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Revision as of 00:57, 12 August 2011 editSmokefoot (talk | contribs)Autopatrolled, Extended confirmed users, Pending changes reviewers, Rollbackers74,227 edits trim procedural details (WP:NOTMANUAL)← Previous edit		Latest revision as of 18:20, 9 September 2022 edit undo88.115.34.218 (talk) →Preparation
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	{{chembox		{{Chembox
			| Verifiedfields = changed
	| verifiedrevid = 293599230
			| Watchedfields = changed
	| Name = Isopropyl iodide
			| verifiedrevid = 444362078
	| ImageFile1 = isopropyl iodide stick.png
			| ImageFile = isopropyl iodide stick.png
	| ImageSize1 = 150px
			| ImageFile_Ref = {{chemboximage|correct|??}}
	| ImageName1 =
			| ImageSize = 100
	| ImageFile = IsopropylIodide.png
			| ImageName = Skeletal formula of isopropyl iodide
	| ImageSize =200px
			| ImageFile1 = IsopropylIodide.png
	| ImageName =
			| ImageFile1_Ref = {{chemboximage|correct|??}}
	| IUPACName = 2-iodopropane
			| ImageSize1 = 160
	| OtherNames = iododimethylmethane, isopropyl iodide, 2-propyliodide, sec-propyl iodide
			| ImageName1 = Spacefill model of isopropyl iodide
	| Section1 = {{Chembox Identifiers
			| PIN = 2-Iodopropane<ref>{{Cite web|title=isopropyl iodide - Compound Summary|url=https://pubchem.ncbi.nlm.nih.gov/summary/summary.cgi?cid=6362&loc=ec_rcs|work=PubChem Compound|publisher=National Center for Biotechnology Information|access-date=3 March 2012|location=USA|date=27 March 2005|at=Identification and Related Records}}</ref>
	| SMILES = CC(I)C
			|Section1={{Chembox Identifiers
	| CASNo = 75-30-9
			| CASNo = 75-30-9
	| CASNo_Ref = {{cascite}}
			| CASNo_Ref = {{cascite|correct|CAS}}
	| RTECS = TZ4200000
			| UNII_Ref = {{fdacite|correct|FDA}}
	}}
			| UNII = 67K05OPZ0E
	| Section2 = {{Chembox Properties
			| PubChem = 6362
	| Formula = C<sub>3</sub>H<sub>7</sub>I
	| MolarMass = 169.99		| ChemSpiderID = 6122
			| ChemSpiderID_Ref = {{chemspidercite|changed|chemspider}}
	| Appearance = Colourless liquid
	| Density = 1.703		| EINECS = 200-859-3
			| UNNumber = 2392
	| Solubility = 0.14 g/100 ml at 12.5 °C
			| MeSHName = isopropyl+iodide
	| Solubility1 = fully ]
	| Solvent1 = ethanol		| RTECS = TZ4200000
			| Beilstein = 1098244
	| Solubility2 = fully ]
			| SMILES = CC(C)I
	| Solvent2 = diethyl ether
			| StdInChI_Ref = {{stdinchicite|changed|chemspider}}
	| Solubility3 = fully ]
			| StdInChI = 1S/C3H7I/c1-3(2)4/h3H,1-2H3
	| Solvent3 = chloroform
			| StdInChIKey = FMKOJHQHASLBPH-UHFFFAOYSA-N
	| Solubility4 = fully ]
			| StdInChIKey_Ref = {{chemspidercite|correct|chemspider}}
	| Solvent4 = benzene
	| RefractIndex = 1.4997
	| MeltingPtC = -90.0
	| BoilingPtC = 89.5
	| pKa =
	| Viscosity = 8.841 c] at 0 °C<br/>6.971 c] at 20 °C
	| Dipole =
	}}
	| Section7 = {{Chembox Hazards
	| ExternalMSDS =
	| FlashPt = 42 °C
	| MainHazards = Possible carcinogen. Harmful if swallowed, inhaled and in contact with skin. Eye, respiratory and mucous membrane irritant.
