Misplaced Pages

Sodium nitrate: Difference between revisions

Article snapshot taken from Wikipedia with creative commons attribution-sharealike license. Give it a read and then ask your questions in the chat. We can research this topic together.
Browse history interactively
Page 1
Page 2
← Previous editContent deleted Content addedVisualWikitext
Revision as of 16:56, 23 July 2011 editMartinBotIII (talk | contribs)136,346 editsm fix MSDS link (ilo.org) using AWB← Previous edit Latest revision as of 16:11, 12 November 2024 edit undo76.71.3.150 (talk) See also: MOS:ALSO 
(400 intermediate revisions by more than 100 users not shown)
Line 1: Line 1:
{{Short description|Chemical compound}}
{{Distinguish|sodium nitrite|sodium nitride|nitratine}}
{{chembox {{chembox
|ImageFile = Dusičnan sodný.JPG
| verifiedrevid = 402672744
|Verifiedfields = changed
|Watchedfields = changed
|verifiedrevid = 441025959
|ImageFileL1 = NaNitrate.png |ImageFileL1 = NaNitrate.png
|ImageSizeL1 = 120px
|ImageFileR1 = Sodium-nitrate-unit-cell-3D-balls.png |ImageFileR1 = Sodium-nitrate-unit-cell-3D-balls.png
|ImageSizeR1 = 120px
|IUPACName = Sodium nitrate |IUPACName = Sodium nitrate
|OtherNames = ]<br/>Chile saltpeter<br/>Nitrate of soda<br/>]<br/>Peru saltpeter<br/>Soda niter<br/>cubic niter |OtherNames = Peru saltpeter<br/>Soda niter<br/>cubic niter
|Section1 = {{Chembox Identifiers |Section1={{Chembox Identifiers
| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} |ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
| ChemSpiderID = 22688 |ChemSpiderID = 22688
| UNII_Ref = {{fdacite|correct|FDA}} |UNII_Ref = {{fdacite|correct|FDA}}
| UNII = 8M4L3H2ZVZ |UNII = 8M4L3H2ZVZ
| InChI = 1/NO3.Na/c2-1(3)4;/q-1;+1 |InChI = 1/NO3.Na/c2-1(3)4;/q-1;+1
| InChIKey = VWDWKYIASSYTQR-UHFFFAOYAL |InChIKey = VWDWKYIASSYTQR-UHFFFAOYAL
| SMILES = .()=O |SMILES = .()=O
| StdInChI_Ref = {{stdinchicite|correct|chemspider}} |StdInChI_Ref = {{stdinchicite|correct|chemspider}}
| StdInChI = 1S/NO3.Na/c2-1(3)4;/q-1;+1 |StdInChI = 1S/NO3.Na/c2-1(3)4;/q-1;+1
| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}} |StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}
| StdInChIKey = VWDWKYIASSYTQR-UHFFFAOYSA-N |StdInChIKey = VWDWKYIASSYTQR-UHFFFAOYSA-N
| CASNo = 7631-99-4 |CASNo = 7631-99-4
|ChEMBL_Ref = {{ebicite|changed|EBI}}
|ChEMBL = 1644698
|CASNo_Ref = {{cascite|correct|CAS}} |CASNo_Ref = {{cascite|correct|CAS}}
|EINECS = |EINECS = 231-554-3
|UNNumber = 1498 |UNNumber = 1498
|PubChem = 24268 |PubChem = 24268
|RTECS = WC5600000 |RTECS = WC5600000
}} }}
|Section2 = {{Chembox Properties |Section2={{Chembox Properties
|Formula = NaNO<sub>3</sub> |Formula = NaNO<sub>3</sub>
|MolarMass = 84.9947 g/mol |MolarMass = 84.9947 g/mol
|Appearance = White powder or colorless crystals with sweet smell |Appearance = White powder or colorless crystals
|Odor = sweet
|Density = 2.257 g/cm<sup>3</sup>, solid |Density = 2.257 g/cm<sup>3</sup>, solid
|MeltingPt = 308 °C |MeltingPtC = 308
|BoilingPt = 380 °C decomp. |BoilingPtC = 380
|BoilingPt_notes = decomposes
|Solubility = 730 g/L (0°C) <br> 921 g/L (25 °C) <br> 1800 g/L (100 °C)
|Solubility = 73 g/100 g water (0 °C) <br /> 91.2 g/100 g water (25 °C)<ref name="Haynes2016">{{cite book|last=Haynes|first=William M.|title=CRC Handbook of Chemistry and Physics|url=https://books.google.com/books?id=VVezDAAAQBAJ|date=2016-06-22|publisher=CRC Press|isbn=978-1-4987-5429-3}}</ref><ref name="pubchem">{{cite web |title=Sodium nitrate |work=PubChem |date= |access-date=11 June 2021 |url= https://pubchem.ncbi.nlm.nih.gov/compound/Sodium-nitrate#section=Solubility}}</ref><br /> 180 g/100 g water (100 °C)
|SolubleOther = very soluble in ]; soluble in ]
|SolubleOther = very soluble in ], ] <br /> soluble in ]<br /> slightly soluble in ] <br /> insoluble in ]
|Solvent =
|RefractIndex = 1.587 (trigonal) <br> 1.336 (rhomobohedral) |RefractIndex = 1.587 (trigonal) <br /> 1.336 (rhombohedral)
|Viscosity = 2.85 cP (317 °C)
|MagSus = &minus;25.6·10<sup>−6</sup> cm<sup>3</sup>/mol
}} }}
|Section3 = {{Chembox Structure |Section3={{Chembox Structure
|CrystalStruct = trigonal and rhombohedral |CrystalStruct = trigonal and rhombohedral
|Coordination =
}} }}
|Section4 = {{Chembox Thermochemistry |Section4={{Chembox Thermochemistry
|DeltaHf = −467&nbsp;kJ/mol<ref name=b1>{{cite book| author = Zumdahl, Steven S.|title =Chemical Principles 6th Ed| publisher = Houghton Mifflin Company| year = 2009| isbn = 978-0-618-94690-7|page=A23}}</ref>
|DeltaHf = −468 kJ/mol
|DeltaGf = −365.9 kJ/mol
|Entropy = 117 J·mol<sup>−1</sup>&thinsp;K<sup>−1</sup>
|Entropy = 116&nbsp;J/(mol K)<ref name=b1/>
|HeatCapacity =
|HeatCapacity = 93.05 J/(mol K)
}} }}
|Section7 = {{Chembox Hazards |Section5={{Chembox Hazards
|ExternalMSDS = |ExternalSDS =
|MainHazards = Harmful ('''Xn''')<br />Oxidant ('''O''')
|EUIndex = Not listed
|GHSPictograms = {{GHS07}}{{GHS03}}
|EUClass =
|RPhrases =
|SPhrases =
|MainHazards = Oxidant, irritant
|NFPA-H = 1 |NFPA-H = 1
|NFPA-F = 0 |NFPA-F = 0
|NFPA-R = 0 |NFPA-R = 0
|NFPA-O = OX |NFPA-S = OX
|FlashPt = Non-flammable |FlashPt = Non-flammable
|PEL =
|LD50 = 3236 mg/kg |LD50 = 3236 mg/kg
}} }}
|Section8 = {{Chembox Related |Section6={{Chembox Related
|OtherAnions = ] |OtherAnions = ]
|OtherCations = ]<br/>]<br/>]<br/>] |OtherCations = ]<br/>]<br/>]<br/>]
|OtherCompounds = ]<br/>]
|OtherFunctn =
|Function =
|OtherCpds = ]<br/>]
}} }}
}} }}


