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Benjamin Gung

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Chinese American academic

Benjamin W. Gung (born July 15, 1953) is a Chinese American organic chemist and academic. He is an emeritus Professor of Chemistry at Miami University.

Gung and his research group have concentrated on two main areas: organic synthesis, including the total synthesis of natural products and the development of new methodologies, and the study of nonbonding interactions involving aromatic rings. Together, they have synthesized a variety of natural products.

Gung is ranked among the top 2 percent of researchers worldwide, according to a recent Stanford University study that used citation analysis to identify leading scholars among nearly eight million authors.

Education and career

After receiving a bachelor's degree in chemistry from Nanjing University in China in 1982, Gung pursued graduate studies in organic chemistry at Kansas State University, where he completed his M.S. in 1984 and Ph.D. in 1987, studying under Richard McDonald and Duy Hua. Following a two-year postdoctoral appointment at the University of South Carolina under James Marshall, he joined the faculty at Miami University, in Oxford, Ohio in 1989. He was promoted to associate professor in 1994 and Full Professor in 2003, and during his tenure there, he spent his sabbatical leave doing research in the group of William Roush at the University of Michigan in 1999. Since 2024, he has been serving as an emeritus Professor.

Gung has supervised graduate and undergraduate students in chemistry research. He has held key roles, including serving as a reviewer for five NSF-Career Applications in 2004 and organizing an NSF-sponsored REU program at Miami University from 2004 to 2006. He also reviewed NIH Fellowship Study Sections from 2006 to 2011 and was a Co-PI on an NSF-DUE project from 2011 to 2014. After retiring in 2024, he continues collaborating with undergraduate students on research, with his publication, co-authored with Miami University students, focusing on amino acids and peptides as effective ligands for metal-centered catalysts

Research

Gung has made contributions to the field of organic chemistry, with over 100 published journal articles. His research interests include stereochemistry in organic reactions, non-covalent molecular interactions, methods development, and computational chemistry. He is known for his studies in stereochemical mechanism and in the development of a Transannular cycloaddition reaction with gold-stabilized allylic carbocations as reactive intermediate.

Selected articles

  • Gung, B. W. (1996). Diastereofacial selection in nucleophilic additions to unsymmetrically substituted trigonal carbons. Tetrahedron, 52(15), 5263–5301.
  • Gung, B. W. (1999). Structure distortions in heteroatom-substituted cyclohexanones, adamantanones, and adamantanes: Origin of diastereofacial selectivity. Chemical reviews, 99(5), 1377–1386.
  • Gung, B. W., Xue, X., & Reich, H. J. (2005). The strength of parallel-displaced arene− arene interactions in chloroform. The Journal of Organic Chemistry, 70(9), 3641–3644.
  • Gung, B. W., Patel, M., & Xue, X. (2005). A threshold for charge transfer in aromatic interactions? A quantitative study of π-stacking interactions. The Journal of Organic Chemistry, 70(25), 10532–10537.
  • Gung, B. W., & Amicangelo, J. C. (2006). Substituent Effects in C6F6 C6H5X Stacking Interactions. The Journal of organic chemistry, 71(25), 9261–9270.
  • Gung, B. W., Zou, Y., Xu, Z., Amicangelo, J. C., Irwin, D. G., Ma, S., & Zhou, H. C. (2008). Quantitative study of interactions between oxygen lone pair and aromatic rings: Substituent effect and the importance of closeness of contact. The Journal of Organic Chemistry, 73(2), 689–693.

