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Cadmium selenate

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Cadmium selenate
CadmiumkationSelenat-Anion
Identifiers
CAS Number
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.034.060 Edit this at Wikidata
EC Number
  • 237-481-3
PubChem CID
UNII
CompTox Dashboard (EPA)
InChI
  • InChI=1S/Cd.H2O4Se/c;1-5(2,3)4/h;(H2,1,2,3,4)/q+2;/p-2Key: VTFKXHQTGNWIJW-UHFFFAOYSA-L
SMILES
  • .(=O)(=O)
Properties
Chemical formula CdO4Se
Molar mass 255.381 g·mol
Appearance colourless solid (dihydrate)
Density 3.62 g·cm (dihydrate)
Melting point 100 °C (dihydrate decomposes)
Solubility in water 70.5 g·l
Hazards
GHS labelling:
Pictograms GHS06: ToxicGHS08: Health hazardGHS09: Environmental hazard
Signal word Warning
Hazard statements H301, H331, H373, H410
Precautionary statements P260, P261, P264, P270, P271, P273, P301+P316, P304+P340, P316, P319, P321, P330, P391, P403+P233, P405, P501
Related compounds
Other anions cadmium sulfate
cadmium selenite
Other cations zinc selenate
mercury selenate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). Infobox references
Chemical compound

Cadmium selenate is a selenate of cadmium, with the chemical formula CdSeO4.

Preparation

Cadmium selenate can be formed by the reaction of cadmium oxide and selenic acid. The product is a mixture of monohydrate and dihydrate.

CdO + H2SeO4 → CdSeO4 + H2O

Properties

Cadmium selenate dihydrate is a colorless solid. At 100 °C, the dihydrate releases water of crystallization to form cadmium selenate monohydrate. The monohydrate is monoclinic with space group P21/c (no. 14), while the dihydrate is orthorhombic, with space group Pbca (no. 61).

References

  1. ^ R. J. Meyer (2013), Cadmium System-Nummer 33, Springer-Verlag, p. 133, ISBN 978-3-662-11295-3
  2. ^ William M. Haynes (2016), CRC Handbook of Chemistry and Physics, 94th Edition, CRC Press, p. 54, ISBN 978-1-4665-7115-0
  3. "Cadmium selenate". pubchem.ncbi.nlm.nih.gov.
  4. ^ Stålhandske, C. (1981-11-15). "Structure of cadmium selenate monohydrate". Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry. 37 (11): 2055–2057. Bibcode:1981AcCrB..37.2055S. doi:10.1107/S0567740881007942.
  5. H.U.v. Vogel (2013), Chemiker-Kalender, Springer-Verlag, p. 78, ISBN 978-3-662-06237-1
Cadmium compounds
Cadmium(I)
Cadmium(II)
Salts and covalent derivatives of the selenate ion
H2SeO4 He
Li2SeO4 Be B C (NH4)2SeO4 O F Ne
Na2SeO4 MgSeO4 Al2(SeO4)3 Si P S Cl Ar
K2SeO4 CaSeO4 Sc Ti V Cr Mn FeSeO4
Fe2(SeO4)3
CoSeO4 NiSeO4 CuSeO4 ZnSeO4 Ga2(SeO4)3 Ge As SeO4 Br Kr
Rb2SeO4 Sr Y Zr(SeO4)2 Nb Mo Tc Ru Rh Pd Ag2SeO4 CdSeO4 In Sn Sb Te I Xe
Cs2SeO4 BaSeO4 * Lu2(SeO4)3 Hf(SeO4)2 Ta W Re Os Ir Pt Au2(SeO3)2(SeO4) Hg Tl PbSeO4 Bi Po At Rn
Fr Ra ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
 
* La2(SeO4)3 Ce2(SeO4)3
Ce(SeO4)2
Pr2(SeO4)3 Nd Pm Sm2(SeO4)3 Eu Gd2(SeO4)3 Tb Dy2(SeO4)3 Ho2(SeO4)3 Er2(SeO4)3 Tm2(SeO4)3 Yb2(SeO4)3
** Ac Th(SeO4)2 Pa U Np Pu Am Cm Bk Cf Es Fm Md No
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