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Johnsenite-(Ce)

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Mineral of the eudialyte group
Johnsenite-(Ce)
General
CategoryCyclosilicate
Formula
(repeating unit)
Na12(Ce,La,Sr,Ca,[ ])3Ca6Mn3Zr3WSi(Si9O27)2(Si3O9)2(CO3)O(OH,Cl)2 (original form)
IMA symbolJsn
Strunz classification9.CO.10 (10 ed)
8/E.25-57 (8 ed)
Dana classification64.1.2.7
Crystal systemTrigonal
Crystal classHexagonal scalenohedral (3m)
H-M symbol: (3 2m)
Space groupR3m
Unit cella = 14.24, c = 30.03  (approximated); Z = 3
Identification
ColorPale yellow to bright orange
Crystal habitSkeletal crystals (etched); aggregates
CleavageNone
FractureUneven
TenacityBrittle
Mohs scale hardness5–6
LusterVitreous
StreakWhite
DiaphaneityTransparent or translucent
Density3.24 (measured)
Optical propertiesUniaxial (−)
Refractive indexnω = 1.65, nε = 1.64 (approximated)
PleochroismNone
References

Johnsenite-(Ce) is a very rare mineral of the eudialyte group, with the chemical formula Na12(Ce,La,Sr,Ca,[ ])3Ca6Mn3Zr3WSi(Si9O27)2(Si3O9)2(CO3)O(OH,Cl)2. The original formula was extended to show the presence of both the cyclic silicate groups and silicon at the M4 site, according to the nomenclature of the eudialyte group. It is the third eudialyte-group mineral with essential tungsten (after khomyakovite and manganokhomyakovite), and second with essential rare earth elements (after zirsilite-(Ce), which is the niobium-analogue of johnsenite-(Ce)). In fact, some niobium substitutes for tungsten in johnsenite-(Ce). Other characteristic feature is the presence of essential carbonate group, shared with carbokentbrooksite, golyshevite, mogovidite and zirsilite-(Ce).

Occurrence and association

Johnsenite-(Ce) was discovered in alkaline rocks of Mont Saint-Hilaire, Quebec, Canada, which is also a type locality for other eudialyte group species: oneillite, khomyakovite and manganokhomyakovite. The association of johnsenite-(Ce) is rich, as it includes aegirine, albite, amphibole-group mineral, burbankite-group mineral, calcite, catapleiite, cerite-(Ce), dawsonite, epididymite, fluorapophyllite, galena, microcline, molybdenite, natrolite, pectolite, pyrite, pyrrhotite, quartz, rhodochrosite, sphalerite, steacyite, stillwellite-(Ce), titanite, tuperssuatsiaite, zakharovite and zirsilite-(Ce).

Notes on chemistry

Notable impurities in johnsenite-(Ce) are iron, titanium, niobium, yttrium, potassium, praseodymium, and neodymium. Traces of gadolinium, samarium, and hafnium are also reported.

Notes on crystal structure

Johnsenite-(Ce) has four-layer structure.

References

  1. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi:10.1180/mgm.2021.43. S2CID 235729616.
  2. ^ Mindat, Johnsenite-(Ce), http://www.mindat.org/min-27479.html
  3. ^ Grice, J.D., and Gault, R.A., 2006. Johnsenite-(Ce): a new member of the eudialyte group from Mont-Saint Hilaire, Quebec, Canada. The Canadian Mineralogist 44, 105–115
  4. Johnsen, O., Ferraris, G., Gault, R.A., Grice, D.G., Kampf, A.R., and Pekov, I.V., 2003. The nomenclature of eudialyte-group minerals. The Canadian Mineralogist 41, 785–794
  5. "Poudrette quarry (Demix quarry; Uni-Mix quarry; Desourdy quarry; Carrière Mont Saint-Hilaire), Mont Saint-Hilaire, La Vallée-du-Richelieu RCM, Montérégie, Québec, Canada - Mindat.org". Mindat.org. Retrieved 2016-03-11.
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