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{{chembox |
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{{Chembox |
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| Verifiedfields = changed |
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| verifiedrevid = 388258909 |
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| Watchedfields = changed |
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| Name = methyl phenylacetate |
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| verifiedrevid = 421473105 |
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| ImageFile = Methyl phenylacetate.png |
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| Name = methyl phenylacetate |
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| ImageSize = 200px |
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| ImageName = Skeletal formula of methyl phenylacetate |
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| ImageFile = Methyl phenylacetate.svg |
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| ImageName = Skeletal formula of methyl phenylacetate |
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| ImageFile1 = Methyl-phenylacetate-3D-balls.png |
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| ImageFile1 = Methyl-phenylacetate-3D-balls.png |
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| ImageSize1 = 210px |
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| ImageSize1 = 210px |
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| ImageName1 = Ball-and-stick model |
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| ImageName1 = Ball-and-stick model |
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| IUPACName = Methyl 2-phenylacetate |
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| PIN = Methyl phenylacetate <!-- the locant ‘2’ for acetic acid is not cited --> |
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| OtherNames = Methyl 2-phenyl acetate, Methyl benzene acetate |
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| OtherNames = Methyl 2-phenylacetate<br />Methyl benzene acetate |
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| Section1 = {{Chembox Identifiers |
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|Section1={{Chembox Identifiers |
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| CASNo_Ref = {{cascite}} |
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| CASNo_Ref = {{cascite|correct|CAS}} |
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| CASNo = 101-41-7 |
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| CASNo = 101-41-7 |
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| UNII_Ref = {{fdacite|changed|FDA}} |
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| UNII = D4PDC41X96 |
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| EINECS = 202-940-9 |
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| EINECS = 202-940-9 |
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| InChI = 1/C9H10O2/c1-11-9(10)7-8-5-3-2-4-6-8/h2-6H,7H2,1H3 |
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| PubChem = 7559 |
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| PubChem = 7559 |
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| SMILES = COC(=O)CC1=CC=CC=C1 |
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| SMILES = COC(=O)CC1=CC=CC=C1 |
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| Beilstein = 878795 |
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| Beilstein = 878795 |
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| ChemSpiderID_Ref = {{chemspidercite|changed|chemspider}} |
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}} |
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| ChemSpiderID = 7278 |
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| Section2 = {{Chembox Properties |
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| InChI = 1/C9H10O2/c1-11-9(10)7-8-5-3-2-4-6-8/h2-6H,7H2,1H3 |
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| InChIKey = CRZQGDNQQAALAY-UHFFFAOYAC |
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| StdInChI_Ref = {{stdinchicite|changed|chemspider}} |
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| StdInChI = 1S/C9H10O2/c1-11-9(10)7-8-5-3-2-4-6-8/h2-6H,7H2,1H3 |
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| StdInChIKey_Ref = {{stdinchicite|changed|chemspider}} |
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| StdInChIKey = CRZQGDNQQAALAY-UHFFFAOYSA-N |
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| RTECS = |
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| MeSHName = C024906 |
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}} |
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|Section2={{Chembox Properties |
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| Formula = C<sub>9</sub>H<sub>10</sub>O<sub>2</sub> |
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| Formula = C<sub>9</sub>H<sub>10</sub>O<sub>2</sub> |
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| MolarMass = 150.1745 g mol<sup>-1</sup> |
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| MolarMass = 150.1745 g mol<sup>−1</sup> |
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| MolarMass_notes = |
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| MolarMass_notes = |
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| Appearance = Colorless liquid |
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| Appearance = Colorless liquid |
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| Density = 1.055 g/cm<sup>3</sup> (± 0.06) |
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| Density = 1.055±0.060{{nbsp}}g/cm<sup>3</sup> |
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| MeltingPt = 50 °C |
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| MeltingPtC = 50 |
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| Melting_notes = |
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| MeltingPt_notes = |
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| BoilingPt = 218 °C |
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| BoilingPtC = 218 |
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| Boiling_notes = |
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| BoilingPt_notes = |
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| SublimationConditions = |
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| SublimationConditions = |
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| Solubility = 2070 mg/L |
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| Solubility = 2070 mg/L |
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| RefractIndex = 1.505 (± 0.02) at 20°C |
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| RefractIndex = 1.505±0.020 at 20 °C |
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| Viscosity = |
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| Viscosity = |
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| CriticalRelativeHumidity = |
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| Dipole = |
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| Dipole = |
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| VaporPressure = 17.3 Pa |
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| VaporPressure = 17.3{{nbsp}}Pa |
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| MagSus = −92.73×10<sup>−6</sup> cm<sup>3</sup>/mol |
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}} |
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| Section3 = {{Chembox Hazards |
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|Section3={{Chembox Hazards |
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| FlashPt = 90.6 °C |
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| FlashPtC = 90.6 |
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| NFPA-H = 1 |
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| NFPA-H = 1 |
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| NFPA-F = 2 |
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| NFPA-F = 2 |
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| NFPA-R = 0 |
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| NFPA-R = 0 |
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| NFPA-O = |
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| NFPA-S = |
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}} |
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}}<!-- |
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}}<!-- |
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| ] |
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| ] |
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| {{{refractive_index_(nD20)|1.50600 - 1.50900 at 20.00 °C}}}--> |
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| {{{refractive_index_(nD20)|1.50600 - 1.50900 at 20.00 °C}}}--> |
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'''Methyl phenylacetate''' is an ] that is the ] formed from ] and ], with the structural formula C<sub>6</sub>H<sub>5</sub>CH<sub>2</sub>COOCH<sub>3</sub>. It is a clear colorless liquid that is only slightly soluble in water, but very soluble in most organic solvents. |
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'''Methyl phenylacetate''' is an ] that is the ] of ], with the structural formula <chem>C_6H_5CH_2COOCH_3</chem>. It is a colorless liquid that is only slightly soluble in water, but soluble in most organic solvents. |
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Methyl phenylacetate has a strong odor similar to honey. The odor is so strong that recommended smelling is of a solution with 10% or less methyl phenylacetate. This compound also naturally occurs in ], ], ], ], ] and some ]. |
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Methyl phenylacetate has a strong odor similar to honey. This compound also occurs in ], ], ], ], ], and some ]. It is used in the flavor industry and in perfumes to impart honey scents.<ref>{{Cite web |
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| title = Methyl Phenyl Acetate |
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| url = http://www.thegoodscentscompany.com/data/rw1008431.html |
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| date = February 22, 2007 |
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| publisher = The Good Scents Company |
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| access-date = January 22, 2008 |
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}}</ref> |
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], precursor to cyclopropanation agents, is prepared by treating methyl phenylacetate with p-acetamidobenzenesulfonyl azide in the presence of base.<ref>{{Cite journal |
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Methyl phenylacetate is used in the flavor industry and in perfumes to impart honey scents. |
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| title = Methyl Phenyldiazoacetate |
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| journal = ] |
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| publisher = ] |
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| first1 = Huw M. L. | last1 = Davies |
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| first2 = Wen‐hao | last2 = Hu |
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| first3 = Dong | last3 = Xing |
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| date = 2015-04-01 |
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| pages = 1–10 |
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| doi = 10.1002/047084289X.rn00444.pub2 |
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| isbn = 9780470842898 |
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}}</ref> |
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==References== |
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==References== |
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{{Reflist}} |
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{{Reflist}} |
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* "Methyl Phenyl Acetate."(February 22, 2007). The Good Scents Company. Retrieved on January 22, 2008. |
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