'''Sodium nitrate''' is the ] with the ] ]]]<sub>3</sub>. This ], also known as ''Chile saltpeter'' or ''Peru saltpeter'' (due to the large deposits found in each country) to distinguish it from ordinary saltpeter, ], is a white solid which is very soluble in ]. The mineral form is also known as '']'', ''nitratite'' or ''soda ]''. '''Sodium nitrate''' is the ] with the ] {{chem|]|]|]|3}}. This ] ] is also known as '''Chile saltpeter''' (large deposits of which were historically mined in ])<ref name=nitrate_towns>{{cite web |title=The Nitrate Towns of Chile |url=https://www.atlasobscura.com/places/nitrate-towns-chile |website=Atlas Obscura |access-date=27 May 2019 |language=en}}</ref><ref name=ghost_towns>{{cite news |last1=Mutic |first1=Anja |title=The ghost towns of northern Chile |url=https://www.washingtonpost.com/lifestyle/travel/the-ghost-towns-of-northern-chile/2012/10/25/fa4adad0-16e2-11e2-a55c-39408fbe6a4b_story.html |access-date=27 May 2019 |newspaper=Washington Post |date=26 October 2012 |language=en}}</ref> to distinguish it from ordinary saltpeter, ]. The mineral form is also known as ], nitratite or soda ].


