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Hydrofluoric acid

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(Redirected from Fluoric acid) Solution of hydrogen fluoride in water
Hydrofluoric acid
Names
IUPAC name Fluorane
Other names Fluorhydric acid
Hydronium fluoride
Identifiers
CAS Number
3D model (JSmol)
ChEBI
ChemSpider
EC Number
  • 231-634-8
PubChem CID
RTECS number
  • MW7875000
UNII
CompTox Dashboard (EPA)
InChI
  • InChI=1S/FH/h1HKey: KRHYYFGTRYWZRS-UHFFFAOYSA-N
  • InChI=1/FH/h1HKey: KRHYYFGTRYWZRS-UHFFFAOYAC
SMILES
  • F.O
  • .
Properties
Chemical formula HF (aq)
Appearance Colorless liquid
Density 1.15 g/mL (for 48% soln.)
Acidity (pKa) 3.17
Hazards
GHS labelling:
Pictograms CorrosiveAcute Toxicity
Signal word Danger
Hazard statements H280, H300+H310+H330, H314
Precautionary statements P260, P262, P264, P270, P271, P280, P284, P301+P310, P301+P330+P331, P302+P350, P303+P361+P353, P304+P340, P305+P351+P338, P310, P320, P321, P322, P330, P361, P363, P403+P233, P405, P410+P403, P501
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 4: Very short exposure could cause death or major residual injury. E.g. VX gasFlammability 0: Will not burn. E.g. waterInstability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogenSpecial hazard ACID: Acid
4 0 0ACID
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). checkY verify (what is  ?) Infobox references
Chemical compound

Hydrofluoric acid is a solution of hydrogen fluoride (HF) in water. Solutions of HF are colorless, acidic and highly corrosive. A common concentration is 49% (48-52%) but there are also stronger solutions (e.g. 70%) and pure HF has a boiling point near room temperature. It is used to make most fluorine-containing compounds; examples include the commonly used pharmaceutical antidepressant medication fluoxetine (Prozac) and the material PTFE (Teflon). Elemental fluorine is produced from it. It is commonly used to etch glass and silicon wafers.

Uses

Production of organofluorine compounds

The principal use of hydrofluoric acid is in organofluorine chemistry. Many organofluorine compounds are prepared using HF as the fluorine source, including Teflon, fluoropolymers, fluorocarbons, and refrigerants such as freon. Many pharmaceuticals contain fluorine.

Production of inorganic fluorides

Most high-volume inorganic fluoride compounds are prepared from hydrofluoric acid. Foremost are Na3AlF6, cryolite, and AlF3, aluminium trifluoride. A molten mixture of these solids serves as a high-temperature solvent for the production of metallic aluminium. Other inorganic fluorides prepared from hydrofluoric acid include sodium fluoride and uranium hexafluoride.

Etchant, cleaner

Wet etching tanks

It is used in the semiconductor industry as a major component of Wright etch and buffered oxide etch, which are used to clean silicon wafers. In a similar manner it is also used to etch glass by treatment with silicon dioxide to form gaseous or water-soluble silicon fluorides. It can also be used to polish and frost glass.

SiO2 + 4 HF → SiF4(g) + 2 H2O
SiO2 + 6 HF → H2SiF6 + 2 H2O

A 5% to 9% hydrofluoric acid gel is also commonly used to etch all ceramic dental restorations to improve bonding. For similar reasons, dilute hydrofluoric acid is a component of household rust stain remover, in car washes in "wheel cleaner" compounds, in ceramic and fabric rust inhibitors, and in water spot removers. Because of its ability to dissolve iron oxides as well as silica-based contaminants, hydrofluoric acid is used in pre-commissioning boilers that produce high-pressure steam. Hydrofluoric acid is also useful for dissolving rock samples (usually powdered) prior to analysis. In similar manner, this acid is used in acid macerations to extract organic fossils from silicate rocks. Fossiliferous rock may be immersed directly into the acid, or a cellulose nitrate film may be applied (dissolved in amyl acetate), which adheres to the organic component and allows the rock to be dissolved around it.

Oil refining

In a standard oil refinery process known as alkylation, isobutane is alkylated with low-molecular-weight alkenes (primarily a mixture of propylene and butylene) in the presence of an acid catalyst derived from hydrofluoric acid. The catalyst protonates the alkenes (propylene, butylene) to produce reactive carbocations, which alkylate isobutane. The reaction is carried out at mild temperatures (0 and 30 °C) in a two-phase reaction.

Production

Hydrofluoric acid was first prepared in 1771, by Carl Wilhelm Scheele. It is now mainly produced by treatment of the mineral fluorite, CaF2, with concentrated sulfuric acid at approximately 265 °C.

