| Revision as of 11:38, 5 December 2011 editBeetstra (talk | contribs)Edit filter managers, Administrators172,031 edits Saving copy of the {{chembox}} taken from revid 429136982 of page Pentacarbonylhydridorhenium for the Chem/Drugbox validation project (updated: ''). |
Latest revision as of 07:20, 25 June 2024 edit JWBE (talk | contribs)Extended confirmed users10,126 edits removed Category:Metal hydrides; added Category:Hydrido complexes using HotCat |
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{{ambox | text = This page contains a copy of the infobox ({{tl|chembox}}) taken from revid of page ] with values updated to verified values.}} |
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{{chembox |
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{{chembox |
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| Watchedfields = changed |
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| verifiedrevid = 400843174 |
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| verifiedrevid = 464197805 |
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| ImageFile = Pentacarbonylhydridorhenium.png |
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| ImageFile = Pentacarbonylhydridorhenium.svg |
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| ImageSize = |
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| ImageSize = |
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| ImageFile1 = Pentacarbonylhydridorhenium-3D-balls.png |
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| ImageFile1 = Pentacarbonylhydridorhenium-3D-balls.png |
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| IUPACName = pentacarbonylhydridorhenium |
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| IUPACName = pentacarbonylhydridorhenium |
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| OtherNames = |
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| OtherNames = |
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| Section1 = {{Chembox Identifiers |
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|Section1={{Chembox Identifiers |
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| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} |
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| ChemSpiderID_Ref = {{chemspidercite|changed|chemspider}} |
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| ChemSpiderID = 21106461 |
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| ChemSpiderID = |
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| InChI = 1/5CO.Re.H/c5*1-2;;/rC5HO5Re/c6-1-11(2-7,3-8,4-9)5-10/h11H |
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| InChI = 1/5CO.Re.H/c5*1-2;;/rC5HO5Re/c6-1-11(2-7,3-8,4-9)5-10/h11H |
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| InChIKey = CNPMTNYPOCHKNC-AUQHHBNCAA |
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| InChIKey = CNPMTNYPOCHKNC-AUQHHBNCAA |
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| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}} |
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| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}} |
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| StdInChIKey = CNPMTNYPOCHKNC-UHFFFAOYSA-N |
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| StdInChIKey = CNPMTNYPOCHKNC-UHFFFAOYSA-N |
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| CASNo = |
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| CASNo = 16457-30-0 |
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| PubChem = |
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| PubChem = 139031000 |
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| SMILES = C(#O)(C#O)(C#O)(C#O)C#O |
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| SMILES = C(#O)(C#O)(C#O)(C#O)C#O |
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}} |
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| Section2 = {{Chembox Properties |
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|Section2={{Chembox Properties |
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| Formula = ReH(CO)<sub>5</sub> |
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| Formula = ReH(CO)<sub>5</sub> |
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| MolarMass = 327.265 g/mol |
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| MolarMass = 327.265 g/mol |
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| Appearance = Colorless liquid |
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| Appearance = Colorless liquid |
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| Density = 2.30 g/mL, liquid |
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| Density = 2.30 g/mL, liquid |
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| MeltingPt = 12.5 °C |
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| MeltingPtC = 12.5 |
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| BoilingPt = 100 °C (decomposes) |
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| BoilingPtC = 100 |
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| BoilingPt_notes = (decomposes) |
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| Solubility = Insoluble |
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| Solubility = Insoluble |
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| Section3 = {{Chembox Hazards |
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| MainHazards = Flammable |
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| FlashPt = |
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| MainHazards = Flammable |
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| FlashPt = |
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'''Pentacarbonylhydridorhenium''' is a ] with the ] ReH(CO)<sub>5</sub>. This colorless liquid is a weak acid and represents one of the most important derivatives of ] (Re<sub>2</sub>(CO)<sub>10</sub>). It is synthesized by treating a ]ic solution of ] (Re(CO)<sub>5</sub>Br) with zinc and ] (HOAc).<ref name=Urb>{{cite journal | author = Michael A. Urbancic, John R. Shapley | title = Pentacarbonylhydridorhenium | journal = ] | volume = 28 | pages = 165–8 | year = 1990 | doi =10.1002/9780470132593.ch43 | isbn = 9780470132593 }}</ref> |
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: Re(CO)<sub>5</sub>Br + Zn + HOAc → ReH(CO)<sub>5</sub> + ZnBrOAc |
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It is moderately sensitive to light: samples turn yellow due to the formation of the ] Re<sub>3</sub>H(CO)<sub>14</sub> |
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: 3 Re(CO)<sub>5</sub>H → Re<sub>3</sub>H(CO)<sub>14</sub> + H<sub>2</sub> + CO |
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At 100 °C, it decomposes to Re<sub>2</sub>(CO)<sub>10</sub>:<ref name=Urb/> |
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: 2 Re(CO)<sub>5</sub>H → H<sub>2</sub> + Re<sub>2</sub>(CO)<sub>10</sub> |
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==References== |
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<references/> |
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{{Rhenium compounds}} |
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{{Carbonyl complexes}} |
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] |
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] |
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] |