Sodium nitrate is used as an ingredient; in ]s, pyrotechnics, as an ingredient in ]s, as a ], and as a ], as well as in ] and ] ]. The compound has been mined extensively for those purposes. Sodium nitrate is a white ] solid very soluble in ]. It is a readily available source of the ] anion (NO<sub>3</sub><sup>−</sup>), which is useful in several reactions carried out on industrial scales for the production of ]s, ], ]s and other ], ] and ] ], ]s (esp. meats), and ]. It has been mined extensively for these purposes.


==History== ==History==
The first shipment of Chile saltpeter to Europe arrived in England in 1820 or 1825, but did not find any buyers and was dumped at sea in order to avoid customs toll.<ref>S. H. Baekeland "Några sidor af den kemiska industrien" (1914) ''Svensk Kemisk Tidskrift'', .</ref><ref name="uppfinn">Friedrich Georg Wieck, ''Uppfinningarnas bok'' (1873, Swedish translation of ''Buch der Erfindungen''), .</ref> With time, however, the mining of South American saltpeter became a profitable business (in 1859, England alone consumed 47,000 metric tons<ref name="uppfinn"/>). ] fought against the allies ] and ] in the ] 1879-1884 and took over the richest deposits. In 1919, ] determined its ] structure using ]. The first shipment of saltpeter to Europe arrived in England from Peru in 1820 or 1825, right after that country's independence from Spain, but did not find any buyers and was dumped at sea in order to avoid customs toll.<ref>S. H. Baekeland "Några sidor af den kemiska industrien" (1914) ''Svensk Kemisk Tidskrift'', .</ref><ref name="uppfinn">Friedrich Georg Wieck, ''Uppfinningarnas bok'' (1873, Swedish translation of ''Buch der Erfindungen''), .</ref> With time, however, the mining of South American saltpeter became a profitable business (in 1859, England alone consumed 47,000 metric tons).<ref name="uppfinn"/> ] fought the ] (1879–1884) against the allies ] and ] and took over their richest deposits of saltpeter. In 1919, ] determined its ] structure using ].


==Sources== {{Anchor|Sources}}
The largest accumulations of naturally occurring sodium nitrate are found in ] and ], where ] salts are bound within mineral deposits called ] ore.<ref>Stephen R. Bown, A Most Damnable Invention: Dynamite, Nitrates, and the Making of the Modern World, Macmillan, 2005, ISBN 0-312-32913-X, p. 157</ref> For more than a century, the world supply of the compound was mined almost exclusively from the ] desert in northern ] until, at the turn of the 20th century, German chemists ] and ] developed a process for producing ] from the atmosphere on an industrial scale (see ]). With the onset of ], Germany began converting ammonia from this process into a synthetic ''Chilean saltpeter'' which was as practical as the natural compound in production of ] and other munitions. By the 1940s, this conversion process resulted in a dramatic decline in demand for sodium nitrate procured from natural sources.


