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{{Use dmy dates|date=January 2023}} |
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{{Chembox |
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| verifiedrevid = 425793992 |
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| verifiedrevid = 433035864 |
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| ImageFile = Cyclic-ozone-3D-balls.png |
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| ImageFile = Cyclic-ozone-3D-balls.png |
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| ImageFile_Ref = {{chemboximage|correct|??}} |
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| ImageFile_Ref = {{chemboximage|correct|??}} |
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| ImageSize = 121 |
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| ImageSize = 100 |
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| ImageName = Ball and stick model of cyclic ozone |
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| ImageName = Ball and stick model of cyclic ozone |
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| SystematicName = Trioxirane<ref name=pubchem>{{Cite web|title=CID 16206854 - Compound Summary|url=https://pubchem.ncbi.nlm.nih.gov/summary/summary.cgi?cid=16206854|work=PubChem Compound|publisher=National Center for Biotechnology Information|access-date = 21 October 2011|location=USA|date=11 July 2007|at=Identification and Related Records}}</ref> |
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| IUPACName = Cyclic ozone |
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| OtherNames = {{ubl|Cyclotrioxidane|Trioxacyclopropane<ref name=pubchem></ref>}} |
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| SystematicName = Trioxirane<ref>{{Cite web|title = CID16206854 - PubChem Public Chemical Database|url = http://pubchem.ncbi.nlm.nih.gov/summary/summary.cgi?cid=16206854|work = The PubChem Project|location = USA|publisher = National Center for Biotechnology Information}}</ref> |
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| Section1 = {{Chembox Identifiers |
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|Section1={{Chembox Identifiers |
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| PubChem = 16206854 |
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| CASNo = 153851-84-4 |
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| PubChem_Ref = {{Pubchemcite|correct|pubchem}} |
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| CASNo_Ref = {{cascite|correct|CAS}} |
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| PubChem = 16206854 |
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| ChemSpiderID = 13375217 |
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| ChemSpiderID = 13375217 |
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| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} |
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| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} |
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| SMILES = O1OO1 |
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| StdInChI = 1S/O3/c1-2-3-1 |
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| SMILES = O1OO1 |
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| StdInChI = 1S/O3/c1-2-3-1 |
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| StdInChI_Ref = {{stdinchicite|correct|chemspider}} |
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| StdInChI_Ref = {{stdinchicite|correct|chemspider}} |
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| StdInChIKey = XQOAKYYZMDCSIA-UHFFFAOYSA-N |
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| InChI = 1/O3/c1-2-3-1 |
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| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}} |
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| StdInChIKey = XQOAKYYZMDCSIA-UHFFFAOYSA-N |
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| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}} |
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| InChIKey = XQOAKYYZMDCSIA-UHFFFAOYAK |
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}} |
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}} |
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| Section2 = {{Chembox Properties |
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|Section2={{Chembox Properties |
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| O = 3 |
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| O=3 |
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| ExactMass = 47.984743866 g mol<sup>-1</sup> |
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'''Cyclic ozone''' is a theoretically predicted form of ]. Like ordinary ozone (O<sub>3</sub>), it would have three ] atoms. It would differ from ordinary ozone how those three oxygen atoms are arranged. In ordinary ozone, the atoms are arranged in a bent line; in cyclic ozone they would form an ]. |
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'''Cyclic ozone''' is a theoretically predicted form of ]. Like ordinary ozone (O<sub>3</sub>), it would have three ] atoms. It would differ from ordinary ozone in how those three oxygen atoms are arranged. In ordinary ozone, the atoms are arranged in a bent line; in cyclic ozone, they would form an ]. |
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Some of properties of cyclic ozone have been predicted theoretically. It should have more energy than ordinary ozone.<ref> |
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Some of the properties of cyclic ozone have been predicted theoretically. It should have more energy than ordinary ozone.<ref> |
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{{Cite journal | last = Hoffmann | first = Roald | authorlink = Roald Hoffman |
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{{Cite journal | last = Hoffmann | first = Roald | author-link = Roald Hoffman |
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| title = The story of O. The Ring | journal = ] |
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| title = The story of O. The Ring | journal = ] |
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| volume = 92 | issue = 1 | pages = 23–24 |
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| volume = 92 | issue = 1 | pages = 23–24 |
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| publisher = | location = | date = January–February 2004 |
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| date = January–February 2004 |
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| doi = 10.1511/2004.1.23 |
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| url = http://www.americanscientist.org/issues/pub/the-story-of-o/5 |
