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Marcial (John Estrada) and Mercedes (Vina Morales) are a young married couple living in Cebu, who pray for children of their own, but have none. After five years, Mercedes becomes pregnant, but is diagnosed with a heart defect, making her pregnancy high-risk. Marcial went to church praying for guidance. While in church, Criselda Barrameda (Dimples Romana) had an epileptic seizure and Marcial, a doctor, brought her to his clinic. Resting in the clinic, Criselda told Marcial of Father Guido, her uncle, who was a priest in her hometown. With his deep faith in God, he was able to perform miraculous healing. People would not listen when Guido claimed it was the work of God and instead began to worship him. Angered, Father Guido left, telling no one of his destination. It was speculated that he was staying in the mountains. It was Father Guido whom Criselda sought for healing. A few months later, while at the church, Mercedes felt extremely thirsty and stole the jar of agua bendita (holy water). Afterwards, she craved agua bendita. Marcial learned Mercedes was carrying twins, one of whom inherited Mercedes' heart condition. Marcial prayed to God for help with his wife's desire for stolen agua bendita. One day, a group of men rush a weakened old man into Marcial's clinic, Father Guido. Nearing the end of his life, Guido instructed Marcial to give the bottle of agua bendita to Criselda. That night, Mercedes bled, almost having a miscarriage; Marcial gave her Father Guido's agua bendita in order to save her and their babies. Marcial later dreamt of the late Father Guido, who told him that if he would not ask for Criselda's forgiveness, there will be consequence to his stealing. Marcial kept his dream from Criselda, but one of daughters was sealed: Agua, the younger sister, was born in water form.

Fearing for Agua's safety, Marcial hid her with his assistant Tonyang, telling Mercedes that Agua is stillborn. Agua was kept in a huge aquarium inside a hidden room in the Cristis' house. Bendita, Agua's twin, was spoiled by her grandmother, Doña Amalia, the mother of Mercedes, while Agua became humble and content in Marcial's supervision. When the family learned of Agua's existence, Mercedes loved her, but Bendita and Doña Amalia hated Agua, usually punishing her by giving her hard chores. At one point, they abandoned Aqua in a park, where she met Tod, Criselda's crippled son.

She healed him with her tears, and he reunited her with her family. Criselda and Baldo, her husband, discovered Marcial's theft of agua bendita, and they took revenge on his family by kidnapping Bendita, mistaking her for Agua. The family travels to Manila to save the child they believe is Agua. Marcial discovers Agua's healing abilities, and used it to cure patients. The cures attracted media attention and the family had to flee on Doña Lisa's yacht. While at sea, Doña Amalia accidentally threw Agua overboard, letting the family think she drowned. Criselda and Tot stayed at the Aguirre household as maids to spy on the Cristis. Agua was found by Ben and Rosy, who raised Agua as their own daughter. They try to return Agua to her family, but learn that they moved to the United States, where Mercedes meets his colleague Luisito, who in turn offers him a job. Bendita once again feels loneliness within her family, and the couple decides to have their marriage annulled.

Ten years later, Bendita is a sassy spoiled teen, while Agua is a rural girl who only wants to be reunited with her family. Marcial is continuing his medical mission until Divina fell in love with him, which is why Mercedes started arranging their divorce. While staying in the Philippines, Agua befriended Dolly, a dolphin, and Otep, Dolly's pet clownfish. Ronnie falls from his sailboat, causing his blindness, and is saved by Agua. The two became close friends, until Marcial discovers Agua. The family reunites, despite Marcial and Mercedes' divorce. After years in America away from Agua, Bendita is unused to Agua. Bendita falls in love with Ronnie, who still loves Agua. Doña Amalia, on the other hand, struggles with debts, and steals the money intended for the hotel Ronnie's mother Solita is planning. Ronnie is reunited with Solita, and his blindness is treated. When he first saw Agua, he was shocked by her looks, causing Agua to run away to a deserted island by herself. On that island, Agua meets Paco (Tod), who befriends her. After a while, Paco brings Agua to Criselda and Baldo, who are now working for Señor Lucas, a fake healer. The group uses Agua's healing powers to benefit themselves.

Amalia approves of Luisito's plan to propose marriage to Mercedes. Agua cannot help but feel like she does not belong anywhere.