==Occurrence==
Chile still has the largest reserves of caliche, with active mines in such locations as ], ] and ], and there it used to be called ''white gold''. Sodium nitrate, ], ] and ] are all obtained by the processing of caliche. The former Chilean saltpeter mining communities of ] were declared ] in 2005.
]
]
The largest accumulations of naturally occurring sodium nitrate are found in ] and ], where ] salts are bound within mineral deposits called ] ore.<ref>Stephen R. Bown, ''A Most Damnable Invention: Dynamite, Nitrates, and the Making of the Modern World'', Macmillan, 2005, {{ISBN|0-312-32913-X}}, p. 157.</ref> Nitrates accumulate on land through marine-fog precipitation and sea-spray oxidation/desiccation followed by gravitational settling of airborne NaNO<sub>3</sub>, KNO<sub>3</sub>, NaCl, Na<sub>2</sub>SO<sub>4</sub>, and I, in the hot-dry desert atmosphere.<ref>{{cite conference|url=https://gsa.confex.com/gsa/inqu/finalprogram/abstract_55601.htm|title=On the Origin of Saltpeter, Northern Chile Coast|author1=Arias, Jaime|date=24 Jul 2003|publisher=International Union for Quaternary Research|access-date=19 Aug 2018|archive-url=https://web.archive.org/web/20160304100458/https://gsa.confex.com/gsa/inqu/finalprogram/abstract_55601.htm|archive-date=4 March 2016}}</ref> El Niño/La Niña extreme aridity/torrential rain cycles favor nitrates accumulation through both aridity and water solution/remobilization/transportation onto slopes and into basins; capillary solution movement forms layers of nitrates; pure nitrate forms rare veins. For more than a century, the world supply of the compound was mined almost exclusively from the ] desert in northern Chile until, at the turn of the 20th century, German chemists ] and ] developed a process for producing ] from the atmosphere on an industrial scale (see ]). With the onset of ], Germany began converting ammonia from this process into a synthetic ''Chilean saltpeter'', which was as practical as the natural compound in production of ] and other munitions. By the 1940s, this conversion process resulted in a dramatic decline in demand for sodium nitrate procured from natural sources.


Chile still has the largest reserves of ], with active mines in such locations as ], ] and Pampa Blanca, and there it used to be called ''white gold''.<ref name=nitrate_towns/><ref name=ghost_towns/> Sodium nitrate, ], ] and ] are all obtained by the processing of caliche. The former Chilean saltpeter mining communities of ] were declared ] in 2005.
Sodium nitrate is also synthesized industrially by neutralizing ] with ].


==Applications== == Synthesis ==
Sodium nitrate is also synthesized industrially by neutralizing ] with ] or ]:
Sodium nitrate was used extensively as a ] and a raw material for the ] of ] in the late 19th century. It can be combined with ] to make a ].


:2 HNO<sub>3</sub> + Na<sub>2</sub>CO<sub>3</sub> → 2 NaNO<sub>3</sub> + H<sub>2</sub>O + CO<sub>2</sub>
Sodium nitrate should not be confused with the related compound, ]. Sodium nitrate in the brine gives cooked corned beef its classic reddish color (without it corned beef comes out gray), and it kills botulism spores. Nitrate is actually changed to nitrite by bacterial action during processing and storage and nitrate itself has no effect on meat color.


