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{{Short description|Monosaccharide with five carbon atoms and a ketone functional group}} |
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{{chembox |
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{{chembox |
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| Verifiedfields = changed |
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| verifiedrevid = 447891597 |
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| Watchedfields = changed |
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|Name=<small>D</small>-Ribulose |
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| verifiedrevid = 450937939 |
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|ImageFileL1=D-ribulose.png |
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| Name = {{sm|d}}-Ribulose |
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|ImageSizeL1=88px |
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|ImageFileR1=Ribulose.png |
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| ImageFileL1 = D-Ribulose.svg |
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| ImageSizeL1 = 90px |
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|ImageSizeR1=150px |
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| ImageFileR1 = Ribulose.svg |
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|IUPACName=(''3R,4R'')-1,3,4,5-Tetrahydroxypentan-2-one |
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| ImageSizeR1 = 150px |
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|OtherNames=<small>D</small>-erythro-2-Pentulose<br>Adonose<br>Arabinulose<br>Araboketose<br>Ribosone |
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| IUPACName = {{sm|d}}-''erythro''-Pent-2-ulose |
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|Section1= {{Chembox Identifiers |
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| SystematicName = (''3R,4R'')-1,3,4,5-Tetrahydroxypentan-2-one |
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| CASNo=488-84-6 |
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| OtherNames = {{sm|d}}-erythro-2-Pentulose<br>Adonose<br>Arabinulose<br>Araboketose<br>Ribosone |
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| CASOther = (D)<br>2042027-5 (L)<br>5556-48-9 (DL) |
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| Section1 = {{Chembox Identifiers |
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| PubChem=151261 |
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| CASNo_Ref = {{cascite|correct|CAS}} |
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| SMILES=D: C(((C(=O)CO)O)O)O<br>L: OCC((O)(O)CO)=O |
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| CASNo=488-84-6 |
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| CASNo_Comment = ({{sm|d}}) |
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| CASNo2_Ref = {{cascite|correct|CAS}} |
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| CASNo2 = 2042-27-5 |
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| CASNo2_Comment = ({{sm|l}}) |
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| CASNo3_Ref = {{cascite|correct|CAS}} |
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| CASNo3 = 5556-48-9 |
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| CASNo3_Comment = ({{sm|dl}}) |
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| UNII_Ref = {{fdacite|correct|FDA}} |
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| UNII = Z7U4KG0138 |
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| UNII_Comment = ({{sm|d}}) |
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| UNII2_Ref = {{fdacite|correct|FDA}} |
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| UNII2 = 202306UV02 |
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| UNII2_Comment = ({{sm|l}}) |
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| UNII3_Ref = {{fdacite|correct|FDA}} |
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| UNII3 = DJM6K5T6YA |
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| UNII3_Comment = ({{sm|dl}}) |
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| PubChem=619 |
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| PubChem2=151261 |
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| PubChem2_Comment = (<small>D</small>) |
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| PubChem3=644111 |
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| PubChem3_Comment = (<small>L</small>) |
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| ChEBI_Ref = {{ebicite|changed|EBI}} |
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| ChEBI = 28721 |
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| ChEBI2 = 17173 |
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| ChEBI2_Comment = (<small>D</small>) |
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| ChEBI3 = 16880 |
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| ChEBI3_Comment = (<small>L</small>) |
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| KEGG = C05052 |
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| KEGG2 = C00309 |
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| KEGG2_Comment = (<small>D</small>) |
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| KEGG3 = C00508 |
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| KEGG3_Comment = (<small>L</small>) |
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| SMILES = C(((C(=O)CO)O)O)O |
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| SMILES_Comment = ({{sm|d}}) |
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| SMILES1 = OCC((O)(O)CO)=O |
