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Other names Pentammineplatinum(IV) chloride, Pentammineplatinum chloride, Chloropentammineplatinum(IV) chloride | |
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Chemical formula | Cl4H15N5Pt |
Molar mass | 422.04 g·mol |
Appearance | white solid |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). Infobox references |
Chloropentammineplatinum chloride is an inorganic compound with the formula [PtCl(NH3)5]Cl3. It is a chloride salt of the coordination complex [PtCl(NH3)5]. It is a white, water soluble solid.
The compound is prepared by treating potassium hexachloroplatinate with aqueous ammonia:
- K2PtCl6 + 5 NH3 → [PtCl(NH3)5]Cl3 + 2 KCl
Related platinum(IV) ammines
The title complex is one of several platinum ammine complexes.
- Hexaammineplatinum(IV) chloride
- Trichlorotriammineplatinum(IV) chloride
- cis-Tetrachlorodiammineplatinum(IV)
- trans-Tetrachlorodiammineplatinum(IV) (RN 16986-23-5)
References
- Curtis, Neville J.; Lawrance, Geoffrey A.; Sargeson, Alan M.; Johnson, Ronald C. (1986). "Pentaammineplatinum(IV) Complexes". Inorganic Syntheses. Vol. 24. pp. 277–279. doi:10.1002/9780470132555.ch74. ISBN 9780471834410.
- Gildengershel, Kh. I. (1966). "Synthesis of Cleve's salts Cl and Cl". Zhurnal Prikladnoi Khimii. 39: 223-5.
- ^ Kauffman, George B.; Slusarczuk, George; Kirschner, Stanley (1963). "cis ‐ and trans ‐Tetrachlorodiammineplatinum(IV)". Inorganic Syntheses. Vol. 7. pp. 236–238. doi:10.1002/9780470132388.ch62. ISBN 9780470131664.