:HNO<sub>3</sub> + NaHCO<sub>3</sub> → NaNO<sub>3</sub> + H<sub>2</sub>O + CO<sub>2</sub>
It can be used in the production of ] by combining it with ] and subsequent separation through ] of the nitric acid, leaving behind a residue of ]. ] gold refiners use sodium nitrate to make a hybrid ] that dissolves gold and other metals.


or also by neutralizing it with ] (however, this reaction is very exothermic):
Less common applications include its use as a substitute oxidizer used in fireworks as a replacement for ] commonly found in ] and as a component in instant cold packs.<ref>Albert A. Robbins "Chemical freezing package" {{US patent|2898744}}, Issue date: August 1959</ref>


:HNO<sub>3</sub> + NaOH → NaNO<sub>3</sub> + H<sub>2</sub>O
Sodium nitrate is used together with ] for heat storage and, more recently, for ] in ] plants.


or by mixing stoichiometric amounts of ] and ], ] or ]:
It is also used in the wastewater industry for facultative microorganism respiration. ], a genus of ]s, consumes nitrate in preference to oxygen, enabling it to grow more rapidly in the wastewater to be treated.

:NH<sub>4</sub>NO<sub>3</sub> + NaOH → NaNO<sub>3</sub> + NH<sub>4</sub>OH

:NH<sub>4</sub>NO<sub>3</sub> + NaHCO<sub>3</sub> → NaNO<sub>3</sub> + NH<sub>4</sub>HCO<sub>3</sub>

:2NH<sub>4</sub>NO<sub>3</sub> + Na<sub>2</sub>CO<sub>3</sub> → 2NaNO<sub>3</sub> + (NH<sub>4</sub>)<sub>2</sub>CO<sub>3</sub>

==Uses==
Most sodium nitrate is used in fertilizers, where it supplies a water-soluble form of nitrogen. Its use, which is mainly outside of high-income countries, is attractive since it does not alter the ] of the soil. Another major use is as a complement to ] in explosives. Molten sodium nitrate and its solutions with potassium nitrate have good thermal stability (up to 600&nbsp;°C) and high heat capacities. These properties are suitable for thermally annealing metals and for storing thermal energy in solar applications.<ref name=Ullmann>{{Ullmann|doi=10.1002/14356007.a17_265|title=Nitrates and Nitrites|year=2000|last1=Laue|first1=Wolfgang|last2=Thiemann|first2=Michael|last3=Scheibler|first3=Erich|last4=Wiegand|first4=Karl}}</ref>

=== Food ===
Sodium nitrate is also a ] used as a preservative and color fixative in cured meats and poultry; it is listed under its ] 251 or ] E251. It is approved for use in the EU,<ref>UK Food Standards Agency: {{cite web|url=http://www.food.gov.uk/safereating/chemsafe/additivesbranch/enumberlist|title=Current EU approved additives and their E Numbers|access-date=2011-10-27}}</ref> US<ref>US Food and Drug Administration: {{cite web|url=https://www.fda.gov/Food/FoodIngredientsPackaging/FoodAdditives/ucm191033.htm#ftnT|title=Listing of Food Additives Status Part II|website=] |access-date=2011-10-27}}</ref> and Australia and New Zealand.<ref>Australia New Zealand Food Standards Code{{cite web|url=http://www.comlaw.gov.au/Details/F2011C00827|title=Standard 1.2.4 – Labelling of ingredients|date=8 September 2011 |access-date=2011-10-27}}</ref> Sodium nitrate should not be confused with ], which is also a common food additive and preservative used, for example, in deli meats.

=== Thermal storage ===
Sodium nitrate has also been investigated as a ] for thermal energy recovery, owing to its relatively high melting enthalpy of 178 J/g.<ref name=":0">{{cite journal|last1=Bauer|first1=Thomas|last2=Laing|first2=Doerte|last3=Tamme|first3=Rainer|date=2011-11-15|title=Characterization of Sodium Nitrate as Phase Change Material|journal=International Journal of Thermophysics|volume=33|issue=1|pages=91–104|doi=10.1007/s10765-011-1113-9|s2cid=54513228|issn=0195-928X}}</ref><ref>{{cite journal|date=1999-06-14|title=Reference materials for calorimetry and differential thermal analysis|url=https://www.sciencedirect.com/science/article/abs/pii/S004060319900009X|journal=Thermochimica Acta|language=en|volume=331|issue=2|pages=93–204|doi=10.1016/S0040-6031(99)00009-X|issn=0040-6031|author=ICTAC Working Group|last2=Sabbah |first2=R. |last3=Xu-Wu |first3=An|last4=Chickos|first4=J.S.|last5=Leitão |first5=M.L.Planas|last6=Roux |first6=M.V.|last7=Torres |first7=L.A.|display-authors=2}}</ref> Examples of the applications of sodium nitrate used for thermal energy storage include ] technologies and direct steam generating ]s.<ref name=":0" />

