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8-Oxogeranial

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8-Oxogeranial
Names
Preferred IUPAC name (2E,6E)-2,6-Dimethylocta-2,6-dienedial
Identifiers
CAS Number
3D model (JSmol)
ChEBI
ChemSpider
KEGG
PubChem CID
CompTox Dashboard (EPA)
InChI
  • InChI=1S/C10H14O2/c1-9(6-7-11)4-3-5-10(2)8-12/h5-8H,3-4H2,1-2H3/b9-6+,10-5+Key: GRHWFPUCRVCMRY-TXFIJWAUSA-N
  • InChI=1/C10H14O2/c1-9(6-7-11)4-3-5-10(2)8-12/h5-8H,3-4H2,1-2H3/b9-6+,10-5+Key: GRHWFPUCRVCMRY-TXFIJWAUBP
SMILES
  • C/C(=C\C=O)/CC/C=C(\C)/C=O
Properties
Chemical formula C10H14O2
Molar mass 166.220 g·mol
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). Infobox references
Chemical compound

8-Oxogeranial is a chemical substance (also incorrectly called 10-oxogeranial), that is a monoterpene. The terpenoid is produced by 8-hydroxygeraniol dehydrogenase which uses 8-hydroxygeraniol as its substrate. 8-Oxogeranial is itself a substrate for iridoid synthase which synthesizes cis–trans-iridodial and cis–trans-nepetalactol.

References

  1. Dewick (2009) Medicinal Natural Products: A Biosynthetic Approach.
  2. Miettinen, Karel; Dong, Lemeng; Navrot, Nicolas; Schneider, Thomas; Burlat, Vincent; Pollier, Jacob; Woittiez, Lotte; Van Der Krol, Sander; Lugan, Raphaël; Ilc, Tina; Verpoorte, Robert; Oksman-Caldentey, Kirsi-Marja; Martinoia, Enrico; Bouwmeester, Harro; Goossens, Alain; Memelink, Johan; Werck-Reichhart, Danièle (2014). "The seco-iridoid pathway from Catharanthus roseus". Nature Communications. 5: 3606. doi:10.1038/ncomms4606. PMC 3992524. PMID 24710322.


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