CaF2 + H2SO4 → 2 HF + CaSO4

The acid is also a by-product of the production of phosphoric acid from apatite and fluoroapatite. Digestion of the mineral with sulfuric acid at elevated temperatures releases a mixture of gases, including hydrogen fluoride, which may be recovered.

Because of its high reactivity toward glass, hydrofluoric acid is stored in fluorinated plastic (often PTFE) containers.

Properties

In dilute aqueous solution hydrogen fluoride behaves as a weak acid, Infrared spectroscopy has been used to show that, in solution, dissociation is accompanied by formation of the ion pair H3O·F.

H2O + HF ⇌ H3O⋅F pKa = 3.17

This ion pair has been characterized in the crystalline state at very low temperature. Further association has been characterized both in solution and in the solid state.

HF + F ⇌ HF
2 log K = 0.6

It is assumed that polymerization occurs as the concentration increases. This assumption is supported by the isolation of a salt of a tetrameric anion H
3F
4 and by low-temperature X-ray crystallography. The species that are present in concentrated aqueous solutions of hydrogen fluoride have not all been characterized; in addition to HF
2 which is known the formation of other polymeric species, H
n−1F
n, is highly likely.

The Hammett acidity function, H0, for 100% HF was first reported as -10.2, while later compilations show -11, comparable to values near -12 for pure sulfuric acid.

Acidity

Unlike other hydrohalic acids, such as hydrochloric acid, hydrogen fluoride is only a weak acid in dilute aqueous solution. This is in part a result of the strength of the hydrogen–fluorine bond, but also of other factors such as the tendency of HF, H
2O, and F
anions to form clusters. At high concentrations, HF molecules undergo homoassociation to form polyatomic ions (such as bifluoride, HF
2) and protons, thus greatly increasing the acidity. This leads to protonation of very strong acids like hydrochloric, sulfuric, or nitric acids when using concentrated hydrofluoric acid solutions. Although hydrofluoric acid is regarded as a weak acid, it is very corrosive, even attacking glass when hydrated.

Dilute solutions are weakly acidic with an acid ionization constant Ka = 6.6×10 (or pKa = 3.18), in contrast to corresponding solutions of the other hydrogen halides, which are strong acids (pKa < 0). However concentrated solutions of hydrogen fluoride are much more strongly acidic than implied by this value, as shown by measurements of the Hammett acidity function H0(or "effective pH"). During self ionization of 100% liquid HF the H0 was first measured as −10.2 and later compiled as −11, comparable to values near −12 for sulfuric acid.

In thermodynamic terms, HF solutions are highly non-ideal, with the activity of HF increasing much more rapidly than its concentration. The weak acidity in dilute solution is sometimes attributed to the high H—F bond strength, which combines with the high dissolution enthalpy of HF to outweigh the more negative enthalpy of hydration of the fluoride ion. Paul Giguère and Sylvia Turrell have shown by infrared spectroscopy that the predominant solute species in dilute solution is the hydrogen-bonded ion pair H3O·F.

H2O + HF ⇌ H3O⋅F

With increasing concentration of HF the concentration of the hydrogen difluoride ion also increases. The reaction

3 HF ⇌ HF
2 + H2F

is an example of homoconjugation.

Health and safety

A hydrofluoric acid burn of the hand
Main article: Hydrofluoric acid burn
This article needs more reliable medical references for verification or relies too heavily on primary sources. Please review the contents of the article and add the appropriate references if you can. Unsourced or poorly sourced material may be challenged and removed. Find sources: "Hydrofluoric acid" – news · newspapers · books · scholar · JSTOR (November 2019)

In addition to being a highly corrosive liquid, hydrofluoric acid is also a powerful contact poison. Since it can penetrate tissue, poisoning can occur readily through exposure of skin or eyes, inhalation, or ingestion. Symptoms of exposure to hydrofluoric acid may not be immediately evident, and this can provide false reassurance to victims, causing them to delay medical treatment. Despite its irritating vapor, HF may reach dangerous levels without an obvious odor. It interferes with nerve function, meaning that burns may not initially be painful. Accidental exposures can go unnoticed, delaying treatment and increasing the extent and seriousness of the injury. Symptoms of HF exposure include irritation of the eyes, skin, nose, and throat, eye and skin burns, rhinitis, bronchitis, pulmonary edema (fluid buildup in the lungs), and bone damage due to HF strongly interacting with calcium in bones. In a concentrated form, HF can cause severe tissue destruction through lesions and mucous membrane damage, but dilute HF is still dangerous because of its high lipid affinity, leading to cellular death of nerves, blood vessels, tendons, bones, and other tissues.

Hydrofluoric burns are treated with a calcium gluconate gel.

In popular culture

See also

References

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