=== Steel coating ===
{{Main article|Black oxide}}
Sodium nitrate is used in a steel coating process in which it forms a surface of ] layer.<ref>{{cite book |last=Fauzi |first=Ahmad Asyraf Bin Ahmad |url=https://books.google.com/books?id=ImcFywEACAAJ |title=Production of Magnetite Thin Film Over Steel Substrate Using Hot Alkaline Nitrate Blackening Method |date=2014 |publisher=Universitat Politècnica de Catalunya. Escola Politècnica Superior d'Enginyeria de Vilanova i la Geltrú. Departament de Ciència dels Materials i Enginyeria Metal·lúrgica, 2014 (Grau en Enginyeria Mecànica) |language=en}}</ref>


==Health concerns== ==Health concerns==
Studies have shown a link between increased levels of nitrates and increased deaths from certain diseases including ], ], ], and ]: possibly through the damaging effect of ] on DNA; however, little has been done to control for other possible causes in the epidemiological results.<ref>{{cite journal |pmid=19363256 |year=2009 |last1=De La Monte |first1=SM |last2=Neusner |first2=A |last3=Chu |first3=J |last4=Lawton |first4=M |title=Epidemilogical trends strongly suggest exposures as etiologic agents in the pathogenesis of sporadic Alzheimer's disease, diabetes mellitus, and non-alcoholic steatohepatitis |volume=17 |issue=3 |pages=519–29 |doi=10.3233/JAD-2009-1070 |journal=Journal of Alzheimer's Disease |pmc=4551511}}</ref> Nitrosamines, formed in cured meats containing sodium nitrate and nitrite, have been linked to ] and ].<ref>{{cite journal |title=Nitrosamine and related food intake and gastric and oesophageal cancer risk: a systematic review of the epidemiological evidence |author1=Jakszyn, Paula |author2=Gonzalez, Carlos-Alberto |journal=World Journal of Gastroenterology |volume=12 |issue=27 |pages=4296–4303 |date=21 Jul 2006 |pmc=4087738 |pmid=16865769 |doi=10.3748/wjg.v12.i27.4296 |doi-access=free}}</ref> Sodium nitrate and nitrite are associated with a higher risk of ].<ref>{{cite journal |pmid=20215514 |year=2010 |last1=Cross |first1=AJ |last2=Ferrucci |first2=LM |last3=Risch |first3=A |last4=Graubard |first4=BI |last5=Ward |first5=MH |last6=Park |first6=Y |last7=Hollenbeck |first7=AR |last8=Schatzkin |first8=A |last9=Sinha |first9=R |display-authors=3 |title=A large prospective study of meat consumption and colorectal cancer risk: An investigation of potential mechanisms underlying this association |volume=70 |issue=6 |pages=2406–14 |doi=10.1158/0008-5472.CAN-09-3929 |pmc=2840051 |journal=Cancer Research}}</ref>
Like ], sodium nitrate forms ]s, a human carcinogen, known to cause DNA damage and increased cellular degeneration. Studies have shown a link between increased levels of nitrates and increased deaths from certain diseases including Alzheimer's, diabetes mellitus and Parkinson's, possibly through the damaging effect of nitrosamines on DNA.<ref></ref>