References

  1. "Benjamin W. Gung, Ph.D. | Department of Chemistry and Biochemistry | CAS". Miami University.
  2. "Miami Faculty Recognized Among Top Scholars" (PDF).
  3. "Benjamin W. Gung". scholar.google.com.
  4. "More than 20 Miami professors among top 2% of researchers based on analysis of citations". www.miamioh.edu.
  5. "Emeritus Faculty⎮Department of Chemistry and Biochemistry". Miami University.
  6. "CAS announces its 2023-24 Dean's Scholars". Miami University. May 5, 2023.
  7. "Past Members". Sharma Laboratory.
  8. "Mason Krysinski Chosen Academic All-MAC". Miami University RedHawks. January 31, 2013.
  9. "NSF Award Search: Award # 0353179 - REU: Summer Undergraduate Research in Chemistry at Miami University, Oxford". www.nsf.gov.
  10. "NSF Award Search: Award # 1044549 - Collaboration and Guided Inquiry in the Organic Chemistry Laboratory". www.nsf.gov.
  11. Gung, Benjamin W.; Kubesch, Cole; Bernstein, Gavriella (November 29, 2024). "Natural Chiral Ligand Strategy: Metal-Catalyzed Reactions with Ligands Prepared from Amino Acids and Peptides". Catalysts. 14 (11): 813. doi:10.3390/catal14110813 – via www.mdpi.com.{{cite journal}}: CS1 maint: unflagged free DOI (link)
  12. ^ Gung, Benjamin W. (April 8, 1996). "Diastereofacial selection in nucleophilic additions to unsymmetrically substituted trigonal carbons". Tetrahedron. 52 (15): 5263–5301. doi:10.1016/0040-4020(95)01023-8 – via ScienceDirect.
  13. ^ Gung, Benjamin W. (May 12, 1999). "Structure Distortions in Heteroatom-Substituted Cyclohexanones, Adamantanones, and Adamantanes:  Origin of Diastereofacial Selectivity". Chemical Reviews. 99 (5): 1377–1386. doi:10.1021/cr980365q – via ACS Publications.
  14. Gung, Benjamin W.; Xue, Xiaowen; Reich, Hans J. (April 29, 2005). "The strength of parallel-displaced arene-arene interactions in chloroform". The Journal of Organic Chemistry. 70 (9): 3641–3644. doi:10.1021/jo050049t. PMID 15845001 – via PubMed.
  15. Gung, Benjamin W.; Patel, Mehul; Xue, Xiaowen (December 1, 2005). "A Threshold for Charge Transfer in Aromatic Interactions? A Quantitative Study of π-Stacking Interactions". The Journal of Organic Chemistry. 70 (25): 10532–10537. doi:10.1021/jo051808a – via ACS Publications.
  16. "Substituent Effects in C6F6-C6H5X Stacking Interactions - PMC".
  17. Marshall, James A.; Welmaker, Gregory S.; Gung, Benjamin W. (January 1, 1991). "On the 1,3-isomerization of nonracemic .alpha.-(alkoxy)allylstannanes". Journal of the American Chemical Society. 113 (2): 647–656. doi:10.1021/ja00002a038 – via ACS Publications.
  18. Gung, Benjamin W.; Xue, Xiaowen; Roush, William R. (September 1, 2002). "The Origin of Diastereofacial Control in Allylboration Reactions Using Tartrate Ester Derived Allylboronates:  Attractive Interactions between the Lewis Acid Coordinated Aldehyde Carbonyl Group and an Ester Carbonyl Oxygen". Journal of the American Chemical Society. 124 (36): 10692–10697. doi:10.1021/ja026373c – via ACS Publications.
  19. "Enthalpy (ΔH) and Entropy (ΔS) for π-Stacking Interactions in near-Sandwich Configurations: The Relative Importance of Electrostatic, Dispersive, and Charge-Transfer Effects - PMC".
  20. Craft, Derek T.; Gung, Benjamin W. (October 6, 2008). "The first transannular [4+3] cycloaddition reaction: synthesis of the ABCD ring structure of cortistatins". Tetrahedron Letters. 49 (41): 5931–5934. doi:10.1016/j.tetlet.2008.07.155. PMC 2597840. PMID 19812680 – via PubMed.
  21. Gung, Benjamin W.; Craft, Derek T.; Bailey, Lauren N.; Kirschbaum, Kristin (January 11, 2010). "Gold-catalyzed transannular [4+3] cycloaddition reactions". Chemistry (Weinheim an Der Bergstrasse, Germany). 16 (2): 639–644. doi:10.1002/chem.200902185. PMC 3539418. PMID 19937623 – via PubMed.
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