	| NFPA-H =
	| NFPA-F =
	| NFPA-R =
	| NFPA-O =
	| RPhrases = R20 R21 R22 R36 R37 R38 R40
	| SPhrases = S16 S23 S26 S36
	}}
	| Section8 = {{Chembox Related
	| Function = ]s
	| OtherFunctn = ]<br>]<br>] }}
	}}		}}
			|Section2={{Chembox Properties
			| C=3 | H=7 | I=1
	'''Isopropyl iodide''' is the ] with the ] (CH<sub>3</sub>)<sub>2</sub>CHI. It is ], ], and volatile. Organic iodides are light-sensitive and take on a yellow colour upon storage, owing to the formation of ].
			| Appearance = Colourless liquid
			| Density = 1.703 g mL<sup>−1</sup>
			| BoilingPtK = 361.9 to 362.9
			| MeltingPtK = 183.15
			| Solubility = 1.4 g L<sup>−1</sup> (at 12.5 °C)
			| Solvent1 = chloroform
			| Solubility1 = Miscible
			| Solvent2 = ethanol
			| Solubility2 = Miscible
			| Solvent3 = diethyl ether
			| Solubility3 = Miscible
			| Solvent4 = benzene
			| Solubility4 = Miscible
			| HenryConstant = 890 nmol Pa<sup>−1</sup> kg<sup>−1</sup>
			| RefractIndex = 1.4997
			| Viscosity = 6.971 mPa (at 20 °C)
			}}
			|Section3={{Chembox Thermochemistry
			| DeltaHf = −77.2–−72.6 kJ mol<sup>−1</sup>
			| HeatCapacity = 137.3 J K<sup>−1</sup> mol<sup>−1</sup>
			}}
			|Section4={{Chembox Hazards
			| GHSPictograms = {{GHS flame}} {{GHS exclamation mark}}
			| GHSSignalWord = '''WARNING'''
			| HPhrases = {{H-phrases|226|302}}
			| FlashPtC = 42
			}}
			|Section5={{Chembox Related
			| OtherFunction_label = alkanes
			| OtherFunction = {{Unbulleted list|]|]|]|]|]|]}}
			| OtherCompounds = ]
			}}
			}}
			'''Isopropyl iodide''' is the ] with the ] (CH<sub>3</sub>)<sub>2</sub>CHI. It is ], ], and volatile. Organic iodides are light-sensitive and take on a yellow colour upon storage, owing to the formation of ].
	==Preparation==		==Preparation==
	Isopropyl iodide is prepared by iodination of ] using ] or, equivalently, with a mixture of ], ], and ].<ref name="merck">Merck Index of Chemicals and Drugs, 9th ed., monograph 5074</ref> An alternative preparation involves the reaction of 2-propyl bromide with an acetone solution of potassium iodide (KI):<ref>Textbook of Practical Organic Chemistry, 5th Edition, Prentice Hall, 1989</ref>		Isopropyl iodide is prepared by iodination of ] using ] or, equivalently, with a mixture of ], ], and ].<ref name="merck">Merck Index of Chemicals and Drugs, 9th ed., monograph 5074</ref> An alternative preparation involves the reaction of ] with an acetone solution of ] (]):<ref>Textbook of Practical Organic Chemistry, 5th Edition, Prentice Hall, 1989</ref>
	:(CH<sub>3</sub>)<sub>2</sub>CHBr + KI → (CH<sub>3</sub>)<sub>2</sub>CHI + KBr		:(CH<sub>3</sub>)<sub>2</sub>CHBr + NaI → (CH<sub>3</sub>)<sub>2</sub>CHI + NaBr
	==References==		==References==
	{{reflist|1}}		{{Reflist}}
			{{Organohalide-stub}}
	]
	{{organohalide-stub}}
	]		]
			]
	]
			]
	]