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}} |
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| issn = | doi = 10.1511/2004.1.23 | id = |
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</ref> |
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| accessdate = 2010-06-05}} |
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</ref> |
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Evidence has been reported that tiny quantities of cyclic ozone exist at the surface of magnesium oxide crystals in air.<ref> |
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There is evidence that tiny quantities of cyclic ozone exist at the surface of ] crystals in air.<ref> |
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{{Cite journal | last = Plass | first = Richard |
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{{Cite journal | last = Plass | first = Richard |
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| coauthors = Kenneth Egan, Chris Collazo-Davila, Daniel Grozea, Eric Landree, |
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| author2=Kenneth Egan |author3=Chris Collazo-Davila |author4=Daniel Grozea |author5=Eric Landree |author6=Laurence D. Marks |author7=Marija Gajdardziska-Josifovska |
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| title = Cyclic Ozone Identified in Magnesium Oxide (111) Surface Reconstructions |
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Laurence D. Marks, and Marija Gajdardziska-Josifovska |
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| title = Cyclic Ozone Identified in Magnesium Oxide (111) Surface Reconstructions |
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| journal = ] | volume = 81 | issue = 22 | pages = 4891–4894 |
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| journal = ] | volume = 81 | issue = 22 | pages = 4891–4894 |
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| publisher = | location = |
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| date = 30 November 1998 |
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| date = November 30, 1998 |
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| url = http://www.numis.northwestern.edu/Research/Articles/1998/98_PRL_Plass.pdf |
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| url = http://www.numis.northwestern.edu/Research/Articles/1998/98_PRL_Plass.pdf |
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| doi = 10.1103/PhysRevLett.81.4891 |
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| issn = |
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| access-date = 5 June 2010 | bibcode=1998PhRvL..81.4891P}} |
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| doi = |
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10.1103/PhysRevLett.81.4891| id = |
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| accessdate = 2010-06-05 | bibcode=1998PhRvL..81.4891P}} |
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</ref> Cyclic ozone has not been made in bulk, although at least one researcher has attempted to do so using lasers.<ref name="sciencedaily"> |
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</ref> Cyclic ozone has not been made in bulk, although at least one researcher has attempted to do so using lasers.<ref name="sciencedaily"> |
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{{Cite journal |
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{{Cite journal |
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| title = Temple Researcher Attempting To Create Cyclic Ozone | journal = Science Daily |
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| title = Temple Researcher Attempting To Create Cyclic Ozone | journal = Science Daily |
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| date = 8 February 2005 |
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| volume = | issue = | pages = | publisher = | location = |
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| url = https://www.sciencedaily.com/releases/2005/02/050205122519.htm| access-date = 5 June 2010}}</ref> Another possibility to stabilize this form of oxygen is to produce it inside confined spaces, e.g., ].<ref name="ReferenceA">{{cite journal|last1=Sabirov|first1=Denis|last2=Igor|first2=Shepelevich|title=Information entropy of oxygen allotropes. A still open discussion about the closed form of ozone|journal=Computational and Theoretical Chemistry|date=2015|volume=1073|issue=1|pages=61–66|doi=10.1016/j.comptc.2015.09.016}}</ref> |
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| date = February 8, 2005 |
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| url = http://www.sciencedaily.com/releases/2005/02/050205122519.htm |
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| issn = | doi = | id = | accessdate = 2010-06-05}}</ref> |
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It has been speculated that, if cyclic ozone could be made in bulk, and it proved to have good ] properties,{{Clarify|date = April 2011}} it could be added to liquid oxygen to improve the ] of rocket fuel.<ref name="sciencedaily"/> |
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It has been speculated that, if cyclic ozone could be made in bulk, and if it proved to have good ] properties, it could be added to liquid oxygen to improve the ] of rocket fuel.<ref name="sciencedaily"/> |
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Currently, the possibility of cyclic ozone is confirmed within diverse theoretical approaches.<ref name="ReferenceA"/><ref>{{cite journal|last1=Xantheas|first1=Sotiris|last2=Atchity|first2=Gregory|last3=Elbert|first3=Stephen|last4=Ruedenberg|first4=Klaus|title=Potential energy surfaces of ozone. I|journal=J. Chem. Phys.|date=1991|volume=94|issue=12|page=8054|doi=10.1063/1.460140|bibcode=1991JChPh..94.8054X|url=https://zenodo.org/record/1232932}}</ref><ref>{{cite journal|last1=Lee|first1=Timothy|title=On the energy separation between the open and cyclic forms of ozone|journal=Chemical Physics Letters|date=1990|volume=169|issue=6|pages=529–533|doi=10.1016/0009-2614(90)85642-P|bibcode=1990CPL...169..529L}}</ref> |
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== References == |
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==References== |
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{{Reflist}} |
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{{Reflist}} |
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==External links== |
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{{Inorganic-compound-stub}} |
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*{{Commonscatinline}} |
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{{oxygenallotropes}} |
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