatory processes of the skin - hordeolum ("barley"), meibomite, ], ], local ], carbunculosis, ].<ref>{{cite web | url=https://pubchem.ncbi.nlm.nih.gov/compound/Malachite-Green | title=Malachite Green }}</ref> It is applied externally, the drug is applied to the damaged surface, capturing the surrounding healthy tissue.{{Citation needed|date=August 2020}}
In ] and ] (and formerly the ]) the dilute alcoholic solution of Brilliant Green is sold as a topical ], also known under a Latin name ''Viridis nitentis spirituosa'' and a Russian name ''зелёнка'' .<ref>M. Balabanova, L. Popova, R. Tchipeva, ''Disease-a-Month'', 50(6), '''2004''', 270-279. </ref>


In ] and ] (and much of the rest of the former ]), the dilute alcoholic solution of brilliant green is sold as a topical ], also known under a Latin name {{lang|la|solutio viridis nitentis spirituosa}} and the colloquial Russian name of {{transl|ru|zelyonka}} ({{wikt-lang|ru|зелёнка}}, {{literally|green stuff}} in Russian),<ref>{{cite journal | doi = 10.1016/j.disamonth.2004.05.002| title = Dyes in dermatology| journal = Disease-a-Month| volume = 50| issue = 6| pages = 270| year = 2004| last1 = Balabanova| first1 = Maria| last2 = Popova| first2 = Liudmila| last3 = Tchipeva| first3 = Rositsa}}</ref>{{Failed verification|date=July 2019}} which is {{transl|uk|zelenka}} ({{wikt-lang|uk|зеленка}}) in Ukrainian.
Brilliant Green is effective against ]. The main advantage of Brilliant Green over the more common antiseptics such as ] is that it does not irritate mucous membranes. Therefore it is often used to treat infections of the eye, tongue sores and sinus infections. Brilliant green induces vomiting when swallowed and is toxic when ingested.<ref>Joseph K. Narat, Brilliant Green: A Clinical Study of its Value as a Local Antiseptic" Annals of Surgery 1931 December; 94(6): 1007–1012. </ref>


A 1% solution in 60% alcohol can be used for treatment of skin. 0.5% solution is used for mucous membranes or for infants.<ref name="Narat1931"/>
⚫ ==References==
⚫ <references/>


Brilliant green is a visible light-activated ] in organic synthesis.<ref>{{Cite journal|last1=Rogers|first1=David A.|last2=Bensalah|first2=Adam T.|last3=Espinosa|first3=Alvaro Tomas|last4=Hoerr|first4=John L.|last5=Refai|first5=Fares H.|last6=Pitzel|first6=Amy K.|last7=Alvarado|first7=Juan J.|last8=Lamar|first8=Angus A.|date=2019-06-07|title=Amplification of Trichloroisocyanuric Acid (TCCA) Reactivity for Chlorination of Arenes and Heteroarenes via Catalytic Organic Dye Activation|journal=Organic Letters|language=en|volume=21|issue=11|pages=4229–4233|doi=10.1021/acs.orglett.9b01414|pmid=31140821|s2cid=169034253 }}</ref>
==Other reading==

* (in Portuguese)
==Safety and toxicity==

Brilliant green is effective against ].<ref>{{Cite journal|last=|first=|date=June 1984|title=Martindale: The extra pharmacopeia, 28th Ed. Edited By James E. F. Reynolds and Anne B. Prasad. The Pharmaceopeial Press, 1 Lamberth High Street, London, SE1 7JN. Distributed in the U.S. by Rittenhouse Book Distributors, Inc., King of Prussia, PA 19406. 1982.|url=http://dx.doi.org/10.1002/jps.2600730653|journal=Journal of Pharmaceutical Sciences|volume=73|issue=6|pages=862|doi=10.1002/jps.2600730653|issn=0022-3549|via=}}</ref> The main advantage of brilliant green over the more common antiseptics such as ] is that it does not irritate mucous membranes as harshly on accidental contact. Soviet medical doctrine deemed it "not for use on ]" and cautions that it can cause eye damage and ophthalmic chemical burns and burns to an eye, at least in the typical formulations produced for medical use.{{Citation needed|date=July 2019}}

Brilliant green induces vomiting when swallowed and is toxic when ingested.<ref name="Narat1931">{{cite journal | pmc = 1391517| year = 1931| last1 = Narat| first1 = J. K.| title = Brilliant Green: A Clinical Study of Its Value As a Local Antiseptic| journal = Annals of Surgery| volume = 94| issue = 6| pages = 1007–1012| doi=10.1097/00000658-193112000-00003| pmid=17866691}}</ref> The compound may lead to serious injuries if it comes in contact with an eye, even resulting in bilateral ] due to ].<ref>{{PubChem|12449}}</ref>

== Politics ==
{{main|Zelyonka attack}}
In ] and sometimes in ], {{transl|ru|zelyonka}} has been used to physically attack political opponents.<ref>{{cite web|url=https://intpolicydigest.org/2017/05/06/how-the-soviet-era-antiseptic-zelyonka-became-a-political-weapon-in-russia-and-ukraine|title=How the Soviet-Era Antiseptic "Zelyonka" Became a Political Weapon in Russia and Ukraine|date=6 May 2017|publisher=|access-date=26 September 2017|archive-date=23 November 2020|archive-url=https://web.archive.org/web/20201123093230/https://intpolicydigest.org/2017/05/06/how-the-soviet-era-antiseptic-zelyonka-became-a-political-weapon-in-russia-and-ukraine/|url-status=dead}}</ref> Since 2016, many opponents of the Russian government have been splashed with {{transl|ru|zelyonka}}, including ], ], liberal activists, ], ], ], ] and ].<ref>{{cite news | url = https://www.economist.com/blogs/economist-explains/2017/05/economist-explains-7 | title = Why are Russian opposition leaders' faces turning green? | newspaper = ] | date = May 10, 2017 | access-date = May 11, 2017}}</ref>

⚫ ==References==
⚫ <references />


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