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{{Redirect|CuTC||CUTC (disambiguation)}} |
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{{Redirect|CuTC||CUTC (disambiguation)}} |
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{{Chembox |
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{{Chembox |
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|Watchedfields = changed |
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| verifiedrevid = 399729557 |
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|verifiedrevid = 399731183 |
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| Reference = <ref> at ]</ref> |
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|Reference = <ref> at ]</ref> |
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| ImageFile = Copper(I)-thiophene-2-carboxylate.png |
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|ImageFile = Copper(I)-thiophene-2-carboxylate.png |
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| ImageSize = 150px |
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|ImageSize = 150px |
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| IUPACName = Copper(I) thiophene-2-carboxylate |
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|IUPACName = Copper(I) thiophene-2-carboxylate |
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| OtherNames = CuTC |
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|OtherNames = CuTC |
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| Section1 = {{Chembox Identifiers |
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|Section1={{Chembox Identifiers |
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| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} |
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|ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} |
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| ChemSpiderID = 9369899 |
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|ChemSpiderID = 9369899 |
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| InChI = 1/C5H4O2S.Cu/c6-5(7)4-2-1-3-8-4;/h1-3H,(H,6,7);/q;+1/p-1 |
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|InChI = 1/C5H4O2S.Cu/c6-5(7)4-2-1-3-8-4;/h1-3H,(H,6,7);/q;+1/p-1 |
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| InChIKey = SFJMFSWCBVEHBA-REWHXWOFAY |
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|InChIKey = SFJMFSWCBVEHBA-REWHXWOFAY |
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| SMILES1 = .C(=O)c1sccc1 |
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|SMILES1 = .C(=O)c1sccc1 |
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| StdInChI_Ref = {{stdinchicite|correct|chemspider}} |
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|StdInChI_Ref = {{stdinchicite|correct|chemspider}} |
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| StdInChI = 1S/C5H4O2S.Cu/c6-5(7)4-2-1-3-8-4;/h1-3H,(H,6,7);/q;+1/p-1 |
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|StdInChI = 1S/C5H4O2S.Cu/c6-5(7)4-2-1-3-8-4;/h1-3H,(H,6,7);/q;+1/p-1 |
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| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}} |
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|StdInChIKey_Ref = {{stdinchicite|correct|chemspider}} |
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| StdInChIKey = SFJMFSWCBVEHBA-UHFFFAOYSA-M |
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|StdInChIKey = SFJMFSWCBVEHBA-UHFFFAOYSA-M |
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| CASNo = 68986-76-5 |
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|CASNo_Ref = {{cascite|correct|??}} |
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| PubChem = 11194830 |
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|CASNo = 68986-76-5 |
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| SMILES = O=C()C1=CC=CS1. |
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|UNII_Ref = {{fdacite|correct|FDA}} |
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|UNII = 7519WBL07L |
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|PubChem = 11194830 |
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|EINECS = 633-277-7 |
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|SMILES = O=C()C1=CC=CS1. |
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}} |
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}} |
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| Section2 = {{Chembox Properties |
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|Section2={{Chembox Properties |
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| C=5|H=3|Cu=1|O=2|S=1 |
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| C=5 | H=3 | Cu=1 | O=2 | S=1 |
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}} |
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| Appearance = |
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|Section3={{Chembox Hazards |
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| Density = |
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|MainHazards = Irritant |
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| MeltingPt = |
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|GHSPictograms = {{GHS07}} |
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| BoilingPt = |
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|GHSSignalWord = Warning |
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| Solubility = }} |
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|HPhrases = {{H-phrases|315|319|335}} |
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| Section3 = {{Chembox Hazards |
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|PPhrases = {{P-phrases|261|264|271|280|302+352|304+340|305+351+338|312|321|332+313|337+313|362|403+233|405|501}} |
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| MainHazards = Irritant ('''Xi''') |
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|PEL = TWA 1 mg/m<sup>3</sup> (as Cu)<ref name=PGCH>{{PGCH|0150}}</ref> |
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| RPhrases = {{R36/37/38}} |
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|REL = TWA 1 mg/m<sup>3</sup> (as Cu)<ref name=PGCH/> |
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| SPhrases = {{S26}} |
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|IDLH = TWA 100 mg/m<sup>3</sup> (as Cu)<ref name=PGCH/>}} |
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| FlashPt = |
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| Autoignition = }} |
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}} |
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}} |
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'''Copper(I)-thiophene-2-carboxylate''' or '''CuTC''' is a ] and a ] in ] that especially promotes the ] between ] ]s.<ref>{{cite journal | doi = 10.1021/cr000664r | title = Aryl-Aryl Bond Formation One Century after the Discovery of the Ullmann Reaction | author = Jwanro Hassan, Marc Sévignon, Christel Gozzi, Emmanuelle Schulz, and Marc Lemaire | journal = Chem. Rev. | year = 2002 | volume = 102 | issue = 5 | pages = 1359–1470 | url = http://pubs.acs.org/spotlight/july2002/cr000664r.pdf | pmid = 11996540}}</ref> |
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'''Copper(I) thiophene-2-carboxylate''' or '''CuTC''' is a ] derived from copper and ]. It is used as a ] to promote the ] between ] ]s.<ref>{{cite journal | doi = 10.1021/jo9700078 | title = Ambient Temperature, Ullmann-like Reductive Coupling of Aryl, Heteroaryl, and Alkenyl Halides |author1=Shijie Zhang |author2=Dawei Zhang |author3=Lanny S. Liebeskind | journal = J. Org. Chem. | year = 1997 | volume = 62 | issue = 8 | pages = 2312–2313 | pmid = 11671553}}</ref> |
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== References == |
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== References == |
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