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Diisopropylzinc

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Diisopropylzinc
Skeletal formula of diisopropylzinc
Ball-and-stick model of the diisopropylzinc molecule
Identifiers
CAS Number
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.221.415 Edit this at Wikidata
PubChem CID
CompTox Dashboard (EPA)
InChI
  • InChI=1S/2C3H7.Zn/c2*1-3-2;/h2*3H,1-2H3;Key: KDUNMLRPPVCIGP-UHFFFAOYSA-N
  • InChI=1/2C3H7.Zn/c2*1-3-2;/h2*3H,1-2H3;/rC6H14Zn/c1-5(2)7-6(3)4/h5-6H,1-4H3Key: KDUNMLRPPVCIGP-LSPCJBSIAV
SMILES
  • CC(C)C(C)C
Properties
Chemical formula C6H14Zn
Molar mass 151.56 g/mol
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). checkY verify (what is  ?) Infobox references
Chemical compound

Diisopropylzinc is an organozinc compound with the chemical formula ZnC6H14.

It is the key reagent in the Soai reaction, which is both autocatalytic and enantiospecific. This chemical is pyrophoric, bursting into flame in air or in contact with water. It is generally packaged in toluene.

References

  1. Benjamin Bederson; Herbert Walther (2002). Advances in Atomic, Molecular, and Optical Physics. Gulf Professional Publishing. pp. 250–. ISBN 978-0-12-003848-0. Retrieved 2013-08-06.
  2. Shibata, Takanori; Morioka, Hiroshi; Hayase, Tadakatsu; Choji, Kaori; Soai, Kenso (1996). "Highly Enantioselective Catalytic Asymmetric Automultiplication of Chiral Pyrimidyl Alcohol". Journal of the American Chemical Society. 118 (2): 471–472. doi:10.1021/ja953066g.
  3. "Diisopropylzinc 1.0M toluene 625-81-0". MilliporeSigma. Retrieved 8 January 2022.
Zinc compounds
Zinc(I)
Organozinc(I) compounds
Zinc(II)
Organozinc(II) compounds
  • Zn(CH3)2
  • Zn(C2H5)2
  • Zn(CH3COO)2
  • Zn(CH(CH3)2)2
  • Zn(C(CH3)3)2
  • Zn(C6H5)2
  • Zn(C3H5O3)2
  • ZnICH2I
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