| Revision as of 18:17, 28 July 2011 editCheMoBot (talk | contribs)Bots141,565 edits Updating {{chembox}} (no changed fields - added verified revid - updated 'UNII_Ref', 'ChEMBL_Ref', 'KEGG_Ref') per Chem/Drugbox validation (report errors← Previous edit |
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{{short description|Chemical compound}}{{Chembox |
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{{Unreferenced|date=February 2007}} |
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| Watchedfields = changed |
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| verifiedrevid = 441909944 |
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{{Chembox |
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| verifiedrevid = 441672667 |
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| ImageFile2 = Tetrahydrofuran-3D-balls.png |
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| ImageFile2 = Tetrahydrofuran-3D-balls.png |
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| ImageFile2_Ref = {{chemboximage|correct|??}} |
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| ImageFile2_Ref = {{chemboximage|correct|??}} |
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| ImageSize2 = 121 |
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| ImageSize2 = 121 |
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| ImageName2 = Ball and stick model of deuterated THF |
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| ImageName2 = Ball and stick model of deuterated THF |
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| ImageFileL1 = THF-d8.png |
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| ImageFileL1 = Gedeutereerd THF.png |
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| ImageFileL1_Ref = {{chemboximage|correct|??}} |
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| ImageFileL1_Ref = {{chemboximage|correct|??}} |
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| ImageSizeL1 = 121 |
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| ImageNameL1 = Skeletal formula of deuterated THF |
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| ImageNameL1 = Skeletal formula of deuterated THF |
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| ImageFileR1 = Tetrahydrofuran-3D-vdW.png |
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| ImageFileR1 = Tetrahydrofuran-3D-vdW.png |
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| ImageFileR1_Ref = {{chemboximage|correct|??}} |
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| ImageFileR1_Ref = {{chemboximage|correct|??}} |
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| ImageSizeR1 = 121 |
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| ImageNameR1 = Spacefill model of deuterated THF |
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| ImageNameR1 = Spacefill model of deuterated THF |
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| Section1 = {{Chembox Identifiers |
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|Section1={{Chembox Identifiers |
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| CASNo_Ref = {{cascite|correct|??}} |
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| CASNo = 1693-74-9 |
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| PubChem = 80290 |
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| CASNo = 1693-74-9 |
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| PubChem = 80290 |
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| PubChem_Ref = {{Pubchemcite|correct|pubchem}} |
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| ChemSpiderID = 72531 |
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| ChemSpiderID = 72531 |
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| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} |
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| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} |
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| EINECS = 216-898-4 |
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| EINECS = 216-898-4 |
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| UNNumber = 2056 |
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| UNNumber = 2056 |
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| Beilstein = 111854 |
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| Beilstein = 111854 |
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| SMILES = C1()OC()()C()()C1() |
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| SMILES = C1()OC()()C()()C1() |
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| StdInChI = 1S/C4H8O/c1-2-4-5-3-1/h1-4H2/i1D2,2D2,3D2,4D2 |
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| StdInChI = 1S/C4H8O/c1-2-4-5-3-1/h1-4H2/i1D2,2D2,3D2,4D2 |
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| StdInChI_Ref = {{stdinchicite|correct|chemspider}} |
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| StdInChI_Ref = {{stdinchicite|correct|chemspider}} |
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| StdInChIKey = WYURNTSHIVDZCO-SVYQBANQSA-N |
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| StdInChIKey = WYURNTSHIVDZCO-SVYQBANQSA-N |
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| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}} |
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| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}} |
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}} |
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}} |
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| Section2 = {{Chembox Properties |
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|Section2={{Chembox Properties |
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| Formula = {{Chem|C|4}}{{Chem|2|H|8|O}} |
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| Formula ={{Chem|C|4|D|8|O}} |
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| MolarMass = 80.1550 g mol<sup>-1</sup> |
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| MolarMass = 80.1550 g mol<sup>−1</sup> |
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| Appearance = Colourless liquid |
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| ExactMass = 80.107728846 g mol<sup>-1</sup> |
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| Density = 985 mg cm<sup>−3</sup> |
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| Apprearance = Colourless liquid |
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| MeltingPtC = -106 |
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| Density = 985 mg cm<sup>-3</sup> |
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| MeltingPtC = -106 |
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| BoilingPtC = 65 to 66 |
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| BoilingPtCL = 65 |
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| BoilingPtCH = 66 |
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}} |
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}} |
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| Section3 = {{Chembox Hazards |
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|Section3={{Chembox Hazards |
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| GHSPictograms = {{GHS flame}} {{GHS exclamation mark}} |
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| GHSPictograms = {{GHS flame}} {{GHS exclamation mark}} |
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| GHSSignalWord = '''DANGER''' |
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| GHSSignalWord = '''DANGER''' |
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| HPhrases = {{H-phrases|225|319|335}} |
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| HPhrases = {{H-phrases|225|319|335}} |
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| PPhrases = {{P-phrases|210|261|305+351+338}} |
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| PPhrases = {{P-phrases|210|261|305+351+338}} |
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| FlashPtC = −17 |
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| EUClass = {{Hazchem F}} {{Hazchem Xi}} |
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| NFPA-F = 3 |
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| RPhrases = {{R11}}, {{R19}}, {{R36/37}} |
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| NFPA-H = 2 |
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| SPhrases = {{S16}}, {{S29}}, {{S33}} |
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| FlashPt = -17 °C |
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| NFPA-R = 0 |
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| NFPA-F = 3 |
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| NFPA-H = 2 |
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| NFPA-R = 0 |
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}} |
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}} |
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}} |
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}} |
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'''Deuterated tetrahydrofuran''' ('''d<sub>8</sub>-THF'''), is a colourless, organic liquid at ]. This ] has the chemical formula (C<sup>2</sup>H<sub>2</sub>)<sub>4</sub>O, and is the ] of ]. Deuterated THF is a rarely used as a solvent in ] due to its expense.{{Citation needed|date = July 2011}} |
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'''Deuterated tetrahydrofuran''' ('''d<sub>8</sub>-THF''') is a colourless, organic liquid at ].<ref>{{Cite journal |last1=Andersson |first1=O. |last2=Suga |first2=H. |date=1996-01-01 |title=Thermal conductivity of normal and deuterated tetrahydrofuran clathrate hydrates |url=https://dx.doi.org/10.1016/0022-3697%2895%2900157-3 |journal=Journal of Physics and Chemistry of Solids |language=en |volume=57 |issue=1 |pages=125–132 |doi=10.1016/0022-3697(95)00157-3 |issn=0022-3697}}</ref> This ] has the chemical formula C<sub>4</sub>D<sub>8</sub>O, and is an ] of ].<ref>{{Cite journal |last1=David |first1=W. I. F. |last2=Ibberson |first2=R. M. |date=1992-02-15 |title=A reinvestigation of the structure of tetrahydrofuran by high-resolution neutron powder diffraction |url=http://scripts.iucr.org/cgi-bin/paper?S0108270191008582 |journal=Acta Crystallographica Section C: Crystal Structure Communications |language=en |volume=48 |issue=2 |pages=301–303 |doi=10.1107/S0108270191008582 |issn=0108-2701}}</ref> Deuterated THF is used as a solvent in ], though its expense can often be prohibitive.{{Citation needed|date = July 2011}} |
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== References == |
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{{Heterocyclic-stub}} |
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{{Reflist}} |
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{{List of NMR solvents}} |
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{{List of NMR solvents}} |
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] |
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] |
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{{NMR-stub}} |
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{{Heterocyclic-stub}} |