Nitrosamines, formed in cured meats containing sodium nitrate and nitrite, have been linked to ] and ].<ref>http://ecnis.openrepository.com/ecnis/handle/10146/25215</ref>
Sodium nitrate and nitrite are associated with a higher risk of ].<ref></ref> ],<ref>, World Cancer Research Fund (2010) accessdate 2010-03-06</ref> states that one of the reasons that processed meat increases the risk of ] is its content of nitrate. A small amount of the nitrate added to meat as a preservative breaks down into nitrite, in addition to any nitrite that may also be added. The nitrite then reacts with protein-rich foods (such as meat) to produce N-nitroso compounds (NOCs). Some types of NOCs are known to cause cancer. NOCs can be formed either when meat is cured or in the body as meat is digested. Substantial evidence in recent decades, facilitated by an increased understanding of pathological processes and science, exists in support of the theory that processed meat increases the risk of ] and that this is due to the nitrate content. A small amount of the nitrate added to meat as a preservative breaks down into nitrite, in addition to any nitrite that may also be added. The nitrite then reacts with protein-rich foods (such as meat) to produce ]ic NOCs (] compounds). NOCs can be formed either when meat is cured or in the body as meat is digested.<ref>, {{Webarchive |url=https://web.archive.org/web/20190726222247/https://www.wcrf.org/sites/default/files/SLR_colorectal_cancer_2010.pdf |date=2019-07-26 }} World Cancer Research Fund (2010)</ref>

However, several things complicate the otherwise straightforward understanding that "nitrates in food raise the risk of cancer". Processed meats have no fiber, vitamins, or phytochemical antioxidants, are high in sodium, may contain high fat, and are often fried or cooked at a temperature sufficient to degrade protein into nitrosamines. Nitrates are key intermediates and effectors in the primary vasculature signaling which is necessary for all mammals to survive.<ref>{{cite journal |last1=Machha |first1=Ajay |last2=Schechter |first2=Alan N. |date=August 2011 |title=Dietary nitrite and nitrate: a review of potential mechanisms of cardiovascular benefits |journal=European Journal of Nutrition |volume=50 |issue=5 |pages=293–303 |doi=10.1007/s00394-011-0192-5 |issn=1436-6207 |pmc=3489477 |pmid=21626413}}</ref>


==See also== ==See also==


* ]
* ], also known as "the Saltpeter War".


==References==
==Notes and references==
{{Reflist}} {{Reflist}}


==Further reading== ==Further reading==
*{{cite journal|first=Dennis|last=Barnum|year=2003|title=Some History of Nitrates|journal=Journal of Chemical Education|volume=80| pages=1393–|url=http://jchemed.chem.wisc.edu/Journal/Issues/2003/Dec/abs1393.html|doi=10.1021/ed080p1393}} * {{cite journal|last1=Archer|first1=Donald G.|title=Thermodynamic properties of the NaNO<sub>3</sub> + H<sub>2</sub>O system|journal=Journal of Physical and Chemical Reference Data|volume=29|issue=5|year=2000|pages=1141–1156|issn=0047-2689|doi=10.1063/1.1329317|bibcode=2000JPCRD..29.1141A}}
* {{cite journal|first=Dennis|last=Barnum|year=2003|title=Some history of nitrates|journal=Journal of Chemical Education|volume=80|issue=12| pages=1393–|doi=10.1021/ed080p1393|bibcode=2003JChEd..80.1393B}}
* {{cite book|first1=J. W.|last1=Mullin|title=Crystallization|url=https://books.google.com/books?id=TiVuQgAACAAJ|year=1997|publisher=Butterworth-Heinemann|isbn=978-0-7506-3759-6}}


==External links== ==External links==
* U.S. ] (public domain) * U.S. ] (public domain)
* *
* Calculators: , and of aqueous sodium nitrate


{{Nitrates}}
{{Salt topics}}
{{Sodium compounds}} {{Sodium compounds}}
{{Authority control}}


]
{{DEFAULTSORT:Sodium Nitrate}}
]
] ]
] ]
]
] ]
] ]
]
] ]
]
]
]

]
]
]
]
]
]
]
]
]
]
]
]
]
]
]
]
]
]
]
]
]
]
]
]
]
]
]
]
]
]
]
]
]