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{{chembox |
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{{chembox |
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| verifiedrevid = 371142740 |
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| verifiedrevid = 428839881 |
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| ImageFile = Furantetracarboxylic acid.svg |
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| ImageFile = Furantetracarboxylic acid.svg |
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| ImageSize = 250px |
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| ImageSize = 250px |
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| IUPACName = furan-2,3,4,5-tetracarboxylic acid |
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| PIN = Furantetracarboxylic acid |
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| OtherNames = |
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| OtherNames = |
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| Section1 = {{Chembox Identifiers |
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|Section1={{Chembox Identifiers |
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| CASNo = 20416-04-0 |
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| CASNo = 20416-04-0 |
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| CASNo_Ref = {{cascite|correct|CAS}} |
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| UNII_Ref = {{fdacite|correct|FDA}} |
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| UNII = 526V46EZC7 |
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| PubChem = 237617 |
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| PubChem = 237617 |
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| SMILES = C1(=C(OC(=C1C(=O)O)C(=O)O)C(=O)O)C(=O)O }} |
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| SMILES = C1(=C(OC(=C1C(=O)O)C(=O)O)C(=O)O)C(=O)O |
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| ChemSpiderID = 207476 |
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| Section2 = {{Chembox Properties |
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| StdInChI = 1S/C8H4O9/c9-5(10)1-2(6(11)12)4(8(15)16)17-3(1)7(13)14/h(H,9,10)(H,11,12)(H,13,14)(H,15,16) |
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| StdInChIKey = IREPGQRTQFRMQR-UHFFFAOYSA-N}} |
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|Section2={{Chembox Properties |
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| Formula = C<sub>8</sub>H<sub>4</sub>O<sub>9</sub> |
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| Formula = C<sub>8</sub>H<sub>4</sub>O<sub>9</sub> |
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| MolarMass = 244.11 g/mol |
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| MolarMass = 244.11 g/mol |
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| BoilingPt = |
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| BoilingPt = |
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| Solubility = }} |
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| Solubility = }} |
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| Section3 = {{Chembox Hazards |
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|Section3={{Chembox Hazards |
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| MainHazards = |
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| FlashPt = |
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| Autoignition = }} |
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| AutoignitionPt = }} |
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}} |
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In ], '''furantetracarboxylic acid''' is an ] with formula {{chem|C|8|H|4|O|9}}, or (C<sub>4</sub>O)(-(CO)OH)<sub>4</sub>, which can be viewed as deriving from ] {{chem|C|4|H|4|O}} through replacement of the four hydrogen atoms by ] ] -(CO)OH. |
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In ], '''furantetracarboxylic acid''' is an ] with formula {{chem|C|8|H|4|O|9}}, or (C<sub>4</sub>O)(-(CO)OH)<sub>4</sub>, which can be viewed as deriving from ] {{chem|C|4|H|4|O}} through replacement of the four hydrogen atoms by ] ] -(CO)OH. |
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By removal of four protons, the acid is expected to yield the anion {{chem|C|8|O|9|4-}}, '''furantetracarboxylate''', which is one of the ]s (consisting solely of ] and ]. By loss of 1 through 3 ]s it forms the anions {{chem|C|8|H|3|O|9|-}}, {{chem|C|8|H|2|O|9|2-}}, and {{chem|C|8|H|1|O|9|3-}}, called respectivey '''trihydrogen-''', '''dihydrogen'''-, and '''hydrogenfurantetracarboxylate'''. The same names are used for the corresponding ]s. |
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By removal of four protons, the acid is expected to yield the anion {{chem|C|8|O|9|4-}}, '''furantetracarboxylate''', which is one of the ]s (consisting solely of ] and ]. By loss of 1 through 3 ]s it forms the anions {{chem|C|8|H|3|O|9|-}}, {{chem|C|8|H|2|O|9|2-}}, and {{chem|C|8|HO|9|3-}}, called respectively '''trihydrogen-''', '''dihydrogen'''-, and '''hydrogenfurantetracarboxylate'''. The same names are used for the corresponding ]s. |
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The acid can be obtained by from dioxalylsuccinate.<ref name=zapa> |
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The acid can be obtained by from dioxalylsuccinate.<ref name=zapa> |
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The salt ] trihydrogenfurantetracarboxylate {{chem|RbH|3|C|8|O|9}} crystallizes as white needles.<ref name=paul> |
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The salt ] trihydrogenfurantetracarboxylate {{chem|RbH|3|C|8|O|9}} crystallizes as white needles.<ref name=paul> |
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Iain C. Paul and Leslie L. Martin (1967), ''The crystal and molecular structure of the monorubidium salt of furantetracarboxylic acid''. Acta Cryst. volume 22 pages 559-567 {{doi|10.1107/S0365110X67001136}} |
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Iain C. Paul and Leslie L. Martin (1967), ''The crystal and molecular structure of the monorubidium salt of furantetracarboxylic acid''. Acta Crystallogr. volume 22 pages 559-567 {{doi|10.1107/S0365110X67001136}} |
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</ref> |
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