Alicea is a surname. Notable people with the surname include:
- Francisco Parés Alicea, Puerto Rican accountant and government official
- Geraldo Alicea (born 1963), American politician
- Ismael Alicea (1954–2015), American librarian
- Jose Alicea Mirabal (born 1967), Puerto Rican basketball player
- Luis Alicea (born 1965), Puerto Rican baseball player
- William Alicea Pérez, Puerto Rican politician
Fictional characters
- Vitin Alicea, a Puerto Rican television and radio character
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