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Actinium(III) nitrate

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Actinium(III) nitrate

The glass is discolored due to the high radiation of actinium
Names
Other names Actinium nitrate
Identifiers
CAS Number
3D model (JSmol)
PubChem CID
InChI
  • InChI=1S/Ac.3NO3/c;3*2-1(3)4/q;3*-1Key: AEFUOHSKBCUMLM-UHFFFAOYSA-N
SMILES
  • (=O)().(=O)().(=O)().
Properties
Chemical formula Ac(NO3)3
Molar mass 413.04
Appearance White substance
Solubility in water Soluble
Hazards
GHS labelling:
Signal word Warning
Related compounds
Related compounds Thorium(IV) nitrate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). Infobox references
Chemical compound

Actinium(III) nitrate is an inorganic compound, actinium salt of nitric acid with the chemical formula Ac(NO3)3. The compound looks like white substance, readily soluble in water.

Synthesis

Actinium nitrate can be obtained by dissolving actinium or actinium hydroxide in nitric acid.

Ac(OH)3 + 3HNO3 → Ac(NO3)3 + 3H2O

Properties

Actinium(III) nitrate decomposes on heating above 600 °C:

4Ac(NO3)3 → 2Ac2O3 + 12NO2 + 3O2

This salt is used as a source of Ac ions to obtain insoluble actinium compounds by precipitation from aqueous solutions.

References

  1. Ferrier, Maryline G.; Stein, Benjamin W.; Batista, Enrique R.; Berg, John M.; Birnbaum, Eva R.; Engle, Jonathan W.; John, Kevin D.; Kozimor, Stosh A.; Lezama Pacheco, Juan S.; Redman, Lindsay N. (22 March 2017). "Synthesis and Characterization of the Actinium Aquo Ion". ACS Central Science. 3 (3): 176–185. doi:10.1021/acscentsci.6b00356. ISSN 2374-7943. PMC 5364452. PMID 28386595.
  2. Salutsky, M. L.; Kirby, H. W. (1 November 1956). "Precipitation of Actinium Oxalate from Homogeneous Solution". Analytical Chemistry. 28 (11): 1780–1782. doi:10.1021/ac60119a044. ISSN 0003-2700. Retrieved 18 August 2021.
Actinium compounds
Salts and covalent derivatives of the nitrate ion
HNO3 He
LiNO3 Be(NO3)2 B(NO3)−4 RONO2
+CO3
+C2O4
NO3
NH4NO3
HOONO2 FNO3
+F
Ne
NaNO3 Mg(NO3)2 Al(NO3)3
Al(NO3)−4
Si P +SO4 ClONO2
+Cl
Ar
KNO3 Ca(NO3)2 Sc(NO3)3 Ti(NO3)4 VO(NO3)3 Cr(NO3)3 Mn(NO3)2 Fe(NO3)2
Fe(NO3)3
Co(NO3)2
Co(NO3)3
Ni(NO3)2 CuNO3
Cu(NO3)2
Zn(NO3)2 Ga(NO3)3 Ge As +SeO3 BrNO3
+Br
Kr
RbNO3 Sr(NO3)2 Y(NO3)3 Zr(NO3)4 NbO(NO3)3 MoO2(NO3)2 Tc Ru Rh(NO3)3 Pd(NO3)2 AgNO3 Cd(NO3)2 In(NO3)3 Sn(NO3)4 Sb4O4(OH)2(NO3)2 Te INO3
+IO3
Xe(NO3)2
CsNO3 Ba(NO3)2 * Lu(NO3)3 Hf(NO3)4 TaO(NO3)3 WO2(NO3)2 ReO3NO3 Os Ir3O(NO3)10 Pt Au(NO3)−4 Hg2(NO3)2
Hg(NO3)2
TlNO3
Tl(NO3)3
Pb(NO3)2 Bi(NO3)3
BiO(NO3)
Po(NO3)4 At Rn
FrNO3 Ra(NO3)2 ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
 
* La(NO3)3 Ce(NO3)3
Ce(NO3)4
Pr(NO3)3 Nd(NO3)3 Pm(NO3)3 Sm(NO3)3 Eu(NO3)3 Gd(NO3)3 Tb(NO3)3 Dy(NO3)3 Ho(NO3)3 Er(NO3)3 Tm(NO3)3 Yb(NO3)3
** Ac(NO3)3 Th(NO3)4 PaO(NO3)3 UO2(NO3)2 Np(NO3)4 Pu(NO3)4 Am(NO3)3 Cm(NO3)3 Bk(NO3)3 Cf(NO3)3 Es Fm Md No
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