Doval is a surname. Notable people with the surname include:
- Ajit Doval (born 1945), Indian intelligence official
- Camilo Doval (born 1997), Dominican baseball relief pitcher for the San Francisco Giants
- Fernanda Doval (born 1975), Brazilian volleyball player
- Fernando Rodríguez Doval (born 1980), Mexican politician
- Juan de Dios Doval Mateo (1943-1980), Spanish politician and law professor
- Narciso Horacio Doval (1944-1991), Argentine footballer
- Shaurya Doval, Indian politician
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