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Revision as of 23:26, 12 May 2011 editCheMoBot (talk | contribs)Bots141,565 edits Updating {{chembox}} (no changed fields - added verified revid - updated 'UNII_Ref', 'ChemSpiderID_Ref', 'StdInChI_Ref', 'StdInChIKey_Ref', 'ChEMBL_Ref', 'KEGG_Ref') per Chem/Drugbox validation (← Previous edit Latest revision as of 20:19, 18 January 2024 edit undoMichael7604 (talk | contribs)Extended confirmed users8,895 edits more specific category 
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{{chembox {{chembox
| verifiedrevid = 371142740 | verifiedrevid = 428839881
| ImageFile = Furantetracarboxylic acid.svg | ImageFile = Furantetracarboxylic acid.svg
| ImageSize = 250px | ImageSize = 250px
| IUPACName = furan-2,3,4,5-tetracarboxylic acid | PIN = Furantetracarboxylic acid
| OtherNames = | OtherNames =
| Section1 = {{Chembox Identifiers |Section1={{Chembox Identifiers
| CASNo = 20416-04-0 | CASNo = 20416-04-0
| CASNo_Ref = {{cascite|correct|CAS}}
| UNII_Ref = {{fdacite|correct|FDA}}
| UNII = 526V46EZC7
| PubChem = 237617 | PubChem = 237617
| SMILES = C1(=C(OC(=C1C(=O)O)C(=O)O)C(=O)O)C(=O)O }} | SMILES = C1(=C(OC(=C1C(=O)O)C(=O)O)C(=O)O)C(=O)O
| ChemSpiderID = 207476
| Section2 = {{Chembox Properties
| StdInChI = 1S/C8H4O9/c9-5(10)1-2(6(11)12)4(8(15)16)17-3(1)7(13)14/h(H,9,10)(H,11,12)(H,13,14)(H,15,16)

| StdInChIKey = IREPGQRTQFRMQR-UHFFFAOYSA-N}}
|Section2={{Chembox Properties
| Formula = C<sub>8</sub>H<sub>4</sub>O<sub>9</sub> | Formula = C<sub>8</sub>H<sub>4</sub>O<sub>9</sub>
| MolarMass = 244.11 g/mol | MolarMass = 244.11 g/mol
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| BoilingPt = | BoilingPt =
| Solubility = }} | Solubility = }}
| Section3 = {{Chembox Hazards |Section3={{Chembox Hazards
| MainHazards = | MainHazards =
| FlashPt = | FlashPt =
| Autoignition = }} | AutoignitionPt = }}
}} }}


In ], '''furantetracarboxylic acid''' is an ] with formula {{chem|C|8|H|4|O|9}}, or (C<sub>4</sub>O)(-(CO)OH)<sub>4</sub>, which can be viewed as deriving from ] {{chem|C|4|H|4|O}} through replacement of the four hydrogen atoms by ] ] -(CO)OH. In ], '''furantetracarboxylic acid''' is an ] with formula {{chem|C|8|H|4|O|9}}, or (C<sub>4</sub>O)(-(CO)OH)<sub>4</sub>, which can be viewed as deriving from ] {{chem|C|4|H|4|O}} through replacement of the four hydrogen atoms by ] ] -(CO)OH.


By removal of four protons, the acid is expected to yield the anion {{chem|C|8|O|9|4-}}, '''furantetracarboxylate''', which is one of the ]s (consisting solely of ] and ]. By loss of 1 through 3 ]s it forms the anions {{chem|C|8|H|3|O|9|-}}, {{chem|C|8|H|2|O|9|2-}}, and {{chem|C|8|H|1|O|9|3-}}, called respectivey '''trihydrogen-''', '''dihydrogen'''-, and '''hydrogenfurantetracarboxylate'''. The same names are used for the corresponding ]s. By removal of four protons, the acid is expected to yield the anion {{chem|C|8|O|9|4-}}, '''furantetracarboxylate''', which is one of the ]s (consisting solely of ] and ]. By loss of 1 through 3 ]s it forms the anions {{chem|C|8|H|3|O|9|-}}, {{chem|C|8|H|2|O|9|2-}}, and {{chem|C|8|HO|9|3-}}, called respectively '''trihydrogen-''', '''dihydrogen'''-, and '''hydrogenfurantetracarboxylate'''. The same names are used for the corresponding ]s.


The acid can be obtained by from dioxalylsuccinate.<ref name=zapa> The acid can be obtained by from dioxalylsuccinate.<ref name=zapa>
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The salt ] trihydrogenfurantetracarboxylate {{chem|RbH|3|C|8|O|9}} crystallizes as white needles.<ref name=paul> The salt ] trihydrogenfurantetracarboxylate {{chem|RbH|3|C|8|O|9}} crystallizes as white needles.<ref name=paul>
Iain C. Paul and Leslie L. Martin (1967), ''The crystal and molecular structure of the monorubidium salt of furantetracarboxylic acid''. Acta Cryst. volume 22 pages 559-567 {{doi|10.1107/S0365110X67001136}} Iain C. Paul and Leslie L. Martin (1967), ''The crystal and molecular structure of the monorubidium salt of furantetracarboxylic acid''. Acta Crystallogr. volume 22 pages 559-567 {{doi|10.1107/S0365110X67001136}}
</ref> </ref>


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] ]
] ]