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{{Use dmy dates|date=January 2023}}
{{Chembox {{Chembox
| Verifiedfields = changed
| verifiedrevid = 425793992
| Watchedfields = changed
| verifiedrevid = 433035864
| ImageFile = Cyclic-ozone-3D-balls.png | ImageFile = Cyclic-ozone-3D-balls.png
| ImageFile_Ref = {{chemboximage|correct|??}} | ImageFile_Ref = {{chemboximage|correct|??}}
| ImageSize = 121 | ImageSize = 100
| ImageName = Ball and stick model of cyclic ozone | ImageName = Ball and stick model of cyclic ozone
| SystematicName = Trioxirane<ref name=pubchem>{{Cite web|title=CID 16206854 - Compound Summary|url=https://pubchem.ncbi.nlm.nih.gov/summary/summary.cgi?cid=16206854|work=PubChem Compound|publisher=National Center for Biotechnology Information|access-date = 21 October 2011|location=USA|date=11 July 2007|at=Identification and Related Records}}</ref>
| IUPACName = Cyclic ozone
| OtherNames = {{ubl|Cyclotrioxidane|Trioxacyclopropane<ref name=pubchem></ref>}}
| SystematicName = Trioxirane<ref>{{Cite web|title = CID16206854 - PubChem Public Chemical Database|url = http://pubchem.ncbi.nlm.nih.gov/summary/summary.cgi?cid=16206854|work = The PubChem Project|location = USA|publisher = National Center for Biotechnology Information}}</ref>
| Section1 = {{Chembox Identifiers |Section1={{Chembox Identifiers
| PubChem = 16206854 | CASNo = 153851-84-4
| PubChem_Ref = {{Pubchemcite|correct|pubchem}} | CASNo_Ref = {{cascite|correct|CAS}}
| PubChem = 16206854
| ChemSpiderID = 13375217 | ChemSpiderID = 13375217
| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} | ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
| SMILES = O1OO1
| StdInChI = 1S/O3/c1-2-3-1 | SMILES = O1OO1
| StdInChI = 1S/O3/c1-2-3-1
| StdInChI_Ref = {{stdinchicite|correct|chemspider}} | StdInChI_Ref = {{stdinchicite|correct|chemspider}}
| StdInChIKey = XQOAKYYZMDCSIA-UHFFFAOYSA-N
| InChI = 1/O3/c1-2-3-1
| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}
| StdInChIKey = XQOAKYYZMDCSIA-UHFFFAOYSA-N
| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}
| InChIKey = XQOAKYYZMDCSIA-UHFFFAOYAK
}} }}
| Section2 = {{Chembox Properties |Section2={{Chembox Properties
| O = 3 | O=3
| ExactMass = 47.984743866 g mol<sup>-1</sup>
}} }}
}} }}


'''Cyclic ozone''' is a theoretically predicted form of ]. Like ordinary ozone (O<sub>3</sub>), it would have three ] atoms. It would differ from ordinary ozone how those three oxygen atoms are arranged. In ordinary ozone, the atoms are arranged in a bent line; in cyclic ozone they would form an ]. '''Cyclic ozone''' is a theoretically predicted form of ]. Like ordinary ozone (O<sub>3</sub>), it would have three ] atoms. It would differ from ordinary ozone in how those three oxygen atoms are arranged. In ordinary ozone, the atoms are arranged in a bent line; in cyclic ozone, they would form an ].


Some of properties of cyclic ozone have been predicted theoretically. It should have more energy than ordinary ozone.<ref> Some of the properties of cyclic ozone have been predicted theoretically. It should have more energy than ordinary ozone.<ref>
{{Cite journal | last = Hoffmann | first = Roald | authorlink = Roald Hoffman {{Cite journal | last = Hoffmann | first = Roald | author-link = Roald Hoffman
| title = The story of O. The Ring | journal = ] | title = The story of O. The Ring | journal = ]
| volume = 92 | issue = 1 | pages = 23–24 | volume = 92 | issue = 1 | pages = 23–24
| publisher = | location = | date = January–February 2004 | date = January–February 2004
| doi = 10.1511/2004.1.23
| url = http://www.americanscientist.org/issues/pub/the-story-of-o/5
}}
| issn = | doi = 10.1511/2004.1.23 | id =
</ref>
| accessdate = 2010-06-05}}
</ref>