Mercedes reaches a decision when Amalia forces her to accept Luisito's proposal. Ben and Rosie try to pull Agua out of her loneliness. Amalia finds a way to stop Mercedes from leaving. An accident leads Ronnie to a fateful encounter with Agua. Agua finds a friend in Ronnie. While taking Ronnie to a medical mission, Ben comes face to face with a strikingly familiar man. Agua arrives at a difficult decision when Marcial shows up at Rosie and Ben's place. The Cristis cannot help but feel excited to finally reunite with Agua. Unknown to them, Baldo and Criselda continue their hunt for the long-lost woman. Marcial and Mercedes decide to hide the truth about their separation from Agua. This causes Bendita to become envious of her twin sister. Bendita's rage intensifies as Mercedes resolves to stay with Agua. Agua's joy is cut short when her acquaintance with sea creatures is reported by Bendita to Amalia. Despite this, the former makes an attempt to get close with Bendita, only to end in a disaster. Bendita finds an opportunity to escape from her family, and ventures in the sea. Agua comes to Bendita's rescue when the latter finds herself in a vulnerable situation. Amalia learns about her financial woes from her lawyer. Bendita expresses her sentiments on her parents’ separation. Agua comes up with a way to help Marcial and Mercedes reconcile. Marcial loses the chance of reconciling with Mercedes when he gets into serious trouble. Mercedes’ relationship with Marcial crumbles down after she discovered his alleged affair with Divina. Bendita becomes determined to steal Ronnie away from Agua. Bendita sabotages Ronnie's plan to serenade Agua. Despite this, Ronnie is bent on fighting for his feelings for Agua. Following his heart, Ronnie makes a choice between Agua and Bendita. Solita leaves no stone unturned in her search for her missing son, Ronnie. Ronnie's love letter sparks an argument between Agua and Bendita. Bendita gets wind of Agua's startling confession. Bendita grows overly inquisitive about her sister's healing ability, leaving Agua even more insecure. Ronnie surprises his mother with his new outlook in life. Ronnie undergoes an eye surgery, much to Agua's dejection. Amalia offers Divina a chance to earn Marcial's affection. Hoping to pull her son out of his misery, Solita gives in to Ronnie's desire to return to the island. Divina is in for a shock as Amalia refuses to let her give up her fight for Marcial's affection. Ronnie expresses his desire to remain friends with Agua despite the latter's fear that he will be disgusted by her appearance. Bendita learns of her sister's extraordinary ability. Divina manages to keep Marcial's attention to her. Ronnie feels that something is not right despite finally seeing Agua in the flesh. Bendita faces the consequences of her deceit. Amalia volunteers to arrange the launch of her and Solita's resort to prevent her business partner from learning about her financial status. Ronnie strikes a deal with Bendita.

Agua escapes the fraudulent healers with Paco's help. Bendita causes Solita's head trauma. The twins exchange appearances on different places; Agua turning normal at the seaport, while Bendita turns blue in the forest. Bendita tries to return to their household, but is kidnapped by Baldo, who thinks she's Agua. Agua returns home, but no one believes she is Agua as she still appears to be Bendita; she experiences Bendita's life, friendships and school, but eventually others come to believe she is who she claims to be. Mercedes' relationship with Luisito ends. Solita discovers Doña Amalia's betrayal, and fires her. Doña Amalia discovers the true Bendita, and makes a truce with Criselda and Baldo in exchange for Bendita's life. The police pursue the couple, leading to Baldo's escape and Criselda's imprisonment.

Doña Amalia continues to hide Bendita in exchange for a truce with Luisito. To learn Bendita's location, Mercedes agrees to marry Luisito. Marcial tries to stop them, but Luisito had a change of heart and freed Mercedes.

Solita files charges against Bendita, not knowing it is Agua. Ronnie frightens Bendita by faking a marriage contract with Agua, when Bendita arrives. Envious of Agua, Bendita steals some agua bendita from Criselda, and uses it to become a fake healer, but Baldo traps Bendita in a freezer. That night, Agua as Bendita celebrates her debut. Doña Amalia's ice sculpture for Bendita's debut arrives; unknown to everyone, the sculpture is Bendita herself in Agua's form, now frozen. Paco and Agua discover what happened to Bendita, while Doña Amalia almost breaks Bendita's ice sculpture. Marcial, Ben, Ronnie, and Paco carry Bendita to the pool to thaw her, but Agua finds a little amount of agua bendita, and drinks it which allows her to switch forms with her twin and regain her healing powers. Bendita thaws, but retains her fluid form; she is brownish while Agua is blue. Bendita blames Agua for what happened, worsening her misdeeds. She began to experience vomiting, abdominal pain, nausea, and finally lung cancer and a brain tumor. As Bendita continue to struggle with her sickness, the Cristi family searches for help. They found some of Criselda and Baldo's agua bendita but while this does not heal Bendita, Agua's is successful. During the preparations for Marcial and Mercedes' wedding, Mercedes is shot by Baldo and is hospitalized. That night, Agua dreams of Padre Gido, who warns her that if she heals her mother, those will be her last healing tears. Bendita calls Baldo to offer the spring water in exchange for her sister. Once freed, Agua goes to the hospital and heals her mother. Doña Amalia helps Criselda escape by leaving a hair pin to unlock the handcuffs fixing her to the hospital bed. Marcial spots Baldo waiting outside the hospital for Criselda; during their struggle for the gun, it goes off, killing Baldo. Paco goes to see his father's body in the hospital morgue and starts to feel anger. Criselda abducts Bendita, but Bendita texts Marcial the license plate number and the police chase Criselda's car. Paco finds Bendita and they embrace. Amalia falls into water; as she cannot swim, Agua saves Doña Amalia's life. Criselda shoots the LPG Tank, causing the boat to explode.