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| SMILES1_Comment = ({{sm|l}}) |
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| ChemSpiderID_Ref = {{chemspidercite|changed|chemspider}} |
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| ChemSpiderID = 133316 |
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| InChI = 1/C5H10O5/c6-1-3(8)5(10)4(9)2-7/h3,5-8,10H,1-2H2/t3-,5-/m1/s1 |
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| InChIKey = ZAQJHHRNXZUBTE-NQXXGFSBBP |
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| StdInChI_Ref = {{stdinchicite|changed|chemspider}} |
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| StdInChI = 1S/C5H10O5/c6-1-3(8)5(10)4(9)2-7/h3,5-8,10H,1-2H2/t3-,5-/m1/s1 |
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| StdInChIKey_Ref = {{stdinchicite|changed|chemspider}} |
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| StdInChIKey = ZAQJHHRNXZUBTE-NQXXGFSBSA-N |
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}} |
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}} |
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|Section2= {{Chembox Properties |
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| Section2 = {{Chembox Properties |
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| C=5|H=10|O=5 |
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| C=5|H=10|O=5 |
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| Appearance= |
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| Appearance= |
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| Density= |
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| Density= |
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}} |
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}} |
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|Section3= {{Chembox Hazards |
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| Section3 = {{Chembox Hazards |
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| MainHazards= |
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| MainHazards= |
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| FlashPt= |
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| FlashPt= |
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| AutoignitionPt= |
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| Autoignition= |
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}} |
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}} |
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}} |
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}} |
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'''Ribulose''' is a ] — a ] containing five ] ]s, and including a ] ]. It has ] {{carbon}}<sub>5</sub>{{hydrogen}}<sub>10</sub>{{oxygen}}<sub>5</sub>. Two ] are possible, <small>D</small>-ribulose (<small>D</small>-erythro-pentulose) and <small>L</small>-ribulose (<small>L</small>-erythro-pentulose). <small>D</small>-Ribulose is the ] of <small>D</small>-]. |
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'''Ribulose''' is a ] — a ] containing five ] ]s, and including a ] ]. It has ] {{chem2|auto=1|C5H10O5}}. Two ] are possible, {{sm|d}}-ribulose ({{sm|d}}-erythro-pentulose) and {{sm|l}}-ribulose ({{sm|l}}-erythro-pentulose). {{sm|d}}-Ribulose is the ] of {{sm|d}}-]. |
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Ribulose sugars are composed in the ]. They are important in the formation of many bioactive substances. For example, <small>D</small>-ribulose is an intermediate in the fungal pathway for <small>D</small>-] production. Also, as the 1,5-bisphosphate, <small>D</small>-ribulose combines with ] at the start of the photosynthesis process in green plants (carbon dioxide trap). |
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Ribulose sugars are composed in the ] from ].<ref>{{cite journal |doi=10.1007/s12010-020-03380-0|title=Characterization of an L-Arabinose Isomerase from Bacillus velezensis and Its Application for L-Ribulose and L-Ribose Biosynthesis|year=2020|last1=Guo|first1=Zongren|last2=Long|first2=Liangkun|last3=Ding|first3=Shaojun|s2cid=220296031|journal=Applied Biochemistry and Biotechnology|volume=192 |issue=3 |pages=935–951 |pmid=32617845}}</ref> They are important in the formation of many bioactive substances. For example, {{sm|d}}-ribulose is an intermediate in the fungal pathway for {{sm|d}}-] production. Also, as the ], {{sm|d}}-ribulose combines with ] at the start of the ] process in green plants (carbon dioxide trap).<ref>{{cite journal |doi=10.1146/annurev.arplant.53.100301.135233|title=RUBISCO: Structure, Regulatory Interactions, and Possibilities for a Better Enzyme|year=2002|last1=Spreitzer|first1=Robert J.|last2=Salvucci|first2=Michael E.|journal=Annual Review of Plant Biology|volume=53|pages=449–475|pmid=12221984}}</ref> |
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Ribulose has the same stereochemistry at carbons 3 and 4 as the five-carbon ]s ] and ]. |
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A synthetic form of ribulose known as sucroribulose is found in many brands of artificial sweeteners. |
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== See also == |
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* ] |
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==References== |
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{{reflist}} |
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{{Carbohydrates}} |
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{{Carbohydrates}} |
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