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Californium tetrafluoride

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Californium tetrafluoride
Names
Other names Californium tetrafluoride
Identifiers
CAS Number
3D model (JSmol)
InChI
  • InChI=1S/Cf.4FH/h;4*1H/q+4;;;;/p-4Key: OXMFOZUWMXDEGZ-UHFFFAOYSA-J
SMILES
  • ....
Properties
Chemical formula CfF4
Molar mass 327 g·mol
Appearance light green solid
Density g/cm
Structure
Crystal structure monoclinic
Related compounds
Related compounds Berkelium tetrafluoride
Einsteinium tetrafluoride
Hazards
Occupational safety and health (OHS/OSH):
Main hazards Radioactive
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). Infobox references
Chemical compound

Californium tetrafluoride is a binary inorganic compound of californium and fluorine with the formula CfF4.

Synthesis

Californium tetrafluoride can be prepared from Cf2O3 and F2 at 400 °C.

2Cf2O3 + 8F2 → 4CfF4 + 3O2

Also californium tetrafluoride is produced by β-decay of BkF4.

Physical properties

Californium tetrafluoride is a light green solid. It possesses a monoclinic UF4 structure.

Chemical properties

CfF4 decomposes to californium trifluoride when heated:

2CfF4 → 2CfF3 + 2F

References

  1. "WebElements Periodic Table » Californium » californium tetrafluoride". winter.group.shef.ac.uk. Retrieved 3 April 2024.
  2. ^ Macintyre, Jane E. (23 July 1992). Dictionary of Inorganic Compounds, Volume 1. Chapman & Hall. p. 2826. ISBN 978-0-412-30120-9. Retrieved 3 April 2024.
  3. Chang, C.-T. P.; Haire, R. G.; Nave, S. E. (1 May 1990). "Magnetic susceptibility of californium fluorides". Physical Review B. 41 (13): 9045–9048. doi:10.1103/physrevb.41.9045. PMID 9993248. Retrieved 3 April 2024.
Californium compounds
Cf(II)
Cf(III)
Organocalifornium(III) compounds
Cf(IV)
Salts and covalent derivatives of the fluoride ion
HF ?HeF2
LiF BeF2 BF
BF3
B2F4
+BO3
CF4
CxFy
+CO3
NF3
FN3
N2F2
NF
N2F4
NF2
?NF5
OF2
O2F2
OF
O3F2
O4F2
?OF4
F2 Ne
NaF MgF2 AlF
AlF3
SiF4 P2F4
PF3
PF5
S2F2
SF2
S2F4
SF3
SF4
S2F10
SF6
+SO4
ClF
ClF3
ClF5
?ArF2
?ArF4
KF CaF
CaF2
ScF3 TiF2
TiF3
TiF4
VF2
VF3
VF4
VF5
CrF2
CrF3
CrF4
CrF5
?CrF6
MnF2
MnF3
MnF4
?MnF5
FeF2
FeF3
FeF4
CoF2
CoF3
CoF4
NiF2
NiF3
NiF4
CuF
CuF2
?CuF3
ZnF2 GaF2
GaF3
GeF2
GeF4
AsF3
AsF5
Se2F2
SeF4
SeF6
+SeO3
BrF
BrF3
BrF5
KrF2
?KrF4
?KrF6
RbF SrF
SrF2
YF3 ZrF2
ZrF3
ZrF4
NbF4
NbF5
MoF4
MoF5
MoF6
TcF4
TcF
5

TcF6
RuF3
RuF
4

RuF5
RuF6
RhF3
RhF4
RhF5
RhF6
PdF2
Pd
PdF4
?PdF6
Ag2F
AgF
AgF2
AgF3
CdF2 InF
InF3
SnF2
SnF4
SbF3
SbF5
TeF4
?Te2F10
TeF6
+TeO3
IF
IF3
IF5
IF7
+IO3
XeF2
XeF4
XeF6
?XeF8
CsF BaF2   LuF3 HfF4 TaF5 WF4
WF5
WF6
ReF4
ReF5
ReF6
ReF7
OsF4
OsF5
OsF6
?OsF
7

?OsF
8
IrF2
IrF3
IrF4
IrF5
IrF6
PtF2
Pt
PtF4
PtF5
PtF6
AuF
AuF3
Au2F10
?AuF6
AuF5•F2
Hg2F2
HgF2
?HgF4
TlF
TlF3
PbF2
PbF4
BiF3
BiF5
?PoF2
PoF4
PoF6
AtF
?AtF3
?AtF5
RnF2
?RnF
4

?RnF
6
FrF RaF2   LrF3 Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
LaF3 CeF3
CeF4
PrF3
PrF4
NdF2
NdF3
NdF4
PmF3 SmF2
SmF3
EuF2
EuF3
GdF3 TbF3
TbF4
DyF2
DyF3
DyF4
HoF3 ErF3 TmF2
TmF3
YbF2
YbF3
AcF3 ThF3
ThF4
PaF4
PaF5
UF3
UF4
UF5
UF6
NpF3
NpF4
NpF5
NpF6
PuF3
PuF4
PuF5
PuF6
AmF2
AmF3
AmF4
?AmF6
CmF3
CmF4
 ?CmF6
BkF3
BkF
4
CfF3
CfF4
EsF3
EsF4
?EsF6
Fm Md No
Halides of actinides
Ac Th Pa U Np Pu Am Cm Bk Cf Es
+6 UF6
UCl6
NpF6 PuF6 AmF6 EsF6
+5 PaF5
PaCl5
PaBr5
PaI5
UF5
UCl5
UBr5
NpF5 PuF5
+4 ThF4
ThCl4
ThBr4
ThI4
PaF4
PaCl4
PaBr4
PaI4
UF4
UCl4
UBr4
UI4
NpF4
NpCl4
NpBr4
PuF4 AmF4 CmF4 BkF4 CfF4 EsF4
+3 AcF3
AcCl3
AcBr3
AcI3
ThF3
ThCl3
ThI3
UF3
UCl3
UBr3
UI3
NpF3
NpCl3
NpBr3
NpI3
PuF3
PuCl3
PuBr3
PuI3
AmF3
AmCl3
AmBr3
AmI3
CmF3
CmCl3
CmBr3
CmI3
BkF3
BkCl3
BkBr3
BkI3
CfF3
CfCl3
CfBr3
CfI3
EsF3
EsCl3
EsBr3
EsI3
+2 ThI2
ThCl2
AmF2
AmCl2
AmBr2
AmI2
CfI2
CfCl2
EsCl2
EsBr2
EsI2
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