Cerium(III) bromide - Misplaced Pages

Cerium(III) bromide is an inorganic compound with the formula CeBr₃. This white hygroscopic solid is of interest as a component of scintillation counters.

Preparation and basic properties

The compound has been known since at least 1899, when Muthman and Stützel reported its preparation from cerium sulfide and gaseous HBr. Aqueous solutions of CeBr₃ can be prepared from the reaction of Ce₂(CO₃)₃·H₂O with HBr. The product, CeBr₃·H₂O can be dehydrated by heating with NH₄Br followed by sublimation of residual NH₄Br. CeBr₃ can be distilled at reduced pressure (~ 0.1 Pa) in a quartz ampoule at 875-880 °C. Like the related salt CeCl₃, the bromide absorbs water on exposure to moist air. The compound melts congruently at 722 °C, and well ordered single crystals may be produced using standard crystal growth methods like Bridgman or Czochralski.

CeBr₃ adopts the hexagonal, UCl₃-type crystal structure with the P6₃/m space group. The cerium ions are 9-coordinate and adopt a tricapped trigonal prismatic geometry. The cerium–bromine bond lengths are 3.11 Å and 3.16 Å.

Applications

CeBr₃-doped lanthanum bromide single crystals are known to exhibit superior scintillation properties for applications in the security, medical imaging, and geophysics detectors.

Undoped single crystals of CeBr₃ have shown promise as a γ-ray scintillation detector in nuclear non-proliferation testing, medical imaging, environmental remediation, and oil exploration.

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References

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