Evidence has been reported that tiny quantities of cyclic ozone exist at the surface of magnesium oxide crystals in air.<ref> There is evidence that tiny quantities of cyclic ozone exist at the surface of ] crystals in air.<ref>
{{Cite journal | last = Plass | first = Richard {{Cite journal | last = Plass | first = Richard
| coauthors = Kenneth Egan, Chris Collazo-Davila, Daniel Grozea, Eric Landree, | author2=Kenneth Egan |author3=Chris Collazo-Davila |author4=Daniel Grozea |author5=Eric Landree |author6=Laurence D. Marks |author7=Marija Gajdardziska-Josifovska
| title = Cyclic Ozone Identified in Magnesium Oxide (111) Surface Reconstructions
Laurence D. Marks, and Marija Gajdardziska-Josifovska
| title = Cyclic Ozone Identified in Magnesium Oxide (111) Surface Reconstructions
| journal = ] | volume = 81 | issue = 22 | pages = 4891–4894 | journal = ] | volume = 81 | issue = 22 | pages = 4891–4894
| publisher = | location = | date = 30 November 1998
| date = November 30, 1998
| url = http://www.numis.northwestern.edu/Research/Articles/1998/98_PRL_Plass.pdf | url = http://www.numis.northwestern.edu/Research/Articles/1998/98_PRL_Plass.pdf
| doi = 10.1103/PhysRevLett.81.4891
| issn =
| access-date = 5 June 2010 | bibcode=1998PhRvL..81.4891P}}
| doi =
10.1103/PhysRevLett.81.4891| id =
| accessdate = 2010-06-05 | bibcode=1998PhRvL..81.4891P}}


</ref> Cyclic ozone has not been made in bulk, although at least one researcher has attempted to do so using lasers.<ref name="sciencedaily"> </ref> Cyclic ozone has not been made in bulk, although at least one researcher has attempted to do so using lasers.<ref name="sciencedaily">
{{Cite journal {{Cite journal
| title = Temple Researcher Attempting To Create Cyclic Ozone | journal = Science Daily | title = Temple Researcher Attempting To Create Cyclic Ozone | journal = Science Daily
| date = 8 February 2005
| volume = | issue = | pages = | publisher = | location =
| url = https://www.sciencedaily.com/releases/2005/02/050205122519.htm| access-date = 5 June 2010}}</ref> Another possibility to stabilize this form of oxygen is to produce it inside confined spaces, e.g., ].<ref name="ReferenceA">{{cite journal|last1=Sabirov|first1=Denis|last2=Igor|first2=Shepelevich|title=Information entropy of oxygen allotropes. A still open discussion about the closed form of ozone|journal=Computational and Theoretical Chemistry|date=2015|volume=1073|issue=1|pages=61–66|doi=10.1016/j.comptc.2015.09.016}}</ref>
| date = February 8, 2005
| url = http://www.sciencedaily.com/releases/2005/02/050205122519.htm
| issn = | doi = | id = | accessdate = 2010-06-05}}</ref>


It has been speculated that, if cyclic ozone could be made in bulk, and it proved to have good ] properties,{{Clarify|date = April 2011}} it could be added to liquid oxygen to improve the ] of rocket fuel.<ref name="sciencedaily"/> It has been speculated that, if cyclic ozone could be made in bulk, and if it proved to have good ] properties, it could be added to liquid oxygen to improve the ] of rocket fuel.<ref name="sciencedaily"/>


Currently, the possibility of cyclic ozone is confirmed within diverse theoretical approaches.<ref name="ReferenceA"/><ref>{{cite journal|last1=Xantheas|first1=Sotiris|last2=Atchity|first2=Gregory|last3=Elbert|first3=Stephen|last4=Ruedenberg|first4=Klaus|title=Potential energy surfaces of ozone. I|journal=J. Chem. Phys.|date=1991|volume=94|issue=12|page=8054|doi=10.1063/1.460140|bibcode=1991JChPh..94.8054X|url=https://zenodo.org/record/1232932}}</ref><ref>{{cite journal|last1=Lee|first1=Timothy|title=On the energy separation between the open and cyclic forms of ozone|journal=Chemical Physics Letters|date=1990|volume=169|issue=6|pages=529–533|doi=10.1016/0009-2614(90)85642-P|bibcode=1990CPL...169..529L}}</ref>
== References ==

==References==
{{Reflist}} {{Reflist}}


==External links==
{{Inorganic-compound-stub}}
*{{Commonscatinline}}


{{oxygenallotropes}}
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