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Acephenanthrylene

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Acephenanthrylene
Names
IUPAC name Acephenanthrylene
Other names 4,5-Benzoacenaphthylene
Benz(e)acenaphthylene
Benzoacenaphthylene
Identifiers
CAS Number
3D model (JSmol)
Beilstein Reference 2247468
ChEBI
ChemSpider
PubChem CID
UNII
CompTox Dashboard (EPA)
InChI
  • InChI=1S/C16H10/c1-2-6-14-12(4-1)10-13-9-8-11-5-3-7-15(14)16(11)13/h1-10HKey: SQFPKRNUGBRTAR-UHFFFAOYSA-N
SMILES
  • C1=CC=C2C(=C1)C=C3C=CC4=C3C2=CC=C4
Properties
Chemical formula C16H10
Molar mass 202.256 g·mol
Related compounds
Related compounds Acenaphthylene
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). Infobox references
Chemical compound

Acephenanthrylene is a tetracyclic polycyclic aromatic hydrocarbon.

Properties and occurrence

Acephenanthrylene is one of the polycyclic aromatic hydrocarbons formed in combustion of various fuels. However, it is not present as an atmospheric pollutant because its vinylic bridge makes it susceptible to photolytic oxidation once released into the atmosphere.

Preparation

Acephenanthrylene has been prepared in 4 steps starting with cyclization of 4-(5-acenapthenyl)butyric acid.

References

  1. "Acephenanthrylene". PubChem.
  2. National Research Council (US) Committee on Pyrene and Selected Analogues (1983). "3, Atmospheric Transformations of Polycyclic Aromatic Hydrocarbons". Polycyclic Aromatic Hydrocarbons: Evaluation of Sources and Effects. National Academies Press.
  3. Scott, Lawrence T.; Reinhardt, Gerd; Roelofs, Nicolas H. (1985). "Acephenanthrylene". The Journal of Organic Chemistry. 50 (26): 5886–5887. doi:10.1021/jo00350a096.
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