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Ent-pimara-9(11),15-diene synthase

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ent-pimara-9(11),15-diene synthase
Identifiers
EC no.4.2.3.31
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ent-Pimara-9(11),15-diene synthase (EC 4.2.3.31, PMD synthase) is an enzyme with systematic name ent-copalyl-diphosphate diphosphate-lyase (ent-pimara-9(11),15-diene-forming). This enzyme catalyses the following chemical reaction

ent-copalyl diphosphate {\displaystyle \rightleftharpoons } ent-pimara-9(11),15-diene + diphosphate

This enzyme is involved in the biosynthesis of the diterpenoid viguiepinol and requires Mg, Co, Zn or Ni for activity.

References

  1. Ikeda C, Hayashi Y, Itoh N, Seto H, Dairi T (January 2007). "Functional analysis of eubacterial ent-copalyl diphosphate synthase and pimara-9(11),15-diene synthase with unique primary sequences". Journal of Biochemistry. 141 (1): 37–45. doi:10.1093/jb/mvm004. PMID 17148547.

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Carbon–oxygen lyases (EC 4.2) (primarily dehydratases)
4.2.1: Hydro-Lyases
4.2.2: Acting on polysaccharides
4.2.3: Acting on phosphates
4.2.99: Other
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