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Revision as of 11:21, 11 August 2011 editCheMoBot (talk | contribs)Bots141,565 edits Updating {{chembox}} (no changed fields - added verified revid - updated 'DrugBank_Ref', 'UNII_Ref', 'ChEMBL_Ref', 'ChEBI_Ref') per Chem/Drugbox validation (report [[Wikipedia_talk:WikiProject_Ch← Previous edit Latest revision as of 19:58, 29 October 2024 edit undoMondtaler (talk | contribs)181 edits GHS04 and H280 specifically address hazards linked to the pressurized storage of gases. As storage methods can vary, these pictograms and hazard statements are not universally applicable to all gaseous compounds.Tag: 2017 wikitext editor 
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{{chembox {{chembox
| Watchedfields = changed
| verifiedrevid = 444244192 | verifiedrevid = 470630671
| ImageFile_Ref = {{chemboximage|correct|??}} | ImageFile_Ref = {{chemboximage|correct|??}}
| ImageFile = Vinylfluoride t.png | ImageFile = Vinylfluoride.svg
| ImageSize = 120px | ImageSize = 120px
| IUPACName = Fluoroethene | PIN = Fluoroethene
| OtherNames = Vinylfluoride, Fluoroethylene, Monofluoroethylene, Vinyl fluoride monomer, VF, R 1141, UN 1860 (inhibited) | OtherNames = Vinylfluoride, Fluoroethylene, Monofluoroethylene, Vinyl fluoride monomer, VF, R 1141, UN 1860 (inhibited)
| Section1 = {{Chembox Identifiers |Section1={{Chembox Identifiers
⚫ | CASNo = 75-02-5
⚫ | ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
⚫ | CASNo_Ref = {{cascite|correct|CAS}}
| Beilstein = 1731574
⚫ | ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
| ChemSpiderID = 6099 | ChemSpiderID = 6099
⚫ | PubChem = 6339
⚫ | ChEBI_Ref = {{ebicite|correct|EBI}}
⚫ | ChEBI = 51314
⚫ | EINECS = 200-832-6
| Gmelin = 130238
⚫ | KEGG_Ref = {{keggcite|correct|kegg}}
⚫ | KEGG = C19185
⚫ | RTECS = YZ7351000
| UNII_Ref = {{fdacite|correct|FDA}}
| UNII = 2598465ICX
⚫ | SMILES = FC=C
⚫ | InChI = 1/C2H3F/c1-2-3/h2H,1H2
| StdInChI_Ref = {{stdinchicite|correct|chemspider}} | StdInChI_Ref = {{stdinchicite|correct|chemspider}}
| StdInChI = 1S/C2H3F/c1-2-3/h2H,1H2 | StdInChI = 1S/C2H3F/c1-2-3/h2H,1H2
| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}} | StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}
| StdInChIKey = XUCNUKMRBVNAPB-UHFFFAOYSA-N | StdInChIKey = XUCNUKMRBVNAPB-UHFFFAOYSA-N
⚫ | CASNo = 75-02-5
⚫ | CASNo_Ref = {{cascite|correct|CAS}}
⚫ | PubChem = 6339
⚫ | ChEBI_Ref = {{ebicite|correct|EBI}}
⚫ | ChEBI = 51314
⚫ | SMILES = FC=C
⚫ | InChI = 1/C2H3F/c1-2-3/h2H,1H2
⚫ | EINECS = 200-832-6
⚫ | RTECS = YZ7351000
⚫ | KEGG_Ref = {{keggcite|correct|kegg}}
⚫ | KEGG = C19185
}} }}
| Section2 = {{Chembox Properties |Section2={{Chembox Properties
| Formula = C<sub>2</sub>H<sub>3</sub>F | Formula = C<sub>2</sub>H<sub>3</sub>F
| MolarMass = 46.04 g/mol | MolarMass = 46.04 g/mol
| Appearance = Colorless gas with a faint, ethereal odor | Appearance = Colorless gas
| Odor = faint, ethereal<ref name=PGCH/>
| Density = 2 g/cm<sup>3</sup> (gas) | Density = 0.636 g/cm<sup>3</sup>
| MeltingPtC = -160.5
0.91 g/cm<sup>3</sup> (liquid)
| MeltingPt_notes =
| MeltingPt = -160.5 °C (-257 °F)
| BoilingPt = -72.2 °C (-98 °F) | BoilingPtC = -72.2
| Solubility = Slightly soluble | BoilingPt_notes =
| Solubility = Slightly soluble
| VaporPressure = 25 500 kPa | VaporPressure = 25.2 atm (370.4 psi)
}} }}
| Section3 = {{Chembox Hazards |Section3={{Chembox Hazards
| MainHazards =
| EUClass = Extremely flammable ('''F+''')
| MainHazards = | FlashPt =
| FlashPt = | AutoignitionPtC = 385
| AutoignitionPt_notes =
| Autoignition = 385 °C
| NFPA-H = 1 | NFPA-H = 1
| NFPA-F = 4 | NFPA-F = 4
| NFPA-R = 2 | NFPA-R = 2
| NFPA-O = | NFPA-S =
| RPhrases = {{R12}} | GHSPictograms = {{GHS02}}{{GHS08}}
| GHSSignalWord = Danger
| SPhrases = {{S9}}, {{S16}}, {{S33}}
| HPhrases = {{H-phrases|220|341|350|373}}
⚫ | ExploLimits = 2.6 - 21.7 %
| PPhrases = {{P-phrases|201|202|210|260|281|308+313|314|377|381|403|405|410+403|501}}
⚫ | ExploLimits = 2.6 - 21.7%
| PEL = none<ref name=PGCH>{{PGCH|0660}}</ref>
| IDLH = N.D.<ref name=PGCH/>
| REL = TWA 1 ppm C 5 ppm<ref name=PGCH/>
}} }}
}} }}


'''Vinyl fluoride''' is an ] with the chemical formula C<sub>2</sub>H<sub>3</sub>F. It is a colorless gas with a faint ]like odor. It is used as the ]ic precursor to the ] polyvinylfluoride. '''Vinyl fluoride''' is an ] with the chemical formula C<sub>2</sub>H<sub>3</sub>F. It is a colorless gas with a faint ]-like odor. It is used as the ]ic precursor to the ] ].


==Production== ==Production==
It was first prepared in 1901 by Frédéric Swarts, the Belgian chemist who was the first to prepare CFCs in 1892. Swarts used the reaction of ] with 1,1-difluoro-2-bromoethane. It is produced industrially by two routes, one being the mercury-catalyzed reaction of ] and ]:<ref>Günter Siegemund, Werner Schwertfeger, Andrew Feiring, Bruce Smart, Fred Behr, Herward Vogel, Blaine McKusick “Fluorine Compounds, Organic” Ullmann's Encyclopedia of Industrial Chemistry, Wiley-VCH, Weinheim, 2002. {{DOI|10.1002/14356007.a11_349}}</ref> It was first prepared in 1901 by Frédéric Swarts, the Belgian chemist who was the first to prepare ]s in 1892. Swarts used the reaction of ] with 1,1-difluoro-2-bromoethane. It is produced industrially by two routes, one being the mercury-catalyzed reaction of ] and ]:<ref>Günter Siegemund, Werner Schwertfeger, Andrew Feiring, Bruce Smart, Fred Behr, Herward Vogel, Blaine McKusick “Fluorine Compounds, Organic” Ullmann's Encyclopedia of Industrial Chemistry, Wiley-VCH, Weinheim, 2002. {{doi|10.1002/14356007.a11_349}}</ref>
:HCCH + HF → CH<sub>2</sub>=CHF :HC≡CH + HF → CH<sub>2</sub>=CHF
It is also prepared from 1,1-chlorofluoroethane: It is also prepared from 1,1-chlorofluoroethane:
:CH<sub>3</sub>CHClF → CH<sub>2</sub>=CHF + HCl :CH<sub>3</sub>CHClF → CH<sub>2</sub>=CHF + HCl


==Safety== ==Safety==
Vinyl fluoride is classified as an ] (likely to cause ] in humans). Vinyl fluoride is classified as an ] (likely to cause ] in humans).

⚫ ==Additional data==
⚫ Its critical point is at 54.8&nbsp;°C (328 K) and 5.24 MPa. Its ] is 1.4 Debye and ] is 361 kJ/kg.


== See also == == See also ==
* ] * ]
* ] * ]
* ]


==References== ==References==
<references/> <references/>

⚫ ==Additional data==
⚫ Its critical point is at 54.8 °C (328 K) and 5.24 MPa. ] is 1.4 Debye and ] is 361 kJ/kg.


== External links == == External links ==
* *
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* * {{Webarchive|url=https://web.archive.org/web/20160303210601/http://encyclopedia.airliquide.com/encyclopedia.asp?GasID=113 |date=2016-03-03 }}
* *
* *


{{fluorine compounds}}
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