| Revision as of 18:33, 18 June 2011 editWoelen (talk | contribs)128 edits Changed description of color. This compound is not red-brown but yellow with a brownish hue.← Previous edit |
Latest revision as of 21:52, 25 June 2023 edit undoKeresluna (talk | contribs)Autopatrolled, Extended confirmed users4,071 editsNo edit summary |
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{{chembox |
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| verifiedrevid = 399695483 |
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| verifiedrevid = 434970460 |
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| Name = Bromine monochloride |
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| ImageFile = Bromine-monochloride-2D.png |
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| Name = Bromine monochloride |
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| ImageFile = Bromine-monochloride-2D.png |
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| ImageSize = 125px |
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| ImageSize = 125px |
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| ImageName = structural diagram |
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| ImageName = structural diagram |
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| ImageFile1 = Bromine-monochloride-3D-vdW.png |
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| ImageSize1 = 125px |
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| ImageFile1 = Bromine-monochloride-3D-vdW.png |
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| ImageName1 = space-filling molecular model |
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| ImageSize1 = 125px |
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| ImageFile2 = BrCl.jpg |
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| ImageName1 = space-filling molecular model |
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| OtherNames = bromine(I) chloride<br />bromochloride<br />bromine chloride |
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| ImageFile2 = BrCl.jpg |
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|Section1={{Chembox Identifiers |
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| OtherNames = bromine(I) chloride<br />bromochloride<br />bromine chloride |
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| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} |
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| Section1 = {{Chembox Identifiers |
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| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} |
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| ChemSpiderID = 55600 |
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| ChemSpiderID = 55600 |
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| PubChem = 61697 |
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| InChI = 1/BrCl/c1-2 |
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| InChI = 1/BrCl/c1-2 |
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| SMILES = BrCl |
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| SMILES = BrCl |
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| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}} |
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| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}} |
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| StdInChIKey = CODNYICXDISAEA-UHFFFAOYSA-N |
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| StdInChIKey = CODNYICXDISAEA-UHFFFAOYSA-N |
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| CASNo_Ref = {{cascite|correct|??}} |
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| CASNo = 13863-41-7 |
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| CASNo = 13863-41-7 |
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| EINECS = 237-601-4 |
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| EINECS = 237-601-4 |
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| UNNo = 2901 |
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| UNNumber = 2901 |
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| RTECS = EF9200000 |
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| UNII = 7G62XY5724 |
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| Section2 = {{Chembox Properties |
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|Section2={{Chembox Properties |
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| Appearance = golden yellow gas |
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| Formula = BrCl |
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| MolarMass = 115.357 g/mol |
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| Formula = BrCl |
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| MolarMass = 115.357 g/mol |
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| Density = 2.172 g/cm³ |
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| Density = 2.172 g/cm<sup>3</sup> |
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| Solvent = other solvents |
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| Solvent = water |
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| SolubleOther = 1.5 g/L |
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| SolubleOther = 8.5 g/L |
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| MeltingPt = -66 °C |
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| MeltingPtC = −54 |
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| MeltingPt_notes = |
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| BoilingPt = 5 °C}} |
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| BoilingPtC = 5 |
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| BoilingPt_notes = }} |
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|Section3={{Chembox Hazards |
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| NFPA-H = 3 |
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| NFPA-R = 2 |
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| NFPA-F = 0 |
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| NFPA-S = Ox |
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'''Bromine monochloride''', also called '''bromine(I) chloride''', '''bromochloride''', and '''bromine chloride''', is an ] ] with chemical formula ]]. It is an unstable brownish yellow gas with boiling point 5°C and melting point -66 °C. Its ] is 13863-41-7 and its ] is 237-601-4.<ref>{{Cite book |last=Gangolli |first=S. |coauthors=] |title=The Dictionary of Substances and Their Effects |date=1999 |isbn=0854048081 |page=676}}</ref> It is a strong oxidizing agent. |
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'''] monochloride''', also called '''bromine(I) chloride''', '''bromochloride''', and '''bromine chloride''', is an ] ] with chemical formula BrCl. It is a very reactive golden yellow gas with boiling point 5 °C and melting point −66 °C. Its ] is 13863-41-7, and its ] is 237-601-4.<ref>{{Cite book |last=Gangolli |first=S. |author2=Royal Society of Chemistry |author2-link=Royal Society of Chemistry |title=The Dictionary of Substances and Their Effects |year=1999 |isbn=0-85404-808-1 |page=676}}</ref> It is a strong oxidizing agent. Its ] in the gas phase was determined by ]; the Br-Cl bond has a length of ''r''<sub>e</sub> = 2.1360376(18) Å.<ref>{{Cite journal |last=Ogilvie |first=J. F. |date=1995 |title=Electric polarity<sup>+</sup>BrCl<sup>–</sup>and rotational g factor from analysis of frequencies of pure rotational and vibration–rotational spectra |url=http://dx.doi.org/10.1039/ft9959103005 |journal=J. Chem. Soc., Faraday Trans. |volume=91 |issue=18 |pages=3005–3006 |doi=10.1039/ft9959103005 |issn=0956-5000}}</ref> Its crystal structure was determined by single crystal X-ray diffraction; the bond length in the solid state is 2.179(2) Å and the shortest intermolecular interaction is ''r''(Cl···Br) = 3.145(2) Å.<ref>{{Cite journal |last=Drews |first=Thomas |last2=Seppelt |first2=Konrad |date=October 2012 |title=Bromine Monofluoride |url=https://onlinelibrary.wiley.com/doi/10.1002/zaac.201200293 |journal=Zeitschrift für anorganische und allgemeine Chemie |language=en |volume=638 |issue=12-13 |pages=2106–2110 |doi=10.1002/zaac.201200293}}</ref> |
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==Uses== |
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==Uses== |
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Bromine monochloride is used in ] in determining low levels of ], to quantitatively oxidize mercury in the sample to Hg(II) state. |
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Bromine monochloride is used in ] in determining low levels of ], to quantitatively oxidize mercury in the sample to Hg(II) state. |
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Bromine monochloride is used as a ], specifically as an ], ], and ], in industrial recirculating cooling water systems. |
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A common use of bromine monochloride is as an ], ], and ] of industrial recirculating cooling water systems. |
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Addition of bromine monochloride is used in some types of ] to increase voltage and energy density.<ref>{{Cite web |url=http://electronic-components.globalspec.com/specifications/electrical_electronic_components/batteries/lithium_batteries |title=Battery Chemistry - Lithium / Thionyl Chloride |accessdate=2008-07-09 |publisher=GlobalSpec}}</ref> |
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Addition of bromine monochloride is used in some types of ] to increase voltage and energy density.<ref>{{Cite web |url=http://electronic-components.globalspec.com/specifications/electrical_electronic_components/batteries/lithium_batteries |title=Battery Chemistry - Lithium / Thionyl Chloride |access-date=2008-07-09 |publisher=GlobalSpec |url-status=dead |archive-url=https://web.archive.org/web/20071223174334/http://electronic-components.globalspec.com/specifications/electrical_electronic_components/batteries/lithium_batteries |archive-date=2007-12-23 }}</ref> |
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==See also== |
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==See also== |
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==References== |
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==References== |
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{{Reflist}} |
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{{Reflist}} |
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{{bromine compounds}} |
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{{Chlorides}} |
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{{Authority control}} |
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