| Revision as of 16:15, 12 May 2011 editCheMoBot (talk | contribs)Bots141,565 edits Updating {{chembox}} (no changed fields - added verified revid - updated 'UNII_Ref', 'ChemSpiderID_Ref', 'StdInChI_Ref', 'StdInChIKey_Ref', 'ChEMBL_Ref', 'KEGG_Ref') per Chem/Drugbox validation (← Previous edit |
Latest revision as of 17:46, 22 September 2023 edit undo50.206.123.142 (talk)No edit summary |
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{{chembox |
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{{chembox |
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| Verifiedfields = changed |
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| verifiedrevid = 288276716 |
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| Watchedfields = changed |
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| verifiedrevid = 428775889 |
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| ImageFileL1 = Pentafluoroethyl-iodide-2D-skeletal.png |
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| ImageFileL1 = Pentafluoroethyl-iodide-2D-skeletal.png |
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| ImageSizeL1 = 120px |
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| ImageSizeL1 = 120px |
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| ImageFileR1 = Pentafluoroethyl-iodide-3D-vdW.png |
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| ImageFileR1 = Pentafluoroethyl-iodide-3D-vdW.png |
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| ImageSizeR1 = 120px |
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| ImageSizeR1 = 120px |
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| IUPACName = 1,1,1,2,2-pentafluoro-2-iodo-ethane |
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| PIN = Pentafluoro(iodo)ethane |
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| OtherNames = |
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| OtherNames = |
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| Section1 = {{Chembox Identifiers |
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|Section1={{Chembox Identifiers |
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| CASNo_Ref = {{cascite|correct|??}} |
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| CASNo = 354-64-3 |
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| CASNo = 354-64-3 |
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| PubChem = 9636 |
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| PubChem = 9636 |
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| SMILES = }} |
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| EINECS = 206-566-7 |
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| ChemSpiderID_Ref = {{chemspidercite|changed|chemspider}} |
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| Section2 = {{Chembox Properties |
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| C=2 | F=5 | I=1 |
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| ChemSpiderID = 9259 |
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| UNII = 0E13B713QU |
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| MolarMass = 245.918 g/mol |
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| SMILES = C(C(F)(F)I)(F)(F)F |
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| Appearance = |
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| InChI = 1/C2F5I/c3-1(4,5)2(6,7)8 |
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| Density = |
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| InChIKey = UXPOJVLZTPGWFX-UHFFFAOYAR |
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| MeltingPt = |
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| StdInChI_Ref = {{stdinchicite|changed|chemspider}} |
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| BoilingPt = |
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| StdInChI = 1S/C2F5I/c3-1(4,5)2(6,7)8 |
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| Solubility = }} |
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| StdInChIKey_Ref = {{stdinchicite|changed|chemspider}} |
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| Section3 = {{Chembox Hazards |
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| StdInChIKey = UXPOJVLZTPGWFX-UHFFFAOYSA-N}} |
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| MainHazards = |
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|Section2={{Chembox Properties |
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| FlashPt = |
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| C=2 | F=5 | I=1 |
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| Autoignition = }} |
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| Appearance = pungent colourless gas<ref name="GESTIS">{{GESTIS|Name=Pentafluoriodethan|ZVG=491002|CAS=354-64-3|Date=2019-01-07}}</ref> |
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| Density = 2.085 g·cm<sup>−3</sup><ref name="GESTIS" /> |
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| MeltingPtC = −92<ref name="GESTIS" /> |
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| BoilingPtC = 12-13<ref name="GESTIS" /> |
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| Solubility =}} |
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|Section3={{Chembox Hazards |
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| MainHazards = |
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| FlashPt = |
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| AutoignitionPt = |
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| GHSPictograms = {{GHS04}}{{GHS07}} |
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| GHSSignalWord = Warning |
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| HPhrases = {{H-phrases|280|315|319|335|336}} |
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| PPhrases = {{P-phrases|261|264|271|280|302+352|304+340|305+351+338|312|321|332+313|337+313|362|403+233|405|410+403|501}} |
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}} |
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'''Pentafluoroethyl iodide''' is a suggested component of a ] composition.<ref>US patent application 20010048094</ref> It is a very dense gas. |
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==Production== |
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Pentafluoroethyl iodide can be produced by ] of ].<ref name="Bernd Baasner">{{cite book| author=Bernd Baasner | title=Houben-Weyl Methods of Organic Chemistry Vol. E 10a, 4th Edition Supplement Organo-Fluorine Compounds - Fluorinating Agents and Their Application in Organic Synthesis | publisher=Georg Thieme Verlag | isbn=978-3-13-181544-6 | date=2014 | page=47,318}}</ref> |
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:<chem>2 C2F4I2 + 2 HF -> C2F5I + I2 + H2</chem> |
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It can also be produced by react ], ] and ].<ref name="R.E. Banks, B.E. Smart, J.C. Tatlow">{{cite book| author=R.E. Banks, B.E. Smart, J.C. Tatlow | title=Organofluorine Chemistry Principles and Commercial Applications | publisher=Springer Science & Business Media | isbn=978-1-4899-1202-2 | date=2013 | page=325}}</ref> |
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:<chem>5 C2F4 + 2 I2 + IF5 -> 5 C2F5I</chem> |
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==Properties== |
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Pentafluoroethyl iodide is a pungent colourless gas<ref name="GESTIS" /> and an ].<ref name="Maynard B. Chenoweth">{{cite book| author=Maynard B. Chenoweth | title=Modern Inhalation Anesthetics | publisher=Springer Science & Business Media | isbn=978-3-642-65055-0 | date=2012 | page=424}}</ref><ref name="Ernst W. Alther">{{cite book| author=Ernst W. Alther | title=Pharmacology of Fluorides | publisher=Springer Science & Business Media | isbn=978-3-662-25198-0 | date=2013 | page=538}}</ref> |
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==Uses== |
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'''Pentafluoroethyl iodide''' is a suggested component of a fire-extinguishing composition.<ref>US patent application 20010048094</ref> |
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Pentafluoroethyl iodide is an intermediate of preparing other compounds.<ref name="google.com">Google Patents: , retrieved 7 January 2019.</ref><ref name="Alexander Schönberg">{{cite book| author=Alexander Schönberg | title=Preparative Organic Photochemistry | publisher=Springer Science & Business Media | isbn=978-3-642-87918-0 | date=2012| page=174}}</ref><ref name="google.com2">Google Patents: , retrieved 7 January 2019.</ref> |
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==References